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\(n_K=\frac{5,85}{15}=0,15(mol)\\ K+H_2O \to KOH +\frac{1}{2}H_2\\ n_{KOH}=n_K=0,15(mol)\\ n_{H_2}=\frac{1}{2}.n_K=\frac{1}{2}.0,15=0,075(mol)\\ m_{dd}=5,85+100-(0,075.2)=105,7(g)\\ C\%=\frac{0,15.56}{105,7}.100=7,95\%\)
nNa=4,6/23=0,2(mol)
PTHH: Na + H2O -> NaOH + 1/2 H2
0,2_______________0,2____0,1(mol)
mddNaOH=4,6+100-0,1.2=104,4(g)
mNaOH=0,2.40=8(g)
=>C%ddNaOH= (8/104,4).100=7,663%
=> Chọn B (gần nhất)
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\(a,\left\{{}\begin{matrix}m_{BaCl_2}=\dfrac{100\cdot10,4\%}{100\%}=10,4\left(g\right)\\m_{H_2SO_4}=\dfrac{200\cdot9,8\%}{100\%}=19,6\left(g\right)\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}n_{BaCl_2}=\dfrac{10,4}{208}=0,05\left(mol\right)\\n_{H_2SO_4}=\dfrac{19,6}{98}=0,2\left(mol\right)\end{matrix}\right.\)
\(PTHH:BaCl_2+H_2SO_4\rightarrow BaSO_4\downarrow+2HCl\)
Vì \(\dfrac{n_{BaCl_2}}{1}< \dfrac{n_{H_2SO_4}}{2}\) nên \(H_2SO_4\) dư
\(\Rightarrow n_{BaSO_4}=n_{BaCl_2}=0,05\left(mol\right)\\ \Rightarrow m_{BaSO_4}=0,05\cdot233=11,65\left(g\right)\)
\(b,n_{HCl}=n_{BaSO_4}=0,05\left(mol\right)\\ \Rightarrow m_{CT_{HCl}}=0,05\cdot36,5=1,825\left(g\right)\\ \Rightarrow m_{dd_{HCl}}=100+200-11,65=288,35\left(g\right)\\ \Rightarrow C\%_{HCl}=\dfrac{1,825}{288,35}\cdot100\%\approx0,63\%\)
n Al 2 SO 4 3 = 0,05/3 x 1 ≈ 0,017 mol
C M Al 2 SO 4 3 = 0,017/0,1 = 0,17M
1)\(n_{NaOH}:\dfrac{60.10\%}{100\%.40}=0,15\left(mol\right)\)
KL dung dịch sau p/ư: 60+40=100(g)
\(n_{NaCl}:\dfrac{100.5,85\%}{100\%.58,5}=0,1\left(mol\right)\)
\(NaOH+HCl\rightarrow NaCl+H_2O\)
1...................1...............1.................(mol)
0,1................0,1............0,1...............(mol)
-> NaOH dư
C% dd HCl: \(\dfrac{0,1.36,5}{40}.100\%=9,125\%\)
\(m_{NaCl}=\dfrac{5,85.100}{100}=5,85g\)
\(n_{NaCl}=\dfrac{5,85}{58,5}=0,1\left(mol\right)\)
\(m_{AgNO_3}=\dfrac{12.100}{100}=12g\)
\(n_{AgNO_3}=\dfrac{12}{170}\approx0,07\left(mol\right)\)
Ta co: \(\dfrac{0,1}{1}>\dfrac{0,07}{1}\Rightarrow\) NaCl dư
NaCl + AgNO3 \(\rightarrow\) NaNO3 + AgCl\(\left(\downarrow\right)\)
de: 0,1 0,07
pu: 0,07 0,07 0,07 0,07
spu: 0,03 0 0,07 0,07
\(m_{NaCl\left(dư\right)}=0,03.58,5=1,755g\)
\(m_{NaNO_3}=0,07.85=5,95g\)
\(m_{ddspu}=m_{ddNaCl}+m_{ddAgNO_3}-m_{AgCl}=189,955g\)
\(C\%_{NaCl\left(dư\right)}=\dfrac{1,755}{189,955}.100\%\approx0,92\%\)
\(C\%_{NaNO_3}=\dfrac{5,95}{189,955}.100\%\approx3,13\%\)