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2Na + 2H2O ---> 2NaOH + H2 (1)
Na2O + H2O ---> 2NaOH (2)
a) nH2 = 0,3 (mol)
Theo pthh (1) : nNa = 2nH2 = 0,6 (mol)
=> mNa = 0,6.23 = 13,8 (g)
=> mNa2O = 26,2 - 13,8 = 12,4 (g)
=> nNa2O = 0,2 (mol)
BTNa : nNaOH = nNa + 2nNa2O = 0,6 + 2.0,2 = 1 (mol)
=> mNaOH = 1.40 = 40(g)
b) %mNa = 13,8.100%/26,2 = 52,67%
%mNa2O = 100% - 52,67% = 47,33%
\(2Na+2H_2O\rightarrow2NaOH+H_2\\ Na_2O+H_2O\rightarrow2NaOH\\ n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ n_{Na}=2.0,3=0,6\left(mol\right)\\ a,m_{Na}=0,6.23=13,8\left(g\right)\\ m_{Na_2O}=26,2-13,8=12,4\left(g\right)\\b, n_{Na_2O}=\dfrac{12,4}{62}=0,2\left(mol\right)\\ n_{NaOH\left(tổng\right)}=n_{Na}+2.n_{Na_2O}=0,6+\dfrac{12,4}{62}=0,8\left(mol\right)\\ m_{c.tan}=m_{NaOH}=0,8.40=32\left(g\right)\\ c,m_{ddNaOH}=m_{hh}+m_{H_2O}-m_{H_2}=26,2+200-0,3.2=225,6\left(g\right)\\ C\%_{ddNaOH}=\dfrac{32}{225,6}.100\approx14,185\%\)
a. PTHH:
\(Ca+2H_2O--->Ca\left(OH\right)_2+H_2\left(1\right)\)
\(CaO+H_2O--->Ca\left(OH\right)_2\left(2\right)\)
b. Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Theo PT(1): \(n_{Ca}=n_{H_2}=0,1\left(mol\right)\)
\(\Rightarrow m_{Ca}=0,1.40=4\left(g\right)\)
\(\Rightarrow\%_{m_{Ca}}=\dfrac{4}{9,6}.100\%=41,7\%\)
\(\%_{m_{CaO}}=100\%-41,7\%=58,3\%\)
c. Ta có: \(n_{CaO}=\dfrac{9,6-4}{56}=0,1\left(mol\right)\)
Ta có: \(n_{hh}=0,1+0,1=0,2\left(mol\right)\)
Theo PT(1,2): \(n_{Ca\left(OH\right)_2}=n_{hh}=0,2\left(mol\right)\)
\(\Rightarrow m_{Ca\left(OH\right)_2}=0,2.74=14,8\left(g\right)\)
\(a,n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
PTHH: Ba + 2H2O ---> Ba(OH)2 + H2
0,3<-------------0,3<---------0,3
=> mBa = 0,3.137 = 41,1 (g)
=> mK2O = 59,9 - 41,1 = 18,8 (g)
\(\rightarrow\left\{{}\begin{matrix}\%m_{Ba}=\dfrac{41,1}{59,9}.100\%=68,61\%\\\%m_{K_2O}=100\%-68,61\%=31,39\%\end{matrix}\right.\)
\(b,n_{K_2O}=\dfrac{18,8}{94}=0,2\left(mol\right)\)
PTHH: K2O + H2O ---> 2KOH
0,2----------------->0,4
Các chất tan trong dd sau phản ứng: KOH, Ba(OH)2
\(\rightarrow\left\{{}\begin{matrix}m_{KOH}=0,4.56=22,4\left(g\right)\\m_{Ba\left(OH\right)_2}=0,3.171=51,3\left(g\right)\end{matrix}\right.\)
a, PTHH : 2K + 2H2O -> 2KOH + H2 (1)
2Na + 2H2O -> 2NaOH + H2 (2)
Khí A là H2
Dung dịch B : KOH , NaOH
mNa =8,5 . 54,12% = 4,6 (g) -(chỗ này có làm tròn xíu lát tính cho dễ )
=>nNa=4,6 /23 = 0,2(mol)
Theo (2) nH2= 1/2 nNa = 0,1 (mol)
Theo (2), nNaOH= nNa = 0,2 (mol)=> mNaOH= 0,2 . 40 = 8(g)
=> mK = 8,5 - 4,6= 3,9 (g)
=>nK = 3,9 / 39 = 0,1 (mol)
Theo (1) , nH2= 1/2 nK = 0,05 (mol)
Theo (1) ,n KOH= nK = 0,1 (mol)=> mKOH = 0,1 . 56=5,6 (g)
\(\Sigma\)nH2= 0,1 + 0,05 = 0,15 (mol)=> VA= 3,36 (l)
a) mNa=4,6g;mK=3,9g ( cái này bạn bik)
pt:\(2Na+2H_2O->2NaOH+H_2\uparrow\)
0,2 ---------------------> 0,2--------->0,1 (mol)
\(2K+2H_2O->2KOH+H_2\uparrow\)
01,------------------->0,1-------------->0,05 ( mol)
VH2= (0,1+0,05).22,4=3,36lit
mNaOH=0,2.40=8g
mKOH=0,156=5,6g
b làm tương tự câu a
Chất không tan là Ag.
=> mAg= 6,25(g)
nH2=0,25(mol)
PTHH: Zn + H2SO4 -> ZnSO4 + H2
-> nZn=nH2= 0,25(mol)
=>mZn= 0,25 . 65=16,25(g)
=> \(\%mAg=\dfrac{6,25}{6,25+16,25}.100\approx27,778\%\\ \Rightarrow\%mZn\approx72,222\%\)
PTHH: \(Na+H_2O\rightarrow NaOH+\dfrac{1}{2}H_2\uparrow\)
\(Na_2O+H_2O\rightarrow2NaOH\)
Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\) \(\Rightarrow n_{Na}=0,6\left(mol\right)\)
\(\Rightarrow\%m_{Na}=\dfrac{0,6\cdot23}{26,2}\cdot100\%\approx52,67\left(g\right)\) \(\Rightarrow\%m_{Na_2O}=47,33\%\)
Mặt khác: \(n_{Na_2O}=\dfrac{26,2-0,6\cdot23}{62}=0,2\left(mol\right)\)
Theo PTHH: \(n_{NaOH}=n_{Na}+2n_{Na_2O}=1\left(mol\right)\) \(\Rightarrow m_{NaOH}=1\cdot40=40\left(g\right)\)