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nH2= 0,12 mol
Fe + 2HCl = FeCl2 + H2
=> nFe = nH2 = 0,12 mol
=> mFe = 0,12*56 = 6,72 gam
=%Fe = (6,72*100%):10 = 67,2%
=> % Cu = 100% -67,2% = 32,8%
\(a)2Na+2HCl\xrightarrow[]{}2NaCl+H_2\\ 2K+2HCl\xrightarrow[]{}2KCl+H_2 \\ b)n_{H_2}=\dfrac{2,24}{22,4}=0,1mol\\ n_{Na}=a,n_K=b\\ \Rightarrow\left\{{}\begin{matrix}23a+39b=6,2\\\dfrac{1}{2}a+\dfrac{1}{2}b=0,1\end{matrix}\right.\\ \Rightarrow a=b=0,1mol\\ \%_{Na}=\dfrac{0,1.23}{6,2}\cdot100=37,1\%\\ \%_K=100-37,1=62,9\%\)
\(a.Mg+2HCl->MgCl_2+H_2\\ MgO+2HCl->MgCl_2+H_2O\\ b.n_{H_2}=\dfrac{2,24}{22,4}=n_{Mg}=0,1mol\\ \%m_{Mg}=\dfrac{0,1.24}{6}=40\%;\%m_{MgO}=60\%\\ n_{MgO}=\dfrac{0,6.6}{40}=0,09\left(mol\right)\\ n_{MgCl_2}=0,1+0,09=0,19\left(mol\right)\\ n_{HCl}=0,19.2=0,38\left(mol\right)\\ V_{ddHCl}=\dfrac{0,38.36,5}{0,2.1,1}=63,0\left(mL\right)\\ C_{M\left(MgCl_2\right)}=\dfrac{0,19}{0,063}=3,0\left(M\right)\)
\(C_2H_5OH+K_2CO_3\rightarrow\left(kopứ\right)\)
\(2CH_3COOH+K_2CO_3\rightarrow2CH_3COOK+CO_2+H_2O\)
2 1 2 1 1 (mol)
0,4 0,2 0,4 0,2 0,2 (mol)
\(nCO_2=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
\(mCH_3COOH=0,4.60=24\left(g\right)\)
\(mK_2CO_3=0,2.138=27,6\left(g\right)\)
\(mCH_3COOK=0,4.98=39,2\left(g\right)\)
\(mCO_2=0,2.44=8,8\left(g\right)\)
\(mdd=mCH_3COOH+mK_2CO_3+mCH_3COOK-mCO_2\)
\(=24+27,6+39,2-8,8=82\left(g\right)\)
\(C\%m_{CH_3COOH}=\dfrac{24.100}{82}=29,27\%\)
\(C\%m_{K_2CO_3}=\dfrac{27,6.100}{82}=33,66\%\)
câu thứ 2 bn tự lm cho bt:>
a, Gọi \(\left\{{}\begin{matrix}n_{C_2H_5OH}=a\left(mol\right)\\n_{CH_3COOH}=b\left(mol\right)\end{matrix}\right.\)
\(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
PTHH:
2C2H5OH + 2Na ---> 2C2H5ONa + H2
a---------------------------------------->0,5a
2CH3COOH + 2Na ---> 2CH3COONa + H2
b------------------------------------------------>0,5b
=> hệ pt \(\left\{{}\begin{matrix}46a+60b=48,8\\0,5a+0,5b=0,5\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,8\left(mol\right)\\b=0,2\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{C_2H_5OH}=0,8.46=36,8\left(g\right)\\m_{CH_3COOH}=0,2.60=12\left(g\right)\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}\%m_{C_2H_5OH}=\dfrac{36,8}{48,8}.100\%=75,41\%\\\%m_{CH_3COOH}=100\%-75,41\%=24,59\%\end{matrix}\right.\)
b, PTHH:
\(C_2H_5OH+CH_3COOH\xrightarrow[t^o]{H_2SO_4đặc}CH_3COOC_2H_5+H_2O\)
LTL: 0,8 > 0,2 => Rượu dư
\(n_{CH_3COOC_2H_5\left(tt\right)}=0,2.85\%=0,17\left(mol\right)\\ m_{este}=0,17.88=14,96\left(g\right)\)
a.Gọi \(\left\{{}\begin{matrix}n_{C_2H_5OH}=x\\n_{CH_3COOH}=y\end{matrix}\right.\)
\(n_{H_2}=\dfrac{11,2}{22,4}=0,5mol\)
\(2C_2H_5OH+2Na\rightarrow2C_2H_5ONa+H_2\)
x 1/2 x ( mol )
\(2CH_3COOH+Na\rightarrow2CH_3COONa+H_2\)
y 1/2 y ( mol )
Ta có:
\(\left\{{}\begin{matrix}46x+60y=48,8\\\dfrac{1}{2}x+\dfrac{1}{2}y=0,5\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,8\\y=0,2\end{matrix}\right.\)
\(\rightarrow m_{C_2H_5OH}=0,8.46=36,8g\)
\(\rightarrow\left\{{}\begin{matrix}\%m_{C_2H_5OH}=\dfrac{36,8}{48,8}.100=75,4\%\\\%m_{CH_3COOH}=100\%-75,4\%=24,6\%\end{matrix}\right.\)
b.\(C_2H_5OH+CH_3COOH\rightarrow\left(H_2SO_4\left(đ\right),t^o\right)CH_3COOC_2H_5+H_2O\)
0,8 < 0,2 ( mol )
0,2 0,2 ( mol )
\(m_{CH_3COOC_2H_5}=0,2.88.85\%=14,96g\)
\(Đặt:n_{C_2H_5OH}=a\left(mol\right);n_{CH_3COOH}=b\left(mol\right)\left(a,b>0\right)\\ a,PTHH:C_2H_5OH+Na\rightarrow C_2H_5ONa+\dfrac{1}{2}H_2\\ CH_3COOH+Na\rightarrow CH_3COONa+\dfrac{1}{2}H_2\\ n_{H_2\left(tổng\right)}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\ b,Ta.lập.hpt:\left\{{}\begin{matrix}46a+60b=10,6\\0,5a+0,5b=0,1\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\\ \%m_{C_2H_5OH}=\dfrac{0,1.46}{10,6}.100\approx43,396\%\\\Rightarrow\%m_{CH_3COOH}\approx100\%-43,396\%\approx56,604\%\)