Cho 6,2g Na2O tan hết vào nước tạo thành 200g dd.
a)tính c% của dd thu đc
b)tính V khí CO2 ở đktc td với dd nói trên.biết sp là muối trung hòa
Mn giúp mình với mình đang cần gấp TT
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\(n_{Na_2O}=\dfrac{6,2}{62}=0,1 \left(mol\right)\)
\(2Na+2H_2O\rightarrow2NaOH+H_2\)
0,1 -----------------> 0,1
\(CM_{base}=CM_{NaOH}=\dfrac{0,1}{0,2}=0,5M\)
b
\(H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\)
0,05 <------ 0,1
\(V_{H_2SO_4}=\dfrac{0,05}{0,2}=0,25\left(l\right)\Rightarrow V_{dd.H_2SO_4}=\dfrac{0,25.100}{20}=1,25\left(l\right)\)
PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
Ta có: \(\left\{{}\begin{matrix}n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\\n_{H_2SO_4}=\dfrac{200\cdot29,4\%}{98}=0,6\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{2}< \dfrac{0,6}{3}\) \(\Rightarrow\) Axit còn dư, Nhôm p/ứ hết
\(\Rightarrow\left\{{}\begin{matrix}n_{Al_2\left(SO_4\right)_3}=0,1\left(mol\right)\\n_{H_2}=0,3\left(mol\right)\\n_{H_2SO_4\left(dư\right)}=0,6-0,3=0,3\left(mol\right)\end{matrix}\right.\)\(\Rightarrow\left\{{}\begin{matrix}m_{Al_2\left(SO_4\right)_3}=0,1\cdot342=34,2\left(g\right)\\m_{H_2SO_4\left(dư\right)}=0,3\cdot98=29,4\left(g\right)\\m_{H_2}=0,3\cdot2=0,6\left(g\right)\\V_{H_2}=0,3\cdot22,4=6,72 \left(l\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd\left(saup/ứ\right)}=m_{Al}+m_{ddH_2SO_4}-m_{H_2}=204,8\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{Al_2\left(SO_4\right)_3}=\dfrac{34,2}{204,8}\cdot100\%\approx16,7\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{29,4}{204,8}\cdot100\%\approx14,36\%\end{matrix}\right.\)
\(a,MgCO_3\rightarrow\left(t^o\right)MgO+CO_2\\ Na_2O+H_2O\rightarrow2NaOH\\ CO_2+2NaOH\rightarrow Na_2CO_3+H_2O\\ n_{CO_2}=n_{MgO}=n_{MgCO_3}=\dfrac{84}{84}=1\left(mol\right);n_{NaOH}=2.n_{Na_2O}=2.\dfrac{4,65}{62}=0,15\left(mol\right)\\ Vì:\dfrac{0,15}{2}>\dfrac{1}{1}\Rightarrow CO_2dư\\ n_{Na_2CO_3}=\dfrac{0,15}{2}=0,075\left(mol\right)\Rightarrow m_{Na_2CO_3}=106.0,075=7,95\left(g\right)\\ m_{CO_2\left(dư\right)}=\left(1-\dfrac{0,15}{2}\right).44=40,7\left(g\right)\\ m_{MgO}=40.1=40\left(g\right)\\ b,n_{CO_2}=0,1\left(mol\right)\\ Có:1< \dfrac{0,15}{0,1}=1,5< 2\\ \Rightarrow SP:n_{Na_2CO_3}=n_{NaHCO_3}=\dfrac{0,1}{2}=0,05\left(mol\right)\\ m_{muối}=0,05.\left(106+84\right)=9,5\left(g\right)\)
\(n_{K2O}=\dfrac{9,4}{94}=0,1\left(mol\right)\)
Pt : \(K_2O+H_2O\rightarrow2KOH|\)
1 1 2
0,1 0,2
a) \(n_{KOH}=\dfrac{0,1.2}{1}=0,2\left(mol\right)\)
200ml = 0,2l
\(C_{M_{ddKOH}}=\dfrac{0,2}{0,2}=1\left(M\right)\)
b) Pt : \(KOH+HCl\rightarrow KCl+H_2O|\)
1 1 1 1
0,1 0,1
\(n_{HCl}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)
\(m_{HCl}=0,1.36,5=3,65\left(g\right)\)
\(m_{ddHCl}=\dfrac{3,65.100}{10}=36,5\left(g\right)\)
c) \(CO_2+2KOH\rightarrow K_2CO_3+H_2O|\)
1 2 1 1
0,05 0,1
\(n_{CO2}=\dfrac{0,1.1}{2}=0,05\left(mol\right)\)
\(V_{CO2\left(dktc\right)}=0,05.22,4=1,12\left(l\right)\)
Chúc bạn học tốt
Ta có: \(n_{Na_2O}=\dfrac{6,2}{62}=0,1\left(mol\right)\)
\(n_{CO_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH: Na2O + CO2 ---to---> Na2CO3
Ta thấy: \(\dfrac{0,1}{1}< \dfrac{0,15}{1}\)
Vậy CO2 dư.
Theo PT: \(n_{Na_2CO_3}=n_{Na_2O}=0,1\left(mol\right)\)
=> \(m_{Na_2CO_3}=0,1.106=10,6\left(g\right)\)
\(n_{Na_2O}=\dfrac{6.2}{62}=0.1\left(mol\right)\)
\(Na_2O+H_2O\rightarrow2NaOH\)
\(0.1.......................0.2\)
\(C\%_{NaOH}=\dfrac{0.2\cdot40}{200}\cdot100\%=4\%\)
\(2NaOH+CO_2\rightarrow Na_2CO_3+H_2O\)
\(0.2..................0.1\)
\(V_{CO_2}=0.1\cdot22.4=2.24\left(l\right)\)