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\(n_{H_2}=\dfrac{13.44}{22.4}=0.6\left(mol\right)\)
\(2R+2nHCl\rightarrow2RCl_n+nH_2\)
\(\dfrac{1.2}{n}......1.2...............0.6\)
\(M_R=\dfrac{14.4}{\dfrac{1.2}{n}}=12n\)
\(BL:n=2\Rightarrow R=24\)
\(R:Mg\)
\(m_{MgCl_2}=0.6\cdot95=57\left(g\right)\)
\(m_{dd}=14.4+146-0.6\cdot2=159.2\left(g\right)\)
\(C\%_{MgCl_2}=\dfrac{57}{159.2}\cdot100\%=35.8\%\)
a)\(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
PTHH: 2Al + 3H2SO4 → Al2(SO4)3 + 3H2
Mol: x 1,5x
PTHH: Mg + H2SO4 → MgSO4 + H2
Mol: y y
Ta có: \(\left\{{}\begin{matrix}27x+24y=5,1\\1,5x+y=0,25\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,1\end{matrix}\right.\)
\(\%m_{Al}=\dfrac{0,1.27.100\%}{5,1}=52,94\%;\%m_{Mg}=100-52,94=47,06\%\)
b)
PTHH: 2Al + 3H2SO4 → Al2(SO4)3 + 3H2
Mol: 0,1 0,15 0,05
PTHH: Mg + H2SO4 → MgSO4 + H2
Mol: 0,1 0,1 0,1
\(m_{ddH_2SO_4}=\dfrac{\left(0,1+0,15\right).98.100}{9,8}=250\left(g\right)\)
mdd sau pứ = 5,1+250-0,15.2 = 254,8(g)
\(C\%_{ddAl_2\left(SO_4\right)_3}=\dfrac{0,05.342.100\%}{254,8}=6,71\%\)
\(C\%_{ddMgSO_4}=\dfrac{0,1.120.100\%}{254,8}=4,71\%\)
a, \(n_{H_2}=0,09\left(mol\right)\)
BT e, có: 2nX = 2nH2 ⇒ nX = 0,09 (mol)
\(\Rightarrow\overline{M}_X=\dfrac{2,64}{0,09}=29,33\left(g/mol\right)\)
Mà: A, B thuộc 2 chu kì liên tiếp.
→ Mg và Ca.
Ta có: \(\left\{{}\begin{matrix}24n_{Mg}+40n_{Ca}=2,64\\2n_{Mg}+2n_{Ca}=0,09.2\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{Mg}=0,06\left(mol\right)\\n_{Ca}=0,03\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{0,06.24}{2,64}.100\%\approx54,55\%\\\%m_{Ca}\approx45,45\%\end{matrix}\right.\)
b, BTNT H, có: \(n_{H_2SO_4}=n_{H_2}=0,09\left(mol\right)\Rightarrow V_{ddH_2SO_4}=\dfrac{0,09}{2}=0,045\left(l\right)\)
BTNT Mg: nMgSO4 = nMg = 0,06 (mol)
\(\Rightarrow C_{M_{MgSO_4}}=\dfrac{0,06}{0,045}=\dfrac{4}{3}\left(M\right)\)
a, \(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
BT e, có: 3nFe = 2nSO2 ⇒ nSO2 = 0,45 (mol)
⇒ VSO2 = 0,45.22,4 = 10,08 (l)
b, BTNT Fe, có: nFe(OH)3 = nFe = 0,3 (mol)
⇒ mFe(OH)3 = 0,3.107 = 32,1 (g)
\(Đặt.kim.loại.kiềm:A\\ 2A+2HCl\rightarrow2ACl+H_2\\ m_{muối}-m_{kl}=m_{Cl^-}\\ \Leftrightarrow m_{Cl^-}=7,45-3,9=3,55\left(g\right)\\ \Rightarrow n_{HCl}=n_{Cl^-}=\dfrac{3,55}{35,5}=0,1\left(mol\right)\\ \Rightarrow n_A=n_{ACl}=n_{HCl}=0,1\left(mol\right)\\ a,M_A=\dfrac{3,9}{0,1}=39\left(\dfrac{g}{mol}\right)\\ \Rightarrow A\left(I\right):Kali\left(K=39\right)\\ b,n_{H_2}=\dfrac{n_{HCl}}{2}=\dfrac{0,1}{2}=0,05\left(mol\right)\\ \Rightarrow V_{H_2\left(đktc\right)}=0,05.22,4=1,12\left(l\right)\\ c,m_{ddHCl}=\dfrac{0,1.36,5.100}{31,7}=\dfrac{3650}{317}\left(g\right)\\ \Rightarrow V_{ddHCl}=\dfrac{\dfrac{3650}{317}}{1,15}\approx10,012\left(g\right)\)
Chị ơi em không hiểu lắm chị có thể giải rõ ra hơn được k ạ:(