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\(n_P=\dfrac{3,1}{31}=0,1\left(mol\right)\)
\(n_{O_2}=\dfrac{4,48}{22,4}=0,2mol\)
4P + 5O2 \(\underrightarrow{t^o}\) 2P2O5
\(\dfrac{0,1}{4}< \dfrac{0,2}{5}\) => O2 dư, Photpho đủ
\(n_{O_2}=0,2-0,04=0,16\left(mol\right)\)
\(m_{P_2O_5}=\) 0,05 . 142 = 7,1 ( g )
a)
\(n_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
PTHH: \(2A+3H_2SO_4\rightarrow A_2\left(SO_4\right)_3+3H_2\)
=> \(n_A=0,4\left(mol\right)\)
=> \(M_A=\dfrac{10,8}{0,4}=27\left(g/mol\right)\)
=> A là Al
b) \(n_{Al_2\left(SO_4\right)_3}=0,2\left(mol\right)\)
=> \(m_{Al_2\left(SO_4\right)_3}=0,2.342=68,4\left(g\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
a: \(n_{Zn}=\dfrac{52}{65}=0.8\left(mol\right)\)
\(\Leftrightarrow n_{HCl}=1.6\left(mol\right)\)
hay \(n_{H_2}=0.8\left(mol\right)\)
\(V_{H_2}=0.8\cdot22.4=17.92\left(lít\right)\)
b: \(m_{ZnCl_2}=0.8\cdot136=108.8\left(g\right)\)
\(m_{H_2}=0.8\cdot2=1.6\left(g\right)\)
\(n_{Zn}=\dfrac{52}{65}=0,8\left(mol\right)\\ Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{ZnCl_2}=n_{H_2}=n_{Zn}=0,8\left(mol\right)\\ a,V_{H_2\left(đktc\right)}=0,8.22,4=17,92\left(l\right)\\ b,n_{HCl}=2.0,8=1,6\left(mol\right)\\ C1:m_{ZnCl_2}=0,8.136=108,8\left(g\right);m_{H_2}=0,8.2=1,6\left(g\right)\\ \Rightarrow m_{thu.được}=m_{ZnCl_2}+m_{H_2}=108,8+1,6=110,4\left(g\right)\\ C2:m_{HCl}=1,6.36,5=58,4\left(g\right)\\ \Rightarrow m_{thu.được}=m_{tham.gia}=m_{Zn}+m_{HCl}=52+58,4=110,4\left(g\right)\)
a, \(n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\)
\(m_{HCl}=36,5.15\%=5,475\left(g\right)\Rightarrow n_{HCl}=\dfrac{5,475}{36,5}=0,15\left(mol\right)\)
PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)
Xét tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,15}{2}\), ta được Mg dư.
Theo PT: \(n_{H_2}=\dfrac{1}{2}n_{HCl}=0,075\left(mol\right)\Rightarrow V_{H_2}=0,075.22,4=1,68\left(l\right)\)
b, \(n_{Mg\left(pư\right)}=\dfrac{1}{2}n_{HCl}=0,075\left(mol\right)\Rightarrow n_{Mg\left(dư\right)}=0,1-0,075=0,025\left(mol\right)\)
\(\Rightarrow m_{Mg\left(dư\right)}=0,025.24=0,6\left(g\right)\)
c, - Cách 1:
\(n_{MgCl_2}=\dfrac{1}{2}n_{HCl}=0,075\left(mol\right)\Rightarrow m_{MgCl_2}=0,075.95=7,125\left(g\right)\)
- Cách 2:
Theo ĐLBT KL, có: mMg (pư) + mHCl = mMgCl2 + mH2
⇒ mMgCl2 = 2,4 - 0,6 + 5,475 - 0,075.2 = 7,125 (g)
a) PTHH: 2Al + 6HCl -> 2AlCl3 + 3 H2
b) nHCl=0,6(mol); nAl=0,3(mol)
Ta có: 0,3/2 > 0,6/6
=> HCl hết, Al dư, tính theo nHCl
c) nH2= 3/6 . nHCl=3/6 . 0,6= 0,3(mol)
=> V=V(H2,đktc)=0,3.22,4= 6,72(l)
\(n_P=\dfrac{6,2}{31}=0,2\left(mol\right)\\ n_{O_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\\ PTHH:4P+5O_2\underrightarrow{t^o}2P_2O_5\\ LTL:\dfrac{0,2}{4}< \dfrac{0,4}{5}\Rightarrow O_2dư\)
\(n_{O_2\left(pư\right)}=\dfrac{5}{4}n_P=\dfrac{5}{4}.0,2=0,25\left(mol\right)\\ n_{O_2\left(dư\right)}=0,4-0,25=0,15\left(mol\right)\)
\(n_{P_2O_5\left(lt\right)}=\dfrac{1}{2}n_P=\dfrac{1}{2}.0,2=0,1\left(mol\right)\\ m_{P_2O_5\left(lt\right)}=0,1.142=14,2\left(g\right)\\ m_{P_2O_5\left(tt\right)}=0,1.142.80\%=11,36\left(g\right)\)
\(n_{Zn}=\dfrac{1,625}{65}=0,025mol\)
\(n_{HCl}=\dfrac{3,65}{36,5}=0,1mol\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,025 < 0,1 ( mol )
0,025 0,05 0,025 0,025 ( mol )
\(V_{H_2}=0,025.22,4=0,56l\)
Chất dư là HCl
\(m_{HCl\left(dư\right)}=\left(0,1-0,05\right).36,5=1,825g\)
\(m_{ZnCl_2}=0,025.136=3,4g\)
huhu cảm ơn bạn đề dài quá nên đưa lên đây làm giúp
nH2 = 0,336/22,4 = 0,015 (mol)
PTHH: 2A + 6HCl -> 2ACl3 + 3H2
nACl3 = nA = 0,015 : 3 . 2 = 0,01 (mol)
M(A) = 0,27/0,01 = 27 (g/mol)
=> A là Al
mAlCl3 = 0,01 . 133,5 = 1,335 (g)
Câu 6.
\(n_{H_2}=\dfrac{0,336}{22,4}=0,015mol\)
\(2A+6HCl\rightarrow2ACl_3+3H_2\)
0,01 0,015
\(\overline{M_A}=\dfrac{0,27}{0,01}=27đvC\)
\(\Rightarrow A\) là Al nhôm.
\(m_{AlCl_3}=0,01\cdot133,5=1,335g\)