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a, Theo giả thiết ta có: \(n_P=\dfrac{3,1}{31}=0,1\left(mol\right)\)
\(4P+5O_2--t^o->2P_2O_5\)
Ta có: \(n_{O_2}=\dfrac{5}{4}.n_P=0,125\left(mol\right)\Rightarrow V_{O_2\left(đktc\right)}=0,125.22,4=2,8\left(l\right)\)
b, Theo giả thiết ta có: \(n_{CH_4}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
\(CH_4+2O_2--t^o->CO_2+2H_2O\)
Ta có: \(n_{O_2}=2.n_{CH_4}=0,1\left(mol\right)\Rightarrow V_{O_2\left(đktc\right)}=2,24\left(l\right)\)
\(n_{KMnO_4}=\dfrac{18.96}{158}=0.12\left(mol\right)\)
\(2KMnO_4\underrightarrow{t^0}K_2MnO_4+MnO_2+O_2\)
\(0.12...........................................0.06\)
\(V_{O_2}=0.06\cdot22.4=1.344\left(l\right)\)
\(n_{Al}=\dfrac{5.4}{27}=0.2\left(mol\right)\)
\(4Al+3O_2\underrightarrow{t^0}2Al_2O_3\)
\(0.08.....0.06.......0.04\)
\(m_{Al\left(dư\right)}=\left(0.2-0.08\right)\cdot27=3.24\left(g\right)\)
\(m_{Al_2O_3}=0.04\cdot102=4.08\left(g\right)\)
\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
PTHH: Fe2O3 + 3H2 --to--> 2Fe + 3H2O
0,1 0,3 0,2
\(V_{H_2}=0,3.22,4=6,72\left(l\right)\)
\(n_{O_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
PTHH: 3Fe + 2O2 --to--> Fe3O4
LTL: \(\dfrac{0,2}{3}>\dfrac{0,1}{2}\rightarrow\) Fe dư
Theo pthh: \(n_{Fe\left(pư\right)}=\dfrac{3}{2}n_{O_2}=\dfrac{3}{2}.0,1=0,15\left(mol\right)\)
\(\rightarrow m_{Fe\left(dư\right)}=\left(0,2-0,15\right).56=2,8\left(g\right)\)
a.\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1mol\)
\(Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\)
0,1 0,3 0,2 ( mol )
\(V_{H_2}=0,3.22,4=6,72l\)
b.\(n_{O_2}=\dfrac{2,24}{22,4}=0,1mol\)
\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)
\(\dfrac{0,2}{3}\) > \(\dfrac{0,1}{2}\) ( mol )
0,15 0,1 ( mol )
Chất dư là Fe
\(m_{Fe\left(dư\right)}=\left(0,2-0,15\right).56=2,8g\)
C2H2 + \(\frac{5}{2}\)O2 => (to) 2CO2 + H2O
0.25 0.625 0.5 0.25 (mol)
nCO2 = V/22.4 = 11.2/22.4 = 0.5 (mol);
m1 = n.M = 0.25 x 26 = 6.5 (g);
m2 = n.M = 0.25 x 18 = 4.5 (g);
m1 + m2 = 6.5 + 4.5 = 11 (g);
V = VO2 = n.22.4 = 0.625x22.4=14(l)
a)\(n_{H_2}=\dfrac{8,96}{22,4}=0,4mol\)
\(2H_2+O_2\underrightarrow{t^o}2H_2O\)
0,4 0,2 0,4
\(V_{O_2}=0,2\cdot22,4=4,48l\)
\(V_{kk}=5V_{O_2}=5\cdot4,48=22,4l\)
b)\(CuO+H_2\rightarrow Cu+H_2O\)
0,4 0,4
\(m_{H_2O}=0,4\cdot18=7,2g\)
\(n_{CH_4}=\dfrac{1,6}{16}=0,1\left(mol\right)\)
PTHH: \(CH_4+2O_2\xrightarrow[]{t^o}CO_2+2H_2O\)
0,1--->0,2----->0,1---->0,2
\(\Rightarrow\left\{{}\begin{matrix}V=V_{CO_2}=0,1.22,4=2,24\left(l\right)\\m=m_{H_2O}=0,2.18=3,6\left(g\right)\end{matrix}\right.\)
nH2 = 1,12/22,4 = 0,05 mol
2H2 + O2 ➝ 2H2O
0,05 ➝ 0,05 mol
➝ mH2O = 0,05.18 = 0,9 gam