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2Al+ 3H2SO4→ Al2(SO4)3+ 3H2
(mol) 0,1 0,15 0,05 0,15
đổi: 300ml=0,3 lít
a) nAl=\(\dfrac{m}{M}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
\(n_{H_2SO_4}=C_M.V=0,5.0,3=0,15\left(mol\right)\)
tỉ lệ:
Al H2SO4
\(\dfrac{0,2}{2}\) > \(\dfrac{0,15}{3}\)
→ Al dư, H2SO4 phản ứng hết sau phản ứng
→ \(V_{H_2}=n.22,4=0,15.22,4=3,36\left(lít\right)\)
b) \(n_{Al\left(dư\right)}=n_{Al\left(bđ\right)}-n_{Al\left(ph.ứ\right)}=0,2-0,1=0,1\left(mol\right)\)
\(C_{M_{Al\left(dư\right)}}=\dfrac{n}{V}=\dfrac{0,1}{0,3}=\dfrac{1}{3}M\)
\(C_{M_{Al_2\left(SO_4\right)_3}}=\dfrac{n}{V}=\dfrac{0,05}{0,3}=\dfrac{1}{6}M\)
\(C_{M_{H_2}}=\dfrac{n}{V}=\dfrac{0,15}{0,3}=0,05M\)
\(n_{Al}=\dfrac{21,6}{27}=0,8\left(mol\right)\)
Pt : \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2O|\)
2 3 1 3
0,8 1,2 0,4 1,2
a) \(n_{H2}=\dfrac{0,8.3}{2}=1,2\left(mol\right)\)
\(V_{H2\left(dktc\right)}=1,2.22,4=26,88\left(l\right)\)
b) \(n_{H2SO4}=\dfrac{0,8.3}{2}=1,2\left(mol\right)\)
⇒ \(m_{H2SO4}=1,2.98=117,6\left(g\right)\)
\(m_{ddH2SO4}=\dfrac{117,6.100}{29,4}=400\left(g\right)\)
c) \(n_{Al2\left(SO4\right)3}=\dfrac{1,2.1}{3}=0,4\left(mol\right)\)
⇒ \(m_{Al2\left(SO4\right)3}=0,4.342=136,8\left(g\right)\)
\(m_{ddspu}=21,6+400-\left(1,2.2\right)=419,2\left(g\right)\)
\(C_{Al2\left(SO4\right)3}=\dfrac{136,8.100}{419,2}=32,63\)0/0
Chúc bạn học tốt
a) \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
_____0,2-->0,6----->0,2---->0,3
=> \(C_{M\left(HCl\right)}=\dfrac{0,6}{0,2}=3M\)
b) VH2 = 0,3.24,79 = 7,437 (l)
c) \(C_{M\left(AlCl_3\right)}=\dfrac{0,2}{0,2}=1M\)
a)
$n_{Al} = \dfrac{5,4}{27} = 0,2(mol)$
$2Al + 3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2$
Theo PTHH:
$n_{H_2SO_4} = n_{H_2} = \dfrac{3}{2}n_{Al} = 0,3(mol)$
$V_{dd\ H_2SO_4} = \dfrac{0,3}{2} = 0,15(lít)$
$n_{Al_2(SO_4)_3} = \dfrac{1}{2}n_{Al} = 0,1(mol)$
$C_{M_{Al_2(SO_4)_3}} = \dfrac{0,1}{0,15} = 0,67M$
b)
$V_{H_2} = 0,3.22,4 = 6,72(lít)$
Bài 3 :
\(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\)
Pt : \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2|\)
2 3 1 3
0,1 0,15 0,05 0,15
a) \(n_{H2}=\dfrac{0,1.3}{2}=0,15\left(mol\right)\)
\(m_{H2}=0,15.2=0,3\left(g\right)\)
\(V_{H2\left(dktc\right)}=0,15.22,4=3,36\left(l\right)\)
b) \(n_{H2SO4}=\dfrac{0,1.3}{2}=0,15\left(mol\right)\)
⇒ \(m=0,15.98=14,7\left(g\right)\)
\(C_{ddH2SO4}=\dfrac{14,7.100}{200}=7,35\)0/0
c) \(n_{Al2\left(SO4\right)3}=\dfrac{0,15.1}{3}=0,05\left(mol\right)\)
⇒ \(m_{Al2\left(SO4\right)3}=0,05.342=17,1\left(g\right)\)
\(m_{ddspu}=2,7+200-0,3=302,4\left(g\right)\)
\(C_{Al2\left(SO4\right)3}=\dfrac{17,1.100}{302,4}=5,65\)0/0
Chúc bạn học tốt
Mình xin lỗi bạn nhé , bạn sửa lại giúp mình :
\(m_{ddspu}=2,7+200-0,3=202,4\left(g\right)\)
\(C_{Al2\left(SO4\right)3}=\dfrac{17,1.100}{202,4}=8,45\)0/0
a,\(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\)
PTHH: 2Al + 3H2SO4 → Al2(SO4)3 + 3H2
Mol: 0,1 0,15 0,05 0,15
\(m_{H_2}=0,15.2=0,3\left(g\right)\)
\(V_{H_2}=0,15.24,79=3,7185\left(l\right)\)
b, \(m_{ddH_2SO_4}=\dfrac{0,15.98.100\%}{200}=7,35\%\)
c, mdd sau pứ = 2,7 + 200 - 0,3 = 202,4 (g)
\(C\%_{ddAl_2\left(SO_4\right)_3}=\dfrac{0,05.342.100\%}{202,4}=8,45\%\)
\(a.n_{H_2}=\dfrac{6,72}{22,4}=0,3mol\\ 2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
0,2 0,3 0,1 0,3
\(m_{Al}=0,2.27=5,4g\\ b.C_{M\left(H_2SO_4\right)}=\dfrac{0,3}{0,45}=\dfrac{2}{3}M\\ c.2H_2+O_2\underrightarrow{t^0}2H_2O\)
0,3 0,15 0,3
\(V_{O_2}=0,15.22,4=3,36l\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ n_{Al}=\dfrac{2}{3}n_{H_2}=\dfrac{2}{3}.0,3=0,2\left(mol\right)\\ a,m_{Al}=0,2.27=5,4\left(g\right)\\ n_{H_2SO_4}=n_{H_2}=0,3\left(mol\right)\\ b,C_{MddH_2SO_4}=\dfrac{0,3}{0,45}=\dfrac{2}{3}\left(M\right)\\ 2H_2+O_2\rightarrow\left(t^o\right)2H_2O\\ n_{O_2}=\dfrac{n_{H_2}}{2}=\dfrac{0,3}{2}=0,15\left(mol\right)\\ c,V_{O_2\left(đktc\right)}=0,15.22,4=3,36\left(l\right)\)
Bài 1 :
\(n_{Zn}=\dfrac{13}{65}=0.2\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(0.2........0.4....................0.2\)
\(V_{dd_{HCl}}=\dfrac{0.4}{0.5}=0.8\left(l\right)\)
\(V_{H_2}=0.2\cdot22.4=4.48\left(l\right)\)
Bài 2 :
\(n_{Al}=\dfrac{5.4}{27}=0.2\left(mol\right)\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(0.2..........0.3.............................0.3\)
\(m_{H_2SO_4}=0.3\cdot98=29.4\left(g\right)\)
\(m_{dd_{H_2SO_4}}=\dfrac{29.4\cdot100}{10}=294\left(g\right)\)
\(V_{H_2}=0.3\cdot22.4=6.72\left(l\right)\)
\(a,n_{H_2SO_4}=0,5\cdot0,1=0,05\left(mol\right)\\ PTHH:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ \Rightarrow n_{H_2}=n_{H_2SO_4}=0,05\left(mol\right)\\ \Rightarrow V_{H_2\left(đktc\right)}=0,05\cdot22,4=1,12\left(l\right)\\ b,n_{Al}=\dfrac{2}{3}n_{H_2SO_4}=\dfrac{1}{30}\left(mol\right)\\ \Rightarrow m_{Al}=\dfrac{1}{30}\cdot27=0,9\left(g\right)\\ c,n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{3}n_{H_2SO_4}\approx0,017\left(mol\right)\\ \Rightarrow C_{M_{Al_2\left(SO_4\right)_3}}=\dfrac{0,017}{0,1}\approx0,17M\)