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nC2H4 = 2,24/22,4 = 0,1 (mol)
PTHH: C2H4 + Br2 -> C2H4Br2
Mol: 0,1 ---> 0,1
CMddBr2 = 0,1/0,2 = 0,5M
\(n_{C_2H_4}=\dfrac{V}{22,4}=\dfrac{2,24}{22,4}=0,1mol\)
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
0,1 0,1 ( mol )
\(C_M=\dfrac{0,1}{0,2}=0,5M\)
a, \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
b, Ta có: \(n_{C_2H_4}+n_{C_2H_2}=\dfrac{0,56}{22,4}=0,025\left(mol\right)\) (1)
Theo PT: \(n_{Br_2}=n_{C_2H_4}+2n_{C_2H_2}=\dfrac{5,6}{160}=0,035\left(mol\right)\) (2)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{C_2H_4}=0,015\left(mol\right)\\n_{C_2H_2}=0,01\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{C_2H_4}=0,015.28=0,42\left(g\right)\\m_{C_2H_2}=0,01.26=0,26\left(g\right)\end{matrix}\right.\)
c, \(CaC_2+2H_2O\rightarrow Ca\left(OH\right)_2+C_2H_2\)
Theo PT: \(n_{CaC_2}=n_{C_2H_2}=0,01\left(mol\right)\Rightarrow m_{CaC_2}=0,01.64=0,64\left(g\right)\)
1. \(n_{Br_2}=0,4.0,5=0,2\left(mol\right)\)
PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
Theo PT: \(n_{C_2H_4}=n_{Br_2}=0,2\left(mol\right)\Rightarrow V_{C_2H_4}=0,2.22,4=4,48\left(l\right)\)
2. \(n_{C_2H_4Br_2}=\dfrac{9,4}{188}=0,05\left(mol\right)\)
PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
Theo PT: \(n_{C_2H_4}=n_{C_2H_4Br_2}=0,05\left(mol\right)\)
\(\Rightarrow\%V_{C_2H_4}=\dfrac{0,05.22,4}{1,4}.100\%=80\%\)
\(\Rightarrow\%V_{CH_4}=100-80=20\%\)
200ml = 0,2l
\(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\)
Pt : \(Zn+2HCl\rightarrow ZnCl_2+H_2|\)
1 2 1 1
0,3 0,6 0,3 0,3
a) \(n_{ZnCl2}=\dfrac{0,3.1}{1}=0,3\left(mol\right)\)
\(C_{M_{ZnCl2}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\)
b) \(n_{H2}=\dfrac{0,3.1}{1}=0,3\left(mol\right)\)
\(V_{H2\left(dktc\right)}=0,3.22,4=6,72\left(l\right)\)
c) Pt : \(NaOH+HCl\rightarrow NaCl+H_2O|\)
1 1 1 1
0,6 0,6
\(n_{NaOH}=\dfrac{0,6.1}{1}=0,6\left(mol\right)\)
\(m_{NaOH}=0,6.40=24\left(g\right)\)
\(m_{ddNaOH}=\dfrac{24.100}{20}=120\left(g\right)\)
Chúc bạn học tốt
\(Gọi : n_{C_2H_4} = a; n_{C_2H_2} = b\\ \Rightarrow a + b = \dfrac{5,6}{22,4} = 0,25(1)\\ C_2H_4 + Br_2 \to C_2H_4Br_2\\ C_2H_2 + 2Br_2 \to C_2H_2Br_4\\ n_{Br_2} = a + 2b = \dfrac{56}{160} =0,35(2)\\ (1)(2)\Rightarrow a = 0,15 ; b = 0,1\\ \Rightarrow \%V_{C_2H_4} = \dfrac{0,15}{0,25} .100\% = 60\%\\ \%V_{C_2H_2} = 100\% -60\% = 40\%\)
\(\left\{{}\begin{matrix}C_2H_4:x\left(mol\right)\\C_2H_2:y\left(mol\right)\end{matrix}\right.\)⇒ x + y = \(\dfrac{6,72}{22,4}=0,3\left(1\right)\)
\(C_2H_4 + Br_2 \to C_2H_4Br_2\\ C_2H_2 + 2Br_2 \to C_2H_2Br_4\)
Theo PTHH :
x + 2y = \(\dfrac{64}{160} = 0,4(2)\)
Từ (1)(2) suy ra: x = 0,2 ; y = 0,1
Vậy :
\(\%V_{C_2H_4} = \dfrac{0,2}{0,3}.100\% = 66,67\%\\ \%V_{C_2H_2} = 100\% - 66,67\% = 33,33\%\)
\(n_{CO_2}=0.3\left(mol\right)\)
\(Đặt:n_{C_2H_2}=a\left(mol\right),n_{C_2H_4}=b\left(mol\right)\)
\(n_{Br_2}=\dfrac{64}{160}=0.4\left(mol\right)\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(\left\{{}\begin{matrix}a+b=0.3\\2a+b=0.4\end{matrix}\right.\)
\(\Leftrightarrow\left\{{}\begin{matrix}a=0.1\\b=0.2\end{matrix}\right.\)
\(\%V_{C_2H_2}=\dfrac{0.1}{0.3}\cdot100\%=33.33\%\)
\(\%V_{C_2H_4}=66.67\%\)
\(n_{C_2H_2}=\dfrac{0.224}{22.4}=0.01\left(mol\right)\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
\(0.01.........0.02........0.01\)
\(m_{C_2H_2Br_4}=0.01\cdot346=3.46\left(g\right)\)
\(V_{dd_{Br_2}}=\dfrac{0.02}{2}=0.01\left(l\right)\)
\(n_{Br_2}=\dfrac{m_{Br_2}}{M_{Br_2}}=\dfrac{56}{160}=0,35mol\)
Gọi \(n_{C_2H_4}\) là x \(\Rightarrow V_{C_2H_4}=22,4x\)
\(n_{C_2H_2}\) là y \(\Rightarrow V_{C_2H_2}=22,4y\)
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
x x ( mol )
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
y 2y ( mol )
Ta có:
\(\left\{{}\begin{matrix}22,4x+22,4y=5,6\\x+2y=0,35\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,15\\y=0,1\end{matrix}\right.\)
\(\Rightarrow V_{C_2H_4}=22,4.0,15=3,36l\)
\(\Rightarrow V_{C_2H_2}=22,4.0,1=2,24l\)
\(\%V_{C_2H_4}=\dfrac{3,36}{5,6}.100=60\%\)
\(\%V_{C_2H_2}=\dfrac{2,24}{5,6}.100=40\%\)
nhh khí = 5,6/22,4 = 0,25 (mol)
Gọi nC2H4 = a (mol); nC2H2 = b (mol)
a + b = 0,25 (1)
nBr2 = 56/160 = 0,35 (mol)
PTHH:
C2H4 + Br2 -> C2H4Br2
Mol: a ---> a
C2H2 + 2Br2 -> C2H2Br4
Mol: b ---> 2b
a + 2b = 0,35 (2)
(1)(2) => a = 0,15 (mol); b = 0,1 (mol)
%VC2H2 = 0,15/0,25 = 60%
%VC2H4 = 100% - 60% = 40%
Đổi: 200ml=0,2l
\(n_{Br_2}=C_M.V=0,5.0.2=0,1\) (mol)
PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(\Rightarrow n_{C_2H_4}=n_{Br_2}=0,1\) (mol)
Thể tích C2H4 cần dùng là: \(V_{C_2H_4}=n.22,4=0,1.22,4=2,24\) (l)