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\(n_S=\dfrac{3.2}{32}=0.1\left(mol\right)\)
\(n_{O_2}=\dfrac{1.12}{22.4}=0.05\left(mol\right)\)
\(S+O_2\underrightarrow{t^0}SO_2\)
\(0.05.0.05...0.05\)
\(\Rightarrow Sdư\)
\(V_{SO_2}=0.05\cdot22.4=1.12\left(l\right)\)
\(b.\)
\(S+O_2\underrightarrow{t^0}SO_2\)
\(0.1..0.1\)
\(V_{kk}=5V_{O_2}=5\cdot0.1\cdot22.4=11.2\left(l\right)\)
a, PT: \(S+O_2\underrightarrow{t^o}SO_2\)
Ta có: \(n_S=\dfrac{3,2}{32}=0,1\left(mol\right)\)
\(n_{O_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,05}{1}\), ta được S dư.
Theo PT: \(n_{SO_2}=n_{O_2}=0,05\left(mol\right)\) \(\Rightarrow V_{SO_2}=0,05.22,4=1,12\left(l\right)\)
b, Theo PT: \(n_{O_2}=n_S=0,1\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,1.22,4=2,24\left(l\right)\)
\(\Rightarrow V_{kk}=2,24.5=11,2\left(l\right)\)
2KMnO4-to>K2MnO4+MnO2+O2
0,3-----------------0,15-----0,15------0,15 mol
n KMnO4=\(\dfrac{47,4}{158}\)=0,3 mol
=>mcr=0,15.197.0,15.87=42,6g
=>VO2=0,15.22,4=3,36l
b) 4P+5O2-to>2P2O5
0,1--------------0,05
nP=\(\dfrac{3,1}{31}\)=0,1 mol
->O2 dư
=>m P2O5=0,05.142=7,1g
mKMnO4 = 47,4/158 = 0,3 (mol)
PTHH: 2KMnO4 -> (t°) K2MnO4 + MnO2 + O2
Mol: 0,3 ---> 0,15 ---> 0,15 ---> 0,15
m = 0,15 . 197 + 0,15 . 87 = 85,2 (g)
V = VO2 = 0,15 . 22,4 = 3,36 (l)
nP = 3,1/31 = 0,1 (mol)
PTHH: 4P + 5O2 -> (t°) 2P2O5
LTL: 0,1/4 < 0,15/5 => O2 dư
nP2O5 = 0,1/2 = 0,05 (mol)
mP2O5 = 0,05 . 142 = 7,1 (g)
a.\(n_{CH_4}=\dfrac{V_{CH_4}}{22,4}=\dfrac{6,72}{22,4}=0,3mol\)
\(CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\)
0,3 0,6 ( mol )
\(V_{O_2}=n_{O_2}.22,4=0,6.22,4=13,44l\)
b.
\(n_P=\dfrac{m_P}{M_P}=\dfrac{3,1}{31}=0,1mol\)
\(4P+5O_2\rightarrow\left(t^o\right)2P_2O_5\)
0,1 0,05 ( mol )
\(m_{P_2O_5}=n_{P_2O_5}.M_{P_2O_5}=0,05.142=7,1g\)
\(a,m_C=48\left(g\right)\rightarrow n_C=\dfrac{m_C}{M_C}=\dfrac{48}{12}=4\left(mol\right)\)
\(V_{O_2}=44,8\left(l\right)\rightarrow n_{O_2}=\dfrac{V_{O_2}}{22,4}=\dfrac{44,8}{22,4}=2\left(mol\right)\)
\(PTHH:C+O_2\underrightarrow{t^o}CO_2\)
\(pt:\) \(1mol\) \(1mol\)
\(đb:\) \(4mol\) \(2mol\)
Xét tỉ lệ:
\(\dfrac{n_{C\left(đb\right)}}{n_{C\left(pt\right)}}=\dfrac{4}{1}=4>\dfrac{n_{O_2\left(đb\right)}}{n_{O_2\left(pt\right)}}=\dfrac{2}{1}=2\)
\(\Rightarrow\) \(O_2\) hết, \(C\) dư.
\(b,PTHH:C+O_2\underrightarrow{t^o}CO_2\)
\(pt:\) \(1mol\) \(1mol\)
\(đb:\) \(2mol\) \(2mol\)
\(\Rightarrow m_{CO_2}=n_{CO_2}.M_{CO_2}=2.\left(1.C+2.O\right)=2.\left(1.12+2.16\right)=88\left(g\right)\)
\(a.n_C=\dfrac{48}{12}=4\left(mol\right);n_{O_2}=\dfrac{44,8}{22,4}=2\left(mol\right)\\ C+O_2\xrightarrow[t^0]{}CO_2\)
Theo pt:\(\dfrac{4}{1}>\dfrac{2}{1}\Rightarrow C\) dư, O2 pư hết
\(b.C+O_2\xrightarrow[t^0]{}CO_2\\ \Rightarrow n_{CO_2}=n_{O_2}=2mol\\ m_{CO_2}=2.44=88\left(g\right)\)
Số mol khí CH4 là: nCH4= =2 mol
PTHH: CH4 + 2O2 CO2 + 2H2O
Tỉ lệ PT: 1mol 2mol
Phản ứng: 2mol → 4mol
=> thể tích khí oxi cần dùng là: VO2=22,4.n=22,4.4=89,6 lít
Đáp án cần chọn là: B
\(n_{CH_4}=\dfrac{32}{16}=2\left(mol\right)\)
PTHH: CH4 + 2O2 --to--> CO2 + 2H2O
2---->4
=> V = 4.22,4 = 89,6 (l)
=> B
\(n_{O_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\\a, 4P+5O_2\rightarrow\left(t^o\right)2P_2O_5\\b,n_{P_2O_5}=\dfrac{2}{5}.0,25=0,1\left(mol\right)\Rightarrow m_{P_2O_5}=142.0,1=14,2\left(g\right)\\c,V_{kk\left(đktc\right)}=4.5,6=28\left(lít\right) \)
\(n_{CH_4}=\dfrac{V_{CH_4}}{22,4}=\dfrac{5,6}{22,4}=0,25mol\)
\(CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\)
0,25 0,5 0,,25 0,5 ( mol )
\(V_{O_2}=n_{O_2}.22,4=0,5.22,4=11,2l\)
\(m_{CO_2}=n_{CO_2}.M_{CO_2}=0,25.44=11g\)
\(m_{H_2O}=n_{H_2O}.M_{H_2O}=0,5.18=9g\)
a.\(n_{KMnO_4}=\dfrac{m}{M}=\dfrac{31,6}{158}=0,2mol\)
\(2KMnO_4\rightarrow\left(t^o\right)K_2MnO_4+MnO_2+O_2\)
0,2 0,1 ( mol )
\(V_{O_2}=n.22,4=0,1.22,4=2,24l\)
b.\(n_{O_2}=0,1.60\%=0,06mol\)
\(2R+\dfrac{1}{2}nO_2\rightarrow\left(t^o\right)R_2O_n\)
\(\dfrac{2,16}{M_R}\) \(\dfrac{2,16n}{M_R}\) ( mol )
\(\Rightarrow\dfrac{2,16n}{M_R}=0,06\)
\(\Rightarrow0,06M_R=2,16n\)
\(\Rightarrow M_R=36n\)
Biện luận:
-n=1 => Loại
-n=2 => Loại
-n=3 => \(M_R=108\) ( g/mol ) R là Bạc ( Ag )
Vậy R là Bạc (Ag)
a, Theo giả thiết ta có: \(n_P=\dfrac{3,1}{31}=0,1\left(mol\right)\)
\(4P+5O_2--t^o->2P_2O_5\)
Ta có: \(n_{O_2}=\dfrac{5}{4}.n_P=0,125\left(mol\right)\Rightarrow V_{O_2\left(đktc\right)}=0,125.22,4=2,8\left(l\right)\)
b, Theo giả thiết ta có: \(n_{CH_4}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
\(CH_4+2O_2--t^o->CO_2+2H_2O\)
Ta có: \(n_{O_2}=2.n_{CH_4}=0,1\left(mol\right)\Rightarrow V_{O_2\left(đktc\right)}=2,24\left(l\right)\)