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PTHH: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\)
\(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
a+b) Ta có: \(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)=n_{H_2SO_4}=n_{ZnSO_4}\)
\(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,3}{0,2}=1,5\left(M\right)=C_{M_{ZnSO_4}}\)
c) Theo PTHH: \(n_{H_2}=n_{Zn}=0,3mol\) \(\Rightarrow V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\)
d) Theo PTHH: \(n_{Fe}=\dfrac{2}{3}n_{H_2}=0,2mol\)
\(\Rightarrow m_{Fe}=0,2\cdot56=11,2\left(g\right)\)
a) \(n_{Fe}=\dfrac{1,12}{56}=0,02\left(mol\right)\)
PTHH: Fe + 2HCl -->FeCl2 + H2
_____0,02->0,04--->0,02--->0,02
=> VH2 = 0,02.22,4 = 0,448(l)
b) mFeCl2 = 0,02.127 = 2,54(g)
c) \(C_{M\left(HCl\right)}=\dfrac{0,04}{0,2}=0,2M\)
Fe + 2HCl → FeCl2 + H2
1 2 1 1
0,02 0,04 0,02 0,02
nFe=\(\dfrac{1,12}{56}\)= 0,02(mol)
a). nH2=\(\dfrac{0,02.1}{1}\)= 0,02(mol)
→VH2= n . 22,4 = 0,02 . 22,4 = 0,448(l)
b). nFeCl2= \(\dfrac{0,02.1}{1}\)= 0,02(mol)
→mFeCl2= n . M = 0,02 . 127 = 2,54(g)
c). 200ml = 0,2l
nHCl= \(\dfrac{0,02.2}{1}\)=0,04(mol)
→CM= \(\dfrac{n}{V}\)= \(\dfrac{0,04}{0,2}\)= 0,2M
Gọi \(n_{Fe}=x\left(mol\right)\)\(;n_{Zn}=y\left(mol\right)\)
\(n_{H_2}=\dfrac{6,72}{22,4}=0,3mol\)
Ta có: \(\left\{{}\begin{matrix}56x+65y=18,6\\2x+2y=2n_{H_2}=0,6\end{matrix}\right.\)\(\Rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)
\(\%m_{Fe}=\dfrac{0,1\cdot56}{18,6}\cdot100\%=30,11\%\)
\(\%m_{Zn}=100\%-30,11\%=69,89\%\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,1 0,2
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,2 0,4
\(n_{HCl}=0,2+0,4=0,6mol\)
\(C_M=\dfrac{n}{V}=\dfrac{0,6}{0,2}=3M\)
ZnO + H2SO4 = ZnSO4 + H2O
0.1mol:2.32mol
=> H2SO4 dư theo ZnO
=> khối lượng axits tham gia: 0,1.(2+32+16.4)=9.8g
=> khối lượng muối : mZnSO4=0.1(65+32+16.4)=16.1g
nồng độ mol sau pu: CM=\(\frac{0.1}{0.58}\)=\(\frac{5}{29}\)
Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
a. PTHH: \(Zn+H_2SO_4--->ZnSO_4+H_2\uparrow\left(1\right)\)
b. Theo PT(1): \(n_{Zn}=n_{H_2}=0,3\left(mol\right)\)
\(\Rightarrow m_{Zn}=65.0,3=19,5\left(g\right)\)
c. Theo PT(1): \(n_{H_2SO_4}=n_{Zn}=0,3\left(mol\right)\)
Đổi 300ml = 0,3 lít
\(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,3}{0,3}=1M\)
d. PTHH: \(2NaOH+H_2SO_4--->Na_2SO_4+2H_2O\left(2\right)\)
Theo PT(2): \(n_{NaOH}=2.n_{H_2SO_4}=2.0,3=0,6\left(mol\right)\)
\(\Rightarrow m_{NaOH}=0,6.40=24\left(g\right)\)
\(\Rightarrow m_{dd_{NaOH}}=\dfrac{24.100\%}{20\%}=120\left(g\right)\)
a/ PTHH:
\(2CH_3COOH+Zn\rightarrow\left(CH_3COO\right)_2Zn+H_2\uparrow\)
0,9 <---- 0,45 <----- 0,45 <---- 0,45
\(n_{H_2}=\dfrac{10,08}{22,4}=0,45\left(mol\right)\)
\(m_{Zn}=0,45.65=29,25\left(g\right)\)
b/ \(C_{MddCH_3COOH}=\dfrac{0,9}{0,2}=4,5\left(M\right)\)
c/ \(CH_3COOH+NaOH\rightarrow CH_3COONa+H_2O\)
0,9 ----> 0,9 ----> 0,9
\(V_{ddNaOH}=\dfrac{0,9}{2}=0,45\left(l\right)\)
\(V_{ddCH_3COONa}=0,2+0,45=0,65\left(l\right)\)
\(C_{MddCH_3COONa}=\dfrac{0,9}{0,65}=1,385\left(M\right)\)