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Gọi \(\left\{{}\begin{matrix}n_{C2H5OH}:x\left(mol\right)\\n_{CH3COOH}:y\left(mol\right)\end{matrix}\right.\)
Ta có:
\(n_{H2}=\frac{4,48}{22,4}=0,2\left(mol\right)\)
\(2C_2H_5OH+2K\rightarrow C_2H_5OK+H_2\)
\(2CH_3COOH+2K\rightarrow2CH_3COOK+H_2\)
Giải hệ PT:
\(\left\{{}\begin{matrix}4x+100y=21,1\\0,5x+0,5y=0,2\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,35\\y=0,05\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{C2H5OH}=\frac{0,35.46}{21,1}.100\%=76,3\%\\\%m_{CH3COOH}=100\%-76,3\%=23,7\%\end{matrix}\right.\)
- Đặt \(\left\{{}\begin{matrix}n_{Al}=a\left(mol\right)\\n_{Mg}=b\left(mol\right)\end{matrix}\right.\Rightarrow27a+24b=10,2\left(1\right)\)
Khí thu được sau p/ứ là khí H2: \(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
2 3 (mol)
a 3/2 a (mol)
\(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
1 1 (mol)
b b (mol)
Từ hai PTHH trên ta có: \(\dfrac{3}{2}a+b=0,5\left(2\right)\)
\(\left(1\right),\left(2\right)\) ta có hệ: \(\left\{{}\begin{matrix}27a+24b=10,2\\\dfrac{3}{2}a+b=0,5\end{matrix}\right.\)
Giải ra ta có \(\left\{{}\begin{matrix}a=0,2\left(mol\right)\\b=0,2\left(mol\right)\end{matrix}\right.\)
a) \(\%Al=\dfrac{m_{Al}}{m_{hh}}.100\%=\dfrac{0,2.27}{10,2}.100\%\approx52,94\%\)
\(\%Mg=100\%-\%Al=100\%-52,94=47,06\%\)
b)
\(3H_2+Fe_2O_3\rightarrow^{t^0}2Fe+3H_2O\)
3 1 2 (mol)
0,5 1/6 1/3 (mol)
\(m_{Fe}=\dfrac{1}{3}.56=\dfrac{56}{3}\left(g\right)\)
\(m_{Fe_2O_3\left(pứ\right)}=\dfrac{1}{6}.160=\dfrac{80}{3}\left(g\right)\)
\(m_{Fe_2O_3\left(dư\right)}=60-m_{Fe}=60-\dfrac{56}{3}=\dfrac{124}{3}\left(g\right)\)
\(a=\dfrac{124}{3}+\dfrac{80}{3}=68\left(g\right)\)
\(C_2H_5OH+K_2CO_3\rightarrow\left(kopứ\right)\)
\(2CH_3COOH+K_2CO_3\rightarrow2CH_3COOK+CO_2+H_2O\)
2 1 2 1 1 (mol)
0,4 0,2 0,4 0,2 0,2 (mol)
\(nCO_2=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
\(mCH_3COOH=0,4.60=24\left(g\right)\)
\(mK_2CO_3=0,2.138=27,6\left(g\right)\)
\(mCH_3COOK=0,4.98=39,2\left(g\right)\)
\(mCO_2=0,2.44=8,8\left(g\right)\)
\(mdd=mCH_3COOH+mK_2CO_3+mCH_3COOK-mCO_2\)
\(=24+27,6+39,2-8,8=82\left(g\right)\)
\(C\%m_{CH_3COOH}=\dfrac{24.100}{82}=29,27\%\)
\(C\%m_{K_2CO_3}=\dfrac{27,6.100}{82}=33,66\%\)
câu thứ 2 bn tự lm cho bt:>
nCaCO3 = 0,1 mol
nH2 = 0,125 mol
Pt: Mg + 2HCl --> MgCl2 + H2
.....0,125 mol<----------------0,125 mol
.....MgCO3 + 2HCl --> MgCl2 + H2O + CO2
.....0,1 mol<----------------------------------0,1 mol
......CO2 + Ca(OH)2 --> CaCO3 + H2O
....0,1 mol<---------------0,1 mol
mA = 0,125 . 24 + 0,1 . 84 = 11,4 (g)
% mMg = \(\dfrac{0,125\times4}{11,4}.100\%=26,3\%\)
% mMgCO3 = \(\dfrac{0,1\times84}{11,4}.100\%=73,7\%\)
\(Đặt:n_{C_2H_5OH}=a\left(mol\right);n_{CH_3COOH}=b\left(mol\right)\left(a,b>0\right)\\ a,PTHH:C_2H_5OH+Na\rightarrow C_2H_5ONa+\dfrac{1}{2}H_2\\ CH_3COOH+Na\rightarrow CH_3COONa+\dfrac{1}{2}H_2\\ n_{H_2\left(tổng\right)}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\ b,Ta.lập.hpt:\left\{{}\begin{matrix}46a+60b=10,6\\0,5a+0,5b=0,1\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\\ \%m_{C_2H_5OH}=\dfrac{0,1.46}{10,6}.100\approx43,396\%\\\Rightarrow\%m_{CH_3COOH}\approx100\%-43,396\%\approx56,604\%\)
a, 2CH3COOH + Na2CO3 ---> 2CH3OONa + H20 + CO2
C2H5OH không tác dụng
b, đặt C2H5OH =x , CH3COOH=y
Ta có hệ 46x + 60y = 21,4 và y=\(\frac{10}{M_{CaCO3}}=\frac{10}{100}=0,1\)
=> x và y => %