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a.\(n_{KMnO_4}=\dfrac{m_{KMnO_4}}{M_{KMnO_4}}=\dfrac{3,16}{158}=0,02mol\)
\(2KMnO_4\rightarrow\left(t^o\right)K_2MnO_4+MnO_2+O_2\)
0,02 0,01 ( mol )
\(V_{O_2}=n_{O_2}.22,4=0,01.22,4=0,224l\)
b.
\(4Al+3O_2\rightarrow\left(t^o\right)2Al_2O_3\)
1/75 0,01 1/150 ( mol )
\(m_{Al}=n_{Al}.M_{Al}=\dfrac{1}{75}.27=0,36g\)
\(m_{Al_2O_3}=n_{Al_2O_3}.M_{Al_2O_3}=\dfrac{1}{150}.102=0,68g\)
2KMnO4-to>K2MnO4+MnO2+O2
0,02-------------------------------------0,01
4Al+3O2-to->2Al2O3
\(\dfrac{1}{75}\)---0,01---------\(\dfrac{1}{150}\)
n KMnO4=\(\dfrac{3,16}{158}\)=0,02 mol
=>VO2=0,01.22,4=0,224 l
b)m Al=\(\dfrac{1}{75}\).27=0,36g
=>m Al2O3=\(\dfrac{1}{150}\)102=0,68g
a) -Theo bài ra, ta có:
nAl = (5,4)/27 = 0,2 (mol)
nO2 = (3360)/(1000.22,4) = 0,15 (mol)
PTPƯ: 4Al + 3O2 ---> 2Al2O3
-Theo PTPƯ, ta thấy: (nAl)/4 = (0,2)/4 = (nO2)/3 = (0,15)/3
=> Al và O2 đều phản ứng hết.
b) -Theo PTPƯ, ta có: nAl2O3 = 2/3 .nO2 = 2/3 .0,15 = 0,1 (mol)
=> mAl2O3 = 0,1.102 = 10,2 (g)
\(a,PTHH:4Al+3O_2\underrightarrow{t^o}2Al_2O_3\\ n_{Al}=\dfrac{m}{M}=\dfrac{10,8}{27}=0,4\left(mol\right)\\ Theo.PTHH:n_{Al_2O_3}=\dfrac{1}{2}.n_{Al}=\dfrac{1}{2}.0,4=0,2\left(mol\right)\\ m_{Al_2O_3}=n.M=0,2.102=20,4\left(g\right)\)
\(b,n_{O_2}=\dfrac{V_{\left(đktc\right)}}{22,4}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\\ Lập.tỉ.lệ:\dfrac{n_{Al}}{4}>\dfrac{n_{O_2}}{3}\Rightarrow Al.dư\\ Theo.PTHH:n_{Al\left(pư\right)}=\dfrac{4}{3}.n_{O_2}=\dfrac{4}{3}.0,2\left(mol\right)\\ n_{Al\left(dư\right)}=n_{Al\left(bđ\right)}-n_{Al\left(pư\right)}=0,4-0,2=0,2\left(mol\right)\\ Theo.PTHH:n_{Al_2O_3}=\dfrac{1}{2}.n_{Al}=\dfrac{1}{2}.0,2=0,1\left(mol\right)\\ m_{Al_2O_3}=n.M=0,1=102=10,2\left(g\right)\)
\(n_{Al}=\dfrac{m}{M}=\dfrac{5,4}{27}=0,2\left(mol\right)\\ PTHH:4Al+3O_2-^{t^o}>2Al_2O_3\)
tỉ lệ: 4 : 3 : 2
n(mol) 0,2---->0,15---->0,1
\(m_{Al_2O_3}=n\cdot M=0,1\cdot\left(27\cdot2+16\cdot3\right)=10,2\left(g\right)\\ V_{O_2\left(dktc\right)}=n\cdot22,4=0,15\cdot22,4=3,36\left(l\right)\)
câu d đề có thiếu ko ạ?
nAl=16,2/27= 0,6(mol)
a) PTHH: 4 Al +3 O2 -to-> 2 Al2O3
nO2= 3/4 . nAl=3/4 . 0,6= 0,45(mol)
=> V(O2,đktc)=0,45 x 22,4=10,08(l)
b) nAl2O3= nAl/2=0,6/2=0,3(mol)
=>mAl2O3=102. 0,3= 30,6(g)
c) 2KMnO4 -to-> K2MnO4 + MnO2 + O2
nKMnO4= 2.nO2=2. 0,45=0,9(mol)
=>mKMnO4= 158 x 0,9= 142,2(g)
Bài này anh giúp rồi mà em. Em không hiểu chỗ nào nhỉ?
\(n_{O_2}=\dfrac{33,6}{22,4}=1,5\left(mol\right)\)
PTHH: 4Al + 3O2 --to--> 2Al2O3
2<---1,5---------->1
=> \(m_{Al_2O_3}=1.102=102\left(g\right)\)
\(m_{Al}=2.27=54\left(g\right)\)
\(n_P=\dfrac{6,2}{31}=0,2\left(mol\right)\\ n_{O_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\\ PTHH:4P+5O_2\underrightarrow{t^o}2P_2O_5\\ LTL:\dfrac{0,2}{4}< \dfrac{0,4}{5}\Rightarrow O_2dư\)
\(n_{O_2\left(pư\right)}=\dfrac{5}{4}n_P=\dfrac{5}{4}.0,2=0,25\left(mol\right)\\ n_{O_2\left(dư\right)}=0,4-0,25=0,15\left(mol\right)\)
\(n_{P_2O_5\left(lt\right)}=\dfrac{1}{2}n_P=\dfrac{1}{2}.0,2=0,1\left(mol\right)\\ m_{P_2O_5\left(lt\right)}=0,1.142=14,2\left(g\right)\\ m_{P_2O_5\left(tt\right)}=0,1.142.80\%=11,36\left(g\right)\)
a.\(n_{Al_2O_3}=\dfrac{30,6}{102}=0,3mol\)
\(4Al+3O_2\rightarrow\left(t^o\right)2Al_2O_3\)
0,6 0,45 0,3 ( mol )
\(m_{Al}=0,6.27=16,2g\)
\(V_{O_2}=0,45.22,4=10,08l\)
\(V_{kk}=10,08.5=50,4l\)
b.\(2KClO_3\rightarrow\left(t^o,MnO_2\right)2KCl+3O_2\)
0,3 0,45 ( mol )
\(m_{KClO_3}=0,3.122,5=36,75g\)
c.\(2KClO_3\rightarrow\left(t^o,MnO_2\right)2KCl+3O_2\)
0,3 0,45 ( mol )
\(n_{KClO_3}=\dfrac{0,3}{75\%}=0,4mol\)
\(m_{KClO_3}=0,4.122,5=49g\)
\(n_{KMnO_4}=\dfrac{18.96}{158}=0.12\left(mol\right)\)
\(2KMnO_4\underrightarrow{t^0}K_2MnO_4+MnO_2+O_2\)
\(0.12...........................................0.06\)
\(V_{O_2}=0.06\cdot22.4=1.344\left(l\right)\)
\(n_{Al}=\dfrac{5.4}{27}=0.2\left(mol\right)\)
\(4Al+3O_2\underrightarrow{t^0}2Al_2O_3\)
\(0.08.....0.06.......0.04\)
\(m_{Al\left(dư\right)}=\left(0.2-0.08\right)\cdot27=3.24\left(g\right)\)
\(m_{Al_2O_3}=0.04\cdot102=4.08\left(g\right)\)