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a) \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
_____0,2-->0,6----->0,2---->0,3
=> \(C_{M\left(HCl\right)}=\dfrac{0,6}{0,2}=3M\)
b) VH2 = 0,3.24,79 = 7,437 (l)
c) \(C_{M\left(AlCl_3\right)}=\dfrac{0,2}{0,2}=1M\)
a) \(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\left(1dm^3=1l\right)\)
PTHH: 2Al + 3H2SO4 → Al2(SO4)3 + 3H2
Mol: x 1,5x
PTHH: Mg + H2SO4 → MgSO4 + H2
Mol: y y
Ta có: \(\left\{{}\begin{matrix}27x+24y=7,8\\1,5x+y=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\)
\(\%m_{Al}=\dfrac{0,2.27.100\%}{7,8}=69,23\%;\%m_{Mg}=100-69,23=30,77\%\)
b)
PTHH: 2Al + 3H2SO4 → Al2(SO4)3 + 3H2
Mol: 0,2 0,3 0,1
PTHH: Mg + H2SO4 → MgSO4 + H2
Mol: 0,1 0,1 0,1
\(V_{ddH_2SO_4}=\dfrac{0,3+0,1}{2}=0,2\left(l\right)=200\left(ml\right)\)
\(\Rightarrow m_{ddH_2SO_4}=1,12.200=224\left(g\right)\)
c) \(C_{M_{ddAl_2\left(SO_4\right)_3}}=\dfrac{0,1}{0,2}=0,5M\)
\(C_{M_{ddMgSO_4}}=\dfrac{0,1}{0,2}=0,5M\)
\(n_{Fe}=\dfrac{11.2}{56}=0.2\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(0.2.......0.4........0.2.......0.2\)
\(V_{H_2}=0.2\cdot22.4=4.48\left(l\right)\)
\(V_{dd_{HCl}}=\dfrac{0.4}{0.2}=2\left(l\right)\)
\(C_{M_{FeCl_2}}=\dfrac{0.2}{2}=0.1\left(M\right)\)
a)
$Fe + 2HCl \to FeCl_2 + H_2$
$n_{H_2} = n_{Fe} = \dfrac{11,2}{56} = 0,2(mol)$
$V_{H_2} = 0,2.22,4 = 4,48(lít)$
b)
$n_{HCl} = 2n_{Fe} = 0,4(mol)$
$V_{dd\ HCl} = \dfrac{0,4}{0,2} = 2(lít) = 2000(ml)$
c)
$n_{FeCl_2} = n_{Fe} = 0,2(mol)$
$\Rightarrow C_{M_{FeCl_2}} = \dfrac{0,2}{2} = 0,1M$
\(a.n_{H_2}=\dfrac{6,72}{22,4}=0,3mol\\ 2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
0,2 0,3 0,1 0,3
\(m_{Al}=0,2.27=5,4g\\ b.C_{M\left(H_2SO_4\right)}=\dfrac{0,3}{0,45}=\dfrac{2}{3}M\\ c.2H_2+O_2\underrightarrow{t^0}2H_2O\)
0,3 0,15 0,3
\(V_{O_2}=0,15.22,4=3,36l\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ n_{Al}=\dfrac{2}{3}n_{H_2}=\dfrac{2}{3}.0,3=0,2\left(mol\right)\\ a,m_{Al}=0,2.27=5,4\left(g\right)\\ n_{H_2SO_4}=n_{H_2}=0,3\left(mol\right)\\ b,C_{MddH_2SO_4}=\dfrac{0,3}{0,45}=\dfrac{2}{3}\left(M\right)\\ 2H_2+O_2\rightarrow\left(t^o\right)2H_2O\\ n_{O_2}=\dfrac{n_{H_2}}{2}=\dfrac{0,3}{2}=0,15\left(mol\right)\\ c,V_{O_2\left(đktc\right)}=0,15.22,4=3,36\left(l\right)\)
a.Mg + H2SO4 -> MgSO4 + H2
b.\(nH2=\dfrac{4.704}{22.4}=0.21mol\) = nMg
mMg = 0.21\(\times24=5.04g\)
\(\%mMg=\dfrac{5.04\times100}{25}=20.16\%\)
\(\%mAg=100-20.16=79.84\%\)
c.MgSO4 + 2KOH -> K2SO4 + Mg(OH)2
0.21 0.42
H2SO4 + 2KOH -> K2SO4 + H2O
0.04 0.08
\(nH2SO4=\dfrac{9.8\times250}{100\times98}=0.25mol\)
Mà nH2SO4 phản ứng = nH2 = 0.21 mol
\(\Rightarrow nH2SO4dư=0.25-0.21=0.04mol\)
=> nKOH = 0.42 + 0.08 = 0.5mol
\(\Rightarrow CM_{KOH}=\dfrac{0.5}{0.625}=0.8M\)
\(a,n_{H_2SO_4}=0,5\cdot0,1=0,05\left(mol\right)\\ PTHH:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ \Rightarrow n_{H_2}=n_{H_2SO_4}=0,05\left(mol\right)\\ \Rightarrow V_{H_2\left(đktc\right)}=0,05\cdot22,4=1,12\left(l\right)\\ b,n_{Al}=\dfrac{2}{3}n_{H_2SO_4}=\dfrac{1}{30}\left(mol\right)\\ \Rightarrow m_{Al}=\dfrac{1}{30}\cdot27=0,9\left(g\right)\\ c,n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{3}n_{H_2SO_4}\approx0,017\left(mol\right)\\ \Rightarrow C_{M_{Al_2\left(SO_4\right)_3}}=\dfrac{0,017}{0,1}\approx0,17M\)
\(n_{Al}=\frac{2,7}{27}=0,1\left(mol\right)\)
\(n_{Al_2O_3}=\frac{5,1}{102}=0,05\left(mol\right)\)
2Al + 3H2SO4 → Al2(SO4)3 + 3H2 (1)
Al2O3 + 3H2SO4 → Al2(SO4)3 + 3H2O (2)
a) Theo PT1: \(n_{H_2}=\frac{3}{2}n_{Al}=\frac{3}{2}\times0,1=0,15\left(mol\right)\)
\(\Rightarrow V=V_{H_2}=0,15\times22,4=3,36\left(l\right)\)
b) Theo Pt1: \(n_{H_2SO_4}=n_{H_2}=0,15\left(mol\right)\)
Theo pT2: \(n_{H_2SO_4}=3n_{Al_2O_3}=3\times0,05=0,15\left(mol\right)\)
\(\Rightarrow\Sigma n_{H_2SO_4}=0,15+0,15=0,3\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4}=0,3\times98=29,4\left(g\right)\)
\(\Rightarrow m_{ddH_2SO_4}=\frac{29,4}{9,8\%}=300\left(g\right)\)
\(\Rightarrow V_{ddH_2SO_4}=\frac{300}{1,12}=267,86\left(ml\right)=0,26786\left(l\right)\)
c) Ta có: \(m_{ddY}=2,7+5,1+300=307,8\left(g\right)\)
Theo PT1: \(n_{Al_2\left(SO_4\right)_3}=\frac{1}{2}n_{Al}=\frac{1}{2}\times0,1=0,05\left(mol\right)\)
Theo Pt2: \(n_{Al_2\left(SO_4\right)_3}=n_{Al_2O_3}=0,05\left(mol\right)\)
\(\Rightarrow\Sigma n_{Al_2\left(SO_4\right)_3}=0,05+0,05=0,1\left(mol\right)\)
\(\Rightarrow m_{Al_2\left(SO_4\right)_3}=0,1\times342=34,2\left(g\right)\)
\(\Rightarrow C_{M_{Al_2\left(SO_4\right)_3}}=\frac{0,1}{0,26786}=0,373\left(M\right)\)
\(C\%_{Al_2\left(SO_4\right)_3}=\frac{34,2}{307,8}\times100\%=11,11\%\)