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Trong \(20,4g\) hỗn hợp có: \(\left\{{}\begin{matrix}n_{Zn}=a\left(mol\right)\\n_{Fe}=b\left(mol\right)\\n_{Al}=c\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow65a+56b+27c=20,4\left(1\right)\)
\(n_{H_2}=\dfrac{10,08}{22,4}=0,45mol\)
\(BTe:2n_{Zn}+2n_{Fe}+3n_{Al}=2n_{H_2}\)
\(\Rightarrow2a+2b+3c=2\cdot0,45\left(2\right)\)
Trong \(0,2mol\) hhX có \(\left\{{}\begin{matrix}Zn:ka\left(mol\right)\\Fe:kb\left(mol\right)\\Al:kc\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow ka+kb+kc=0,2\)
\(n_{Cl_2}=\dfrac{6,16}{22,4}=0,275mol\)
\(BTe:2n_{Zn}+3n_{Fe}+3n_{Al}=2n_{Cl_2}\)
\(\Rightarrow2ka+3kb+3kc=2\cdot0,275\)
Xét thương:
\(\dfrac{ka+kb+kc}{2ka+3kb+3kc}=\dfrac{0,2}{2\cdot0,275}\Rightarrow\dfrac{a+b+c}{2a+3b+3c}=\dfrac{4}{11}\)
\(\Rightarrow3a-b-c=0\left(3\right)\)
Từ (1), (2), (3)\(\Rightarrow\left\{{}\begin{matrix}a=0,1mol\\b=0,2mol\\c=0,1mol\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}m_{Zn}=6,5g\\m_{Fe}=11,2g\\m_{Al}=2,7g\end{matrix}\right.\)
PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)
Ta có: \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Theo PT: \(n_{Zn}=n_{H_2}=0,2\left(mol\right)\)
\(\Rightarrow m_{Zn}=0,2.65=13\left(g\right)\)
\(m_{ZnO}=21,1-13=8,1\left(g\right)\)
Có: \(n_{ZnO}=\dfrac{8,1}{81}=0,1\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{Zn}+2n_{ZnO}=0,6\left(mol\right)\)
\(\Rightarrow m_{HCl}=0,6.36,5=21,9\left(g\right)\Rightarrow C\%_{ddHCl}=\dfrac{21,9}{200}.100\%=10,95\%\)
Theo PT: \(n_{ZnCl_2}=n_{Zn}+n_{ZnO}=0,3\left(mol\right)\)
\(\Rightarrow m_{ZnCl_2}=0,3.136=40,8\left(g\right)\)
Bạn tham khảo nhé!
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a) \(2Al+6HCl\rightarrow2AlCl_3+3H_2\left(1\right)\\ Fe+2HCl\rightarrow FeCl_2+H_2\left(2\right)\\ 2Al+2NaOH+2H_2O\rightarrow2NaAlO_2+3H_2\)
Cho hỗn hợp tác dụng với NaOH, chất rắn không tan là Fe
=> mFe= 1,12 (g) \(\Rightarrow n_{Fe}=0,02\left(mol\right)\)
Ta có: \(n_{H_2\left(2\right)}=n_{Fe}=0,02\left(mol\right)\)
=> \(n_{H_2\left(1\right)}=\Sigma n_{H_2}-n_{H_2\left(2\right)}=0,065-0,02=0,045\left(mol\right)\)
\(\Rightarrow n_{Al}=\dfrac{2}{3}n_{H_2\left(1\right)}=0,03\left(mol\right)\)
\(\Rightarrow m_{Al}=0,03.27=0,81\left(g\right)\)
\(\Rightarrow\%m_{Al}=41,97\%,\%m_{Fe}=58,03\%\)
b) \(m_{FeCl_2}=0,02.127=2,54\left(g\right)\\ m_{AlCl_3}=0,03.133,5=4,005\left(g\right)\)
a) Fe + 2HCl --> FeCl2 + H2
FeO + 2HCl --> FeCl2 + H2O
b) \(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
______0,5<-1<------0,5<---0,5
=> mFe = 0,5.56 = 28 (g)
=> \(\left\{{}\begin{matrix}\%Fe=\dfrac{28}{100}.100\%=28\%\\\%FeO=100\%-28\%=72\%\end{matrix}\right.\)
c) \(n_{FeO}=\dfrac{72}{72}=1\left(mol\right)\)
PTHH: FeO + 2HCl --> FeCl2 + H2O
______1---->2
=> mHCl = (1+2).36,5 = 109,5 (g)
=> \(m_{ddHCl}=\dfrac{109,5.100}{30}=365\left(g\right)\)
=> \(V_{ddHCl}=\dfrac{365}{1,15}=317,39\left(ml\right)\)
\(a,n_{H_2}=\dfrac{4,48}{22,4}=0,2mol\\ Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,2 0,4 0,2 0,2
\(m_{Zn}=0,2.65=13g\\ m_{ZnO}=29,2-13=16,2g\\ b.n_{ZnO}=\dfrac{16,2}{81}=0,2mol\\ ZnO+2HCl\rightarrow ZnCl_2+H_2O\)
0,2 0,4 0,2
\(m_{HCl}=\left(0,4+0,4\right).36,5=29,2g\\ C_{\%HCl}=\dfrac{29,2}{200}\cdot100\%=14,6\%\\ c.m_{ZnCl_2}=\left(0,2+0,2\right).136=54,4g\)
Zn + 2HCl => ZnCl2 + H2 ↑ (1)
Fe + 2HCl => FeCl2 + H2 ↑ (2)
m HCl = 100.29,2% = 29,2 (g)
M HCl = 1 + 35,5 = 36,5 (g/mol)
=> n HCl = \(\dfrac{29,2}{36,5}\) = 0,8 (mol)
Goị số mol của Zn , Fe lần lượt là a , b (mol) ; (a,b > 0)
Theo phương trình (1) , n HCl (1) = 2.n Zn = 2.a (mol)
Theo phương trình (2) , n HCl (2) = 2.n Fe = 2.b (mol)
Có n HCl = n HCl (1) + n HCl (2)
=> 0,8 = 2.a + 2.b (1)
Theo phương trình (1) , n ZnCl2 = n Zn = a (mol)
M ZnCl2 = 65 + 35,5.2 = 136 (g/mol)
=> m ZnCl2 = 136.a (g)
Theo phương trình (2) , n FeCl2 = n Fe = b (mol)
M FeCl2 = 56 + 35,5.2 = 127 (g/mol)
=> m ZnCl2 = 127.b (g)
Theo bài ra , ta có :
m muối = m FeCl2 + m ZnCl2
=> 52,6 = 127.b + 136.a (2)
Từ (1) và (2) => a = 0,2 ; b = 0,2
m Zn = 0,2.65 = 13 (g)
m Fe = 0,2.56 = 11,2 (g)
=> m hỗn hợp = m Zn + m Fe = 13 + 11,2 = 24,2 (g)
=> %m Fe = \(\dfrac{11,2}{24,2}.100\%\) ≃ 46,28 %
=> %m Zn = \(\dfrac{13}{24,2}.100\%\) ≃ 53,72 %
a/ Fe + 2HCl \(\rightarrow\) FeCl2 + H2
nH2 = \(\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
Theo PTHH: nH2 = nFe = 0,15 (mol) \(\Rightarrow m_{Fe}=0,15.56=8,4\left(g\right)\)
\(\Rightarrow m_{Cu}=11-8,4=2,6\left(g\right)\)
\(\Rightarrow\%m_{Fe}=\dfrac{8,4}{11}.100\%\approx76,4\%\)
\(\Rightarrow\%m_{Cu}=100-76,4\approx23,6\%\)
b/ Theo PTHH ta có: nHCl = 2nFe = 2.0,15 = 0,3 (mol)
\(\Rightarrow V_{ddHCl}=\dfrac{0,3}{2}=0,15\left(M\right)\)
c/ mHCl = 36,5 . 0,3 = 10,95(g)
\(\Rightarrow C\%_{HCl}=\dfrac{m_{HCl}}{m_{ddHCl}}.100\%=\dfrac{10,95}{200}.100\%=5,475\%\)
Đặt nFe=a nZn=b(mol)
Từ đó suy ra \(56a+65b=25,1\left(1\right)\)
\(n_{HCl}=0,8\left(mol\right)\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ Zn+2HCl\rightarrow ZnCl_2+H_2\)
Lại suy ra được \(2a+2b=0,8\left(2\right)\)
Suy ra a=0,1 b=0,3 (mol)
\(V_{H_2}=\dfrac{0,8\cdot22,4}{2}=8,96\left(l\right)\\ m_{muoi}=m_{KL}+m_{Cl}=25,1+0,8\cdot35,5=53,5\left(g\right)\\ \%m_{Fe}=\dfrac{0,1\cdot56}{25,1}\cdot100\%\approx22,31\left(\%\right)\\ \%m_{Zn}=100\%-22,31\%=77,69\left(\%\right)\)