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a)
$CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O$
b) Theo PTHH : $V_{O_2} = 2V_{CH_4} = 11,2(lít)$
$n_{CH_4} = \dfrac{5,6}{22,4} = 0,25(mol)$
Theo PTHH : $n_{H_2O} = 2n_{CH_4} = 0,5(mol)$
$m_{H_2O} = 0,5.18 = 9(gam)$
nK=0,2(mol)
PTHH: 4K + O2 -to-> 2 K2O
nK2O= 0,1(mol) => mK2O=0,1.94=9,4(g)
nO2=0,05(mol) -> V(O2,đktc)=0,05.22,4=1,12(l)
V(kk,dktc)=5.V(O2,dktc)=5.1,12=5,6(l)
\(n_{Fe_3O_4}=\dfrac{m_{Fe_3O_4}}{M_{Fe_3O_4}}=\dfrac{23,2}{232}=0,1mol\)
\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)
0,3 0,2 0,1 ( mol )
\(m_{Fe}=n_{Fe}.M_{Fe}=0,3.56=16,8g\)
\(V_{O_2}=n_{O_2}.22,4=0,2.22,4=4,48l\)
\(V_{kk}=\dfrac{4,48.100}{20}=22,4l\)
\(2KMnO_4\rightarrow\left(t^o\right)K_2MnO_4+MnO_2+O_2\)
0,4 0,2 ( mol )
\(n_{KMnO_4}=\dfrac{0,4}{85\%}=\dfrac{8}{17}mol\)
\(m_{KMnO_4}=n_{KMnO_4}.M_{KMnO_4}=\dfrac{8}{17}.158=74,3529g\)
\(a,CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\)
Vì n và V tỉ lệ thuận với nhau. Nên ta có:
\(V_{O_2}=2.V_{CH_4}=2.2,768=5,536\left(l\right)\)
\(b,V_{kk}=\dfrac{100}{21}.V_{O_2}=\dfrac{100}{21}.5,536=\dfrac{2768}{105}\left(l\right)\)
\(n_{H_2}\)=\(\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH 2H2 +O2----to--->2H2O
0,2....0,1.................0,2
=>\(m_{H_2O}=0,2.18=3,6\left(g\right)\)
=>\(V_{O_2}=0,1.22,4=2,24\left(l\right)\)
=>Vkk=2,24.5=11,2(l)
\(n_{H_2} = \dfrac{4,48}{22,4} = 0,2(mol)\\ 2H_2 + O_2 \xrightarrow{t^o} 2H_2O\\ n_{H_2O} = n_{H_2} =0,2(mol) \Rightarrow m_{H_2O} = 0,2.18 = 3,6(gam)\\ n_{O_2} = \dfrac{1}{2}n_{H_2} = 0,1(mol)\\ \Rightarrow V_{O_2} = 0,1.22,4 = 2,24(lít)\\ \Rightarrow V_{không\ khí} = 5V_{O_2} = 2,24.5 = 11,2(lít) \)
\(m_{CH_4}=0,3.16=4,8(g)\)
Bảo toàn KL: \(m_{CH_4}+m_{O_2}=m_{CO_2}+m_{H_2O}\)
\(\Rightarrow m_{O_2}=10,8+13,2-4,8=19,2(g)\\ \Rightarrow V_{O_2}=\dfrac{19,2}{32}.22,4=13,44(l)\\ \Rightarrow V_{kk}=13,44.5=67,2(l)\)
\(n_{CO_2}=\dfrac{4.4}{44}=0.1\left(mol\right)\)
\(CH_4+2O_2\underrightarrow{^{^{t^0}}}CO_2+2H_2O\)
\(0.1.......0.2........0.1..........0.2\)
\(m_{CH_4}=0.1\cdot16=1.6\left(g\right)\)
\(V_{H_2O}=0.2\cdot22.4=4.48\left(l\right)\)
\(V_{kk}=5V_{O_2}=5\cdot0.2\cdot22.4=22.4\left(l\right)\)
Bài 1:
a) H2 + CuO \(\underrightarrow{to}\) Cu + H2O
\(n_{Cu}=\dfrac{0,32}{32}=0,01\left(mol\right)\)
b) Theo PT: \(n_{CuO}=n_{Cu}=0,01\left(mol\right)\)
\(\Rightarrow m_{CuO}=0,01\times80=0,8\left(g\right)\)
c) Theo PT: \(n_{H_2}=n_{Cu}=0,01\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,01\times22,4=0,224\left(l\right)\)
d) Theo pT: \(n_{H_2O}=n_{Cu}=0,01\left(mol\right)\)
\(\Rightarrow m_{H_2O}=0,01\times18=0,18\left(g\right)\)
Bài 2:
\(m_{CH_4}=0,3\times16=4,8\left(g\right)\)
CH4 + 2O2 \(\underrightarrow{to}\) CO2 + 2H2O
Theo ĐL BTKL ta có:
\(m_{CH_4}+m_{O_2}=m_{CO_2}+m_{H_2O}\)
\(\Leftrightarrow4,8+m_{O_2}=13,2+10,8\)
\(\Leftrightarrow m_{O_2}=13,2+10,8-4,8=19,2\left(g\right)\)
\(\Rightarrow n_{O_2}=\dfrac{19,2}{32}=0,6\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,6\times22,4=13,44\left(l\right)\)
\(\Rightarrow V_{KK}=13,44\times5=67,2\left(l\right)\)