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4Al+3O2-to>2Al2O3
0,04---0,03------0,02 mol
n Al=\(\dfrac{1,08}{27}\)=0,04 mol
=>VO2=0,03.22,4=0,672l
b)
2A+O2-to>2AO
0,06--0,03 mol
=>\(\dfrac{3,84}{A}=0,06\)
=>A=64 :=>Al là Đồng
\(a,PTHH:4A+3O_2\underrightarrow{t^o}2A_2O_3\\ Áp.dụng.ĐLBTKL,ta.có:\\ m_A+m_{O_2}=m_{A_2O_3}\\ \Rightarrow m_{O_2}=m_{A_2O_3}-m_A=20,4-10,8=9,6\left(g\right)\)
\(\Rightarrow n_{O_2}=\dfrac{m}{M}=\dfrac{9,6}{32}=0,3\left(mol\right)\\ Theo.PTHH:n_A=\dfrac{4}{3}.n_{O_2}=\dfrac{4}{3}.0,3=0,4\left(mol\right)\\ \Rightarrow M_A=\dfrac{m}{n}=\dfrac{10,8}{0,4}=27\left(\dfrac{g}{mol}\right)\\ \Rightarrow A.là.Al\left(nhôm\right)\)
\(b,V_{O_2\left(đktc\right)}=n.22,4=0,4.22,4=8,96\left(l\right)\\ \Rightarrow V_{kk\left(đktc\right)}=V_{O_2\left(đktc\right)}.5=8,96.5=44,8\left(l\right)\)
\(a,4A+3O_2\rightarrow\left(t^o\right)2A_2O_3\\ Theo.ĐLBTKL:\\ m_A+m_{O_2}=m_{A_2O_3}\\ \Leftrightarrow10,8+m_{O_2}=20,4\\ \Leftrightarrow m_{O_2}=9,6\left(g\right)\\ \Rightarrow n_{O_2}=\dfrac{9,6}{32}=0,3\left(mol\right)\\ n_A=\dfrac{4}{3}.0,3=0,4\left(mol\right)\Rightarrow M_A=\dfrac{m_A}{n_A}=\dfrac{10,8}{0,4}=27\left(\dfrac{g}{mol}\right)\\ \Rightarrow A:Nhôm\left(Al=27\right)\\ b,V_{kk\left(đktc\right)}=\dfrac{100}{20}.V_{O_2\left(đktc\right)}=5.\left(0,3.22,4\right)=33,6\left(l\right)\)
\(2Cu+O_2\rightarrow\left(t^o\right)2CuO\\ n_{CuO}=n_{Cu}=\dfrac{6,4}{64}=0,1\left(mol\right);n_{O_2}=\dfrac{0,1}{2}=0,05\left(mol\right)\\ a,V_{O_2\left(đktc\right)}=0,05.22,4=1,12\left(l\right)\\ V_{kk\left(đktc\right)}=\dfrac{100.1,12}{20}=5,6\left(l\right)\\ b,m_{CuO}=0,1.80=8\left(g\right)\\ c,2R+O_2\rightarrow\left(t^o\right)2RO\\ n_R=2.n_{O_2}=2.0,05=0,1\left(mol\right)\\ M_R=\dfrac{2,4}{0,1}=24\left(\dfrac{g}{mol}\right)\\ \Rightarrow R:Magie\left(Mg=24\right)\)
a) \(n_{Al}=\dfrac{8,1}{27}=0,3\left(mol\right)\)
PTHH: 4Al + 3O2 --to--> 2Al2O3
______0,3--------------->0,15
=> \(m_{Al_2O_3\left(PTHH\right)}=0,15.102=15,3\left(g\right)\)
=> mAl2O3 (thực tế) = \(\dfrac{15,3.100}{90}=17\left(g\right)\)
\(n_{KClO_3\left(bd\right)}=\dfrac{55,125}{122,5}=0,45\left(mol\right)\)
=> \(n_{KClO_3\left(pư\right)}=\dfrac{0,45.85}{100}=0,3825\left(mol\right)\)
PTHH: 2KClO3 --to,MnO2--> 2KCl + 3O2
0,3825------------------->0,57375
=> \(V_{O_2}=0,57375.22,4=12,852\left(l\right)\)
a, \(2Cu+O_2\underrightarrow{t^o}2CuO\)
b, \(n_{Cu}=\dfrac{16}{64}=0,25\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{1}{2}n_{Cu}=0,125\left(mol\right)\Rightarrow V_{O_2}=0,125.22,4=2,8\left(l\right)\)
c, \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
Theo PT: \(n_{KMnO_4}=2n_{O_2}=0,25\left(mol\right)\Rightarrow m_{KMnO_4}=0,25.158=39,5\left(g\right)\)
\(a.\)
\(n_{O_2}=\dfrac{3.36}{22.4}=0.15\left(mol\right)\)
\(2KMnO_4\underrightarrow{t^0}K_2MnO_4+MnO_2+O_2\)
\(0.3...................................................0.15\)
\(m_{KMnO_4}=0.3\cdot158=47.4\left(g\right)\)
\(4R+nO_2\underrightarrow{t^0}2R_2O_n\)
\(\dfrac{0.6}{n}....0.15\)
\(M_R=\dfrac{19.5}{\dfrac{0.6}{n}}=32.5n\)
\(n=2\Rightarrow R=65\)
\(Rlà:Zn\)
\(a) 2KMnO_4 \xrightarrow{t^o} K_2MnO_4 + MnO_2 + O_2\\ n_{KMnO_4} = 2n_{O_2} = 2.\dfrac{3,36}{22,4} = 0,3(mol)\\ m_{KMnO_4} = 0,3.158 = 47,4(gam)\\ b) 4R + nO_2 \xrightarrow{t^o} 2R_2O_n\\ n_R = \dfrac{4}{n}n_{O_2} = \dfrac{0,6}{n}(mol)\\ \Rightarrow \dfrac{0,6}{n}R = 19,5\Rightarrow R = \dfrac{65}{2}n\)
Với n = 2 thì R = 65(Zn)
\(n_{KMnO_4}=\dfrac{118,5}{158}=0,75\left(mol\right)\\
pthh:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
0,75 0,375
=> \(V_{O_2}=0,375.22,4=8,4\left(l\right)\\
V_{kk}=8,4.5=42\left(l\right)\)
\(n_{KMnO_4}=\dfrac{63,2}{158}=0,4\left(mol\right)\\ pthh:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
0,4 0,2
=> \(V_{O_2\left(lt\right)}=0,2.22,4=4,48\left(l\right)\\ V_{O_2\left(tt\right)}=\dfrac{90.4,48}{100}=4,032\left(l\right)\)