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PTHH: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\)
\(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
a+b) Ta có: \(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)=n_{H_2SO_4}=n_{ZnSO_4}\)
\(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,3}{0,2}=1,5\left(M\right)=C_{M_{ZnSO_4}}\)
c) Theo PTHH: \(n_{H_2}=n_{Zn}=0,3mol\) \(\Rightarrow V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\)
d) Theo PTHH: \(n_{Fe}=\dfrac{2}{3}n_{H_2}=0,2mol\)
\(\Rightarrow m_{Fe}=0,2\cdot56=11,2\left(g\right)\)
\(n_{Fe_2O_3}=\dfrac{8}{160}=0,05\left(mol\right)\)
PTHH: Fe2O3 + 3H2SO4 --> Fe2(SO4)3 + 3H2O
______0,05------>0,15--------->0,05
=> mH2SO4 = 0,15.98 = 14,7(g)
=> \(C\%\left(H_2SO_4\right)=\dfrac{14,7}{100}.100\%=14,7\%\)
\(C\%\left(Fe_2\left(SO_4\right)_3\right)=\dfrac{0,05.400}{8+100}.100\%=18,52\%\)
PTHH: Fe2(SO4)3 + 6NaOH --> 2Fe(OH)3\(\downarrow\) + 3Na2SO4
________0,05----------------------->0,1
=> mFe(OH)3 = 0,1.107=10,7(g)
a) FeO + 2 HCl -> FeCl2 + H2O
FeCl2 + 2 NaOH -> Fe(OH)2 (kết tủa) + 2 NaCl
m(rắn)=m(kt)=mFe(OH)2=24(g)
=> nFe(OH)2= 24/90= 8/45 (mol)
=> nFeO=nFeCl2=nFe(OH)2= 8/45(mol)
=>m=mFeO=8/45 . 72=12,8(g)
nHCl=2.nFeCl2=2.nFe(OH)2=2. 8/45 = 16/45(mol)
-> VddHCl= (16/45)/ 1= 16/45 (l)= 355,556(ml)
\(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\\ n_{H_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\\ n_{Zn}=n_{H_2SO_4}=n_{H_2}=0,05\left(mol\right)\\ m_{Zn}=0,05.65=3,25\left(g\right)\\ m_{\text{dd}H_2SO_4}=\dfrac{0,05.98}{19,6\%}=25\left(g\right)\\ V_{\text{dd}H_2SO_4}=\dfrac{25}{1,84}\approx13,587\left(ml\right)\)
Ta có: \(n_{Fe_2O_3}=\dfrac{9,6}{160}=0,06\left(mol\right)\)
a. PTHH: Fe2O3 + 3H2SO4 ---> Fe2(SO4)3 + 3H2O (1)
Theo PT(1): \(n_{H_2SO_4}=3.n_{Fe_2O_3}=3.0,06=0,18\left(mol\right)\)
=> \(m_{H_2SO_4}=0,18.98=17,64\left(g\right)\)
Ta có: \(C_{\%_{H_2SO_4}}=\dfrac{17,64}{m_{dd_{H_2SO_4}}}.100\%=9,8\%\)
=> \(m_{dd_{H_2SO_4}}=180\left(g\right)\)
b. Ta có: \(m_{dd_{Fe_2\left(SO_4\right)_3}}=9,6+180=189,6\left(g\right)\)
Theo PT(1): \(n_{Fe_2\left(SO_4\right)_3}=n_{Fe_2O_3}=0,06\left(mol\right)\)
=> \(m_{Fe_2\left(SO_4\right)_3}=0,06.400=24\left(g\right)\)
=> \(C_{\%_{Fe_2\left(SO_4\right)_3}}=\dfrac{24}{189,6}.100\%=12,66\%\)
c. PTHH: Fe2(SO4)3 + 3BaCl2 ---> 3BaSO4↓ + 2FeCl3 (2)
Theo PT(2): \(n_{BaSO_4}=3.n_{Fe_2\left(SO_4\right)_3}=3.0,06=0,18\left(mol\right)\)
=> \(m_{BaSO_4}=0,18.233=41,94\left(g\right)\)
Theo PT(2): \(n_{BaCl_2}=n_{BaSO_4}=0,18\left(mol\right)\)
=> \(m_{BaCl_2}=0,18.208=37,44\left(g\right)\)
Ta có: \(C_{\%_{BaCl_2}}=\dfrac{37,44}{m_{dd_{BaCl_2}}}.100\%=10,4\%\)
=> \(m_{dd_{BaCl_2}}=360\left(g\right)\)
\(m_{ct}=\dfrac{20.98}{100}=19,6\left(g\right)\)
\(n_{H2SO4}=\dfrac{19,6}{98}=0,2\left(mol\right)\)
Pt : \(CuO+H_2SO_4\rightarrow CuSO_4+H_2O|\)
1 1 1 1
0,2 0,2 0,2
a) \(n_{CuO}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
⇒ \(m_{CuO}=0,2.80=16\left(g\right)\)
b) \(n_{CuSO4}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
⇒ \(m_{CuSO4}=0,2.160=32\left(g\right)\)
c) \(m_{ddspu}=16+98=114\left(g\right)\)
\(C_{CuSO4}=\dfrac{32.100}{114}=28,7\)0/0
Chúc bạn học tốt
PTHH: \(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
Ta có: \(n_{Fe_2O_3}=\dfrac{4,8}{160}=0,03\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{H_2SO_4}=0,09\left(mol\right)\\n_{Fe_2\left(SO_4\right)_3}=0,03\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{ddH_2SO_4}=\dfrac{0,09\cdot98}{9,8\%}=90\left(g\right)\\m_{Fe_2\left(SO_4\right)_3}=0,03\cdot400=12\left(g\right)\end{matrix}\right.\)
a,
Fe2O3+ 3H2SO4 \(\rightarrow\) Fe2(SO4)3+ 3H2O
Fe2(SO4)3+ 3BaCl2 \(\rightarrow\)3BaSO4+ 2FeCl3
b,
nBaSO4= \(\frac{34,95}{233}\)= 0,15 mol
\(\rightarrow\) nFe2O3= nFe2(SO4)3= \(\frac{0,15}{3}\)= 0,05 mol
nH2SO4= 0,05.3= 0,15 mol
mFe2O3= 0,05.160= 8g
m dd H2SO4=\(\frac{\text{0,15.98.100}}{19,6}\)= 75g