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PT chữ: sắt + Oxi \(\rightarrow\) Oxit sắt từ
PTHH: \(3Fe+2O_2\rightarrow Fe_3O_4\)
\(n_{Fe}=\dfrac{m}{M}=\dfrac{28}{56}=0,5\left(mol\right)\\ PTHH:Fe+2HCl->FeCl_2+H_2\)
ti le 1 : 2 : 1 : 1
n(mol) 0,5-->1--------->0,5------>0,5
\(m_{FeCl_2}=n\cdot M=0,5\cdot\left(56+35,5\cdot2\right)=63,5\left(g\right)\\ V_{H_2\left(dktc\right)}=n\cdot22,4=0,5\cdot22,4=11,2\left(l\right)\)
nFe = 33,6 : 56 = 0,6 (mol)
pthh : 3Fe + 2O2 -t--> Fe3O4
0,6--> 0,4------->0,2 (mol)
=> vO2 = 0,4.22,4 = 8,96 (mol)
=> mFe3O4 = 0,2.232 = 46,4 (g)
pthh : 2KClO3 -t--> 2KClO3 + 3O2
0,267<-----------------------0,4(mol)
mKClO3= 0,267 .122,5 = 32,67 (g)
a, \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b, Ta có: \(n_{Fe}=\dfrac{50,4}{56}=0,9\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{2}{3}n_{Fe}=0,6\left(mol\right)\Rightarrow V_{O_2}=0,6.22,4=13,44\left(l\right)\)
c, \(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=0,3\left(mol\right)\Rightarrow m_{Fe_3O_4}=0,3.232=69,6\left(g\right)\)
d, \(2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
Theo PT: \(n_{KClO_3}=\dfrac{2}{3}n_{O_2}=0,4\left(mol\right)\Rightarrow m_{KClO_3}=0,4.122,5=49\left(g\right)\)
\(n_{Fe}=\dfrac{m}{M}=\dfrac{50,4}{56}=0,9\left(mol\right)\)
\(a.PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
3 2 1
0,9 0,6 0,3
\(b.V_{O_2}=n.24,79=0,6.24,79=14,874\left(l\right)\)
\(c.m_{Fe_3O_4}=n.M=0,3.\left(56.3+16.4\right)=69,6\left(g\right)\)
\(d.V_{O_2}=14,874\left(l\right)\\ \Rightarrow n_{O_2}=\dfrac{V}{24,79}=\dfrac{14,874}{24,79}=0,6\left(mol\right)\\ PTHH:2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
2 2 3
0,6 0,6 0,9
\(m_{KClO_3}=n.M=0,6.\left(39+35,5+16.3\right)=55,5\left(g\right).\)
3Fe+2O2-to>Fe3O4
0,225--0,15
n Fe=\(\dfrac{12,6}{56}\)=0,225 mol
VO2=0,15.22,4=3,36l
2KClO3-to>2KCl+3O2
0,1---------------------0,15
=>m KClO3=0,1.122,5=12,25g
\(a,3Fe+2O_2\rightarrow Fe_3O_4\)
\(b,\)
Ta có : \(n_{Fe}=\dfrac{m}{M}=\dfrac{126}{56}=2,25\left(mol\right)\)
\(\Rightarrow n_{O_2}=\dfrac{2}{3}n_{Fe}=\dfrac{2}{3}.2,25=1,5\left(mol\right)\)
\(\Rightarrow VO_2=33,6\left(l\right)\)
\(c,\)
\(PTHH:2KClO_3\rightarrow2KCl+3O_2\)
Theo \(PTHH:n_{KClO_3}=\dfrac{2}{3}n_{O_2}=\dfrac{2}{3}.1,5=1\left(mol\right)\)
\(\Rightarrow m_{KClO_3}=n.M=1,122,5=122,5\left(g\right)\)
Sắt + oxygen \(\rightarrow\) Gỉ sắt
Phương trình bảo toàn khối lượng :
msắt + moxygen = mgỉ sắt
=> moxygen = 31.2 - 28 = 3.2(g)
\(V_{O_2}=\dfrac{3.2}{32}\cdot24.79=2.479\left(l\right)\)