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n CuSO4 = \(\dfrac{11,2}{160}\)= 0.07 mol
a, PTHH
CuSO4 + 2KOH------------> Cu[OH]2 + K2SO4
0.07mol-------0.14mol----------0.07mol
b, mCu[OH]2 = 0,07. 98 =6,86 g
c, 80ml= 0,08l
CM KOH = \(\dfrac{n}{V}\)= \(\dfrac{0,14}{0,08}\)= 1,75 M
a, \(MgCl_2+2NaOH\rightarrow Mg\left(OH\right)_2+2NaCl\)
\(Mg\left(OH\right)_2\underrightarrow{t^o}MgO+H_2O\)
b, \(n_{MgCl_2}=0,2.0,25=0,05\left(mol\right)\)
Theo PT: \(n_{MgO}=n_{Mg\left(OH\right)_2}=n_{MgCl_2}=0,05\left(mol\right)\)
\(\Rightarrow m_{MgO}=0,05.40=2\left(g\right)\)
c, \(n_{NaOH}=2n_{MgCl_2}=0,1\left(mol\right)\)
\(\Rightarrow m_{ddNaOH}=\dfrac{0,1.40}{15\%}=\dfrac{80}{3}\left(g\right)\)
a, PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(FeO+2HCl\rightarrow FeCl_2+H_2O\)
b, Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,2\left(mol\right)\)
\(\Rightarrow m_{Al}=0,2.27=5,4\left(g\right)\)
⇒ mFeO = 12,6 - 5,4 = 7,2 (g)
c, Phần này đề cho dd NaOH dư hay vừa đủ bạn nhỉ?
d, Cho hh vào dd H2SO4 đặc nguội thì có khí thoát ra.
PT: \(2FeO+4H_2SO_{4\left(đ\right)}\rightarrow Fe_2\left(SO_4\right)_3+SO_2+4H_2O\)
Ta có: \(n_{FeO}=\dfrac{7,2}{72}=0,1\left(mol\right)\)
Theo PT: \(n_{SO_2}=\dfrac{1}{2}n_{FeO}=0,05\left(mol\right)\)
\(\Rightarrow V_{SO_2}=0,05.22,4=1,12\left(l\right)\)
\(a.CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\\ Cu\left(OH\right)_2-^{t^o}\rightarrow CuO+H_2O\\b. n_{CuSO_4}=n_{Na_2SO_4}=0,2\left(mol\right)\\ m_{Na_2SO_4}=0,2.142=28,4\left(g\right)\\ c.BTNT\left(Cu\right):n_{CuO}=n_{CuSO_4}=0,2\left(mol\right)\\ \Rightarrow m_{CuO}=0,2.80=16\left(g\right)\)
\(n_{CuCl_2}=\dfrac{1,35}{135}=0,01(mol)\\ n_{KOH}=\dfrac{28.10}{100.56}=0,05(mol)\\ a,CuCl_2+2KOH\to Cu(OH)_2\downarrow+2KCl\\ Cu(OH)_2\xrightarrow{t^o}CuO+H_2O\\ \dfrac{n_{CuCl_2}}{1}<\dfrac{n_{KOH}}{2}\Rightarrow KOH\text{ dư}\\ b,n_{CuO}=n_{Cu(OH)_2}=0,01(mol)\\ \Rightarrow m_{CuO}=0,01.80=0,8(g)\)
\(c,n_{KCl}=0,02(mol);n_{KOH(dư)}=0,05-0,01.2=0,03(mol)\\ \Rightarrow m_{Cu(OH)_2}=0,01.98=0,98(g);m_{KCl}=0,02.74,9=1,49(g)\\ \Rightarrow \begin{cases} C\%_{KCl}=\dfrac{1,49}{1,35+28-0,98}.100\%=5,25\%\\ C\%_{KOH(dư)}=\dfrac{0,03.56}{1,35+28-0,98}.100=5,92\% \end{cases}\)
\(n_{CuCl2}=\dfrac{1,35}{135}=0,01\left(mol\right)\)
\(m_{ct}=\dfrac{10.28}{100}=2,8\left(g\right)\)
\(n_{KOH}=\dfrac{2,8}{56}=0,05\left(mol\right)\)
a) Pt : \(CuCl_2+2KOH\rightarrow Cu\left(OH\right)_2+2KCl|\)
1 2 1 2
0,01 0,05 0,01 0,02
\(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O|\)
1 1 1
0,01 0,01
b) Lập tỉ số so sánh : \(\dfrac{0,01}{1}< \dfrac{0,05}{2}\)
⇒ CuCl2 phản ứng hết , KOH dư
⇒ Tính toán dựa vào số mol của CuCl2
\(n_{CuO}=\dfrac{0,01}{1}=0,01\left(mol\right)\)
⇒ \(m_{CuO}=0,01.80=0,8\left(g\right)\)
c) \(n_{KCl}=\dfrac{0,01.2}{1}=0,02\left(mol\right)\)
⇒ \(m_{KCl}=0,02.74,5=1,49\left(g\right)\)
\(n_{KOH\left(dư\right)}=0,05-\left(0,01.2\right)=0,03\left(mol\right)\)
⇒ \(m_{KOH\left(dư\right)}=0,03.56=1,68\left(g\right)\)
\(m_{ddspu}=1,35+28=29,35\left(g\right)\)
\(C_{KCl}=\dfrac{1,49.100}{29,35}=5,08\)0/0
\(C_{ddKOH\left(dư\right)}=\dfrac{1,68.100}{29,35}=5,72\)0/0
Chúc bạn học tốt
2NaOH + CuSO4 -> Cu(OH)2 + Na2SO4
x 0,5x
2KOH + CuSO4 -> Cu(OH)2 + K2SO4
y 0,5y
Cu(OH)2 -> CuO + H2O
0,125 0,125
nCuO= 10/80 = 0,125 mol
đặt x=nNaOH , y=nKOH mol
theo đề bài , ta có hệ pt
40x + 56y = 11,6 -> x=0,15
0,5x + 0,5y = 0,125 y=0,1
mNaOH= 0,15*40=6 g
mKOH= 5,6 g
Chúc bạn thành công nha =))))
\(\begin{array}{l} a,\\ PTHH:\\ AlCl_3+3KOH\to Al(OH)_3\downarrow+3KCl\ (1)\\ 2Al(OH)_3\xrightarrow{t^o} Al_2O_3+3H_2O\ (2)\\ b,\\ n_{KOH}=\dfrac{3,36}{56}=0,06\ (mol)\\ Theo\ pt\ (1):\ n_{AlCl_3}=\dfrac{1}{3}n_{KOH}=0,02\ (mol)\\ \Rightarrow m_{AlCl_3}=0,02\times 133,5=2,67\ (g)\\ c,\\ Theo\ pt\ (1):\ n_{Al(OH)_3}=\dfrac{1}{3}n_{KOH}=0,02\ (mol)\\ Theo\ pt\ (2):\ n_{Al_2O_3}=\dfrac{1}{2}n_{Al(OH)_3}=0,01\ (mol)\\ \Rightarrow m_{Al_2O_3}=0,01\times 102=1,02\ (g)\end{array}\)