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a. PTHH:
\(Ca+2H_2O--->Ca\left(OH\right)_2+H_2\left(1\right)\)
\(CaO+H_2O--->Ca\left(OH\right)_2\left(2\right)\)
b. Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Theo PT(1): \(n_{Ca}=n_{H_2}=0,1\left(mol\right)\)
\(\Rightarrow m_{Ca}=0,1.40=4\left(g\right)\)
\(\Rightarrow\%_{m_{Ca}}=\dfrac{4}{9,6}.100\%=41,7\%\)
\(\%_{m_{CaO}}=100\%-41,7\%=58,3\%\)
c. Ta có: \(n_{CaO}=\dfrac{9,6-4}{56}=0,1\left(mol\right)\)
Ta có: \(n_{hh}=0,1+0,1=0,2\left(mol\right)\)
Theo PT(1,2): \(n_{Ca\left(OH\right)_2}=n_{hh}=0,2\left(mol\right)\)
\(\Rightarrow m_{Ca\left(OH\right)_2}=0,2.74=14,8\left(g\right)\)
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
PTHH:
Ca + 2H2O ---> Ca(OH)2 + H2
0,1<-------------0,1<---------0,1
=> \(\left\{{}\begin{matrix}m_{Ca}=0,1.40=4\left(g\right)\\m_{CaO}=9,6-4=5,6\left(g\right)\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}\%m_{Ca}=\dfrac{4}{9,6}.100\%=41,67\%\\\%m_{CaO}=100\%-41,67\%=58,33\%\end{matrix}\right.\)
\(n_{CaO}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PTHH: CaO + H2O ---> Ca(OH)2
0,1------------------>0,1
=> \(m_{Ca\left(OH\right)_2}=\left(0,1+0,1\right).74=14,8\left(g\right)\)
Bài 14:
a) \(n_{H_2}=\dfrac{12,395}{24,79}=0,5\left(mol\right)\)
PTHH: Ca + 2H2O --> Ca(OH)2 + H2
0,5<--------------0,5<----0,5
=> mCa = 0,5.40 = 20 (g)
=> \(\left\{{}\begin{matrix}\%m_{Ca}=\dfrac{20}{34}.100\%=58,82\%\\\%m_{CaO}=100\%-58,82\%=41,18\%\end{matrix}\right.\)
b) b phải là khối lượng bazo thu được chứ nhỉ..., sao tính đc m dung dịch
\(n_{CaO}=\dfrac{34-20}{56}=0,25\left(mol\right)\)
PTHH: CaO + H2O --> Ca(OH)2
0,25---------->0,25
=> mCa(OH)2 = (0,5 + 0,25).74 = 55,5 (g)
\(n_{H_2}=\dfrac{12,395}{24,79}=0,5\left(mol\right)\)
\(Ca+2H_2O\rightarrow Ca\left(OH\right)_2+H_2\)
0,5 0,5 0,5 ( mol )
( \(CaO+H_2O\) không giải phóng \(H_2\) )
\(m_{Ca}=0,5.40=20g\)
\(\rightarrow\left\{{}\begin{matrix}\%m_{Ca}=\dfrac{20}{34}.100=58,82\%\\\%m_{CaO}=100\%-58,82\%=41,18\%\end{matrix}\right.\)
\(n_{CaO}=\dfrac{34-20}{56}=0,25\left(mol\right)\)
\(CaO+H_2O\rightarrow Ca\left(OH\right)_2\)
0,25 0,25 ( mol )
\(m_{Ca\left(OH\right)_2}=\left(0,5+0,25\right).74=55,5g\)
PTHH: \(Na+H_2O\rightarrow NaOH+\dfrac{1}{2}H_2\uparrow\)
\(Na_2O+H_2O\rightarrow2NaOH\)
Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\) \(\Rightarrow n_{Na}=0,6\left(mol\right)\)
\(\Rightarrow\%m_{Na}=\dfrac{0,6\cdot23}{26,2}\cdot100\%\approx52,67\left(g\right)\) \(\Rightarrow\%m_{Na_2O}=47,33\%\)
Mặt khác: \(n_{Na_2O}=\dfrac{26,2-0,6\cdot23}{62}=0,2\left(mol\right)\)
Theo PTHH: \(n_{NaOH}=n_{Na}+2n_{Na_2O}=1\left(mol\right)\) \(\Rightarrow m_{NaOH}=1\cdot40=40\left(g\right)\)