Cho 100 gam dung dịch NaCl 5,85% vào 100 gam dung dịch AgNO3 12%. Tính nồng độ % dung dịch sau phản ứng.
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a, Gọi \(m_{NaCl\left(thêm\right)}=a\left(g\right)\)
\(m_{NaCl\left(bđ\right)}=5\%.100=5\left(g\right)\\ \Rightarrow C\%_{NaCl}=\dfrac{5+a}{100+a}.100\%=5,5\%\\ \Leftrightarrow a=0,53\left(g\right)\)
b, \(m_{NaCl}=58,5.5,5\%=3,2175\left(g\right)\\ n_{NaCl}=\dfrac{3,2175}{58,5}=0,055\left(mol\right)\)
PTHH: NaCl + AgNO3 ---> AgCl↓ + NaNO3
0,055-->0,055------>0,055---->0,055
\(m_{AgCl}=0,055.143,5=7,8925\left(g\right)\\ m_{ddY}=58,5+200-7,8925=250,6075\left(g\right)\\ \Rightarrow C\%_{NaNO_3}=\dfrac{0,055.85}{250,6075}.100\%=1,87\%\)
\(n_K=\frac{5,85}{15}=0,15(mol)\\ K+H_2O \to KOH +\frac{1}{2}H_2\\ n_{KOH}=n_K=0,15(mol)\\ n_{H_2}=\frac{1}{2}.n_K=\frac{1}{2}.0,15=0,075(mol)\\ m_{dd}=5,85+100-(0,075.2)=105,7(g)\\ C\%=\frac{0,15.56}{105,7}.100=7,95\%\)
\(n_{KOH}=\dfrac{400.7\%}{56}=0,5\left(mol\right)\)
\(n_{H_2SO_4}=\dfrac{100.19,6\%}{98}=0,2\left(mol\right)\)
PTHH: 2KOH + H2SO4 --> K2SO4 + 2H2O
Xét tỉ lệ: \(\dfrac{0,5}{2}>\dfrac{0,2}{1}\) => KOH dư, H2SO4 hết
PTHH: 2KOH + H2SO4 --> K2SO4 + 2H2O
0,4<----0,2-------->0,2
=> \(\left\{{}\begin{matrix}m_{KOH\left(dư\right)}=\left(0,5-0,4\right).56=5,6\left(g\right)\\m_{K_2SO_4}=0,2.174=34,8\left(g\right)\end{matrix}\right.\)
mdd sau pư = 400 + 100 = 500 (g)
=> \(\left\{{}\begin{matrix}C\%_{KOH.dư}=\dfrac{5,6}{500}.100\%=1,12\%\\C\%_{K_2SO_4}=\dfrac{34,8}{500}.100\%=6,96\%\end{matrix}\right.\)
\(n_{KOH}=\dfrac{400.7}{100}:56=0,5\left(mol\right)\)
\(n_{H_2SO_4}=\dfrac{100.19,6}{100}:98=0,2\left(mol\right)\)
\(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)
0,4 0,2 0,2
Lập tỉ lệ:
\(\dfrac{0,5}{2}>\dfrac{0,2}{1}\) => KOH dư.
\(m_{dd}=400+100=500\left(g\right)\)
\(n_{KOH.dư}=0,5-0,4=0,1\left(mol\right)\)
\(C\%_{K_2SO_4}=\dfrac{0,2.174.100}{500}=6,96\%\)
\(C\%_{KOH}=\dfrac{0,1.56.100}{500}=1,12\%\)
nNa=4,6/23=0,2(mol)
PTHH: Na + H2O -> NaOH + 1/2 H2
0,2_______________0,2____0,1(mol)
mddNaOH=4,6+100-0,1.2=104,4(g)
mNaOH=0,2.40=8(g)
=>C%ddNaOH= (8/104,4).100=7,663%
=> Chọn B (gần nhất)
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\(a,\left\{{}\begin{matrix}m_{BaCl_2}=\dfrac{100\cdot10,4\%}{100\%}=10,4\left(g\right)\\m_{H_2SO_4}=\dfrac{200\cdot9,8\%}{100\%}=19,6\left(g\right)\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}n_{BaCl_2}=\dfrac{10,4}{208}=0,05\left(mol\right)\\n_{H_2SO_4}=\dfrac{19,6}{98}=0,2\left(mol\right)\end{matrix}\right.\)
\(PTHH:BaCl_2+H_2SO_4\rightarrow BaSO_4\downarrow+2HCl\)
Vì \(\dfrac{n_{BaCl_2}}{1}< \dfrac{n_{H_2SO_4}}{2}\) nên \(H_2SO_4\) dư
\(\Rightarrow n_{BaSO_4}=n_{BaCl_2}=0,05\left(mol\right)\\ \Rightarrow m_{BaSO_4}=0,05\cdot233=11,65\left(g\right)\)
\(b,n_{HCl}=n_{BaSO_4}=0,05\left(mol\right)\\ \Rightarrow m_{CT_{HCl}}=0,05\cdot36,5=1,825\left(g\right)\\ \Rightarrow m_{dd_{HCl}}=100+200-11,65=288,35\left(g\right)\\ \Rightarrow C\%_{HCl}=\dfrac{1,825}{288,35}\cdot100\%\approx0,63\%\)
\(m_{NaCl}=\dfrac{5,85.100}{100}=5,85g\)
\(n_{NaCl}=\dfrac{5,85}{58,5}=0,1\left(mol\right)\)
\(m_{AgNO_3}=\dfrac{12.100}{100}=12g\)
\(n_{AgNO_3}=\dfrac{12}{170}\approx0,07\left(mol\right)\)
Ta co: \(\dfrac{0,1}{1}>\dfrac{0,07}{1}\Rightarrow\) NaCl dư
NaCl + AgNO3 \(\rightarrow\) NaNO3 + AgCl\(\left(\downarrow\right)\)
de: 0,1 0,07
pu: 0,07 0,07 0,07 0,07
spu: 0,03 0 0,07 0,07
\(m_{NaCl\left(dư\right)}=0,03.58,5=1,755g\)
\(m_{NaNO_3}=0,07.85=5,95g\)
\(m_{ddspu}=m_{ddNaCl}+m_{ddAgNO_3}-m_{AgCl}=189,955g\)
\(C\%_{NaCl\left(dư\right)}=\dfrac{1,755}{189,955}.100\%\approx0,92\%\)
\(C\%_{NaNO_3}=\dfrac{5,95}{189,955}.100\%\approx3,13\%\)