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nZn=\(\dfrac{19.5}{65}\)=0.3(mol)
nH2SO4=\(\dfrac{39.2}{98}\)=0.4(mol)
PTHH:
Zn + H2SO4 --> ZnSO4 + H2
B/đ`:0.3 0.4 0 0
P/ứ: 0.3-->0.3--->0.3-->0.3
SauP/ứ:0 0.1 0.3 0.3
=> PTHH => khí thu đc sau p/ứ là : H2
=> VH2(đktc)=0.3*22.4=6.72(l)
Đặt nCuO=a (mol) ; nFe3O4= b (mol)
PTHH:
CuO + H2 --> Cu + H2O (1)
P/ứ: a --------->a (mol)
Fe3O4 + 4H2 --> 3Fe + 4H2O (2)
P/ứ: b ------------> b (mol)
Vì sau khi nung hỗn hợp thì H2O thoát ra và chất còn lại là Fe và Cu
=> m hh A giảm = m H2O
Từ PTHH: (1);(2)
=> nH2O=nH2= 0.3(mol)
=> mH2O=0.3*18=5.4(g)
=> m = 5.4 (g)
a, PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
\(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
Ta có: \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Theo PT: \(n_{Fe}=n_{H_2}=0,2\left(mol\right)\)
\(\Rightarrow m_{Cu}=24-m_{Fe}=12,8\left(g\right)\) \(\Rightarrow n_{Cu}=\dfrac{12,8}{64}=0,2\left(mol\right)\)
Theo PT: \(\left\{{}\begin{matrix}n_{CuO}=n_{Cu}=0,2\left(mol\right)\\n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe}=0,1\left(mol\right)\end{matrix}\right.\)
⇒ m = mCuO + mFe2O3 = 0,2.80 + 0,1.160 = 32 (g)
b, \(\left\{{}\begin{matrix}\%m_{CuO}=\dfrac{0,2.80}{32}.100\%=50\%\\\%m_{Fe_2O_3}=50\%\end{matrix}\right.\)
c, Theo PT: \(n_{H_2}=n_{CuO}+3n_{Fe_2O_3}=0,5\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,5.22,4=11,2\left(l\right)\)
\(n_{Mg}=2x\left(mol\right),n_{Fe}=x\left(mol\right)\)
\(n_{HCl}=0.2\cdot0.45=0.9\left(mol\right)\)
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(n_{HCl}=2\cdot2x+2\cdot x=0.9\left(mol\right)\)
\(\Rightarrow x=0.15\)
\(m_{hh}=0.3\cdot24+0.15\cdot56=15.6\left(g\right)\)
\(V_{H_2}=0.45\cdot22.4=10.08\left(l\right)\)
Đặt \(\left\{{}\begin{matrix}n_{Al}=x\\n_{Zn}=y\\n_{Cu}=z\end{matrix}\right.\) ( mol )
\(m_{hh}=27x+65y+64z=22,8\left(g\right)\) (1)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
x 1,5x ( mol )
\(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
y y ( mol )
\(n_{H_2}=1,5x+y=\dfrac{11,2}{22,4}=0,5\left(mol\right)\) (2)
B là Cu
\(2Cu+O_2\rightarrow\left(t^o\right)2CuO\)
z z ( mol )
\(n_{CuO}=z=\dfrac{5,5}{80}=0,06875\left(mol\right)\) (3)
\(\left(1\right);\left(2\right);\left(3\right)\Rightarrow\left\{{}\begin{matrix}x=0,2\\y=0,2\\z=0,06875\end{matrix}\right.\)
\(\left\{{}\begin{matrix}m_{Al}=0,2.27=5,4\left(g\right)\\m_{Zn}=0,2.65=13\left(g\right)\\m_{Cu}=22,8-5,4-13=4,4\left(g\right)\end{matrix}\right.\)
Gọi $n_{Na} = a(mol)$
2Na + 2H2O → 2NaOH + H2
a...........................a..........0,5a.....(mol)
2Al + 2NaOH + 2H2O → 2NaAlO2 + 3H2
..a...........a............................................1,5a....(mol)
Suy ra : $0,5a + 1,5a = \dfrac{3,36}{22,4} = 0,15 \Rightarrow a = 0,075$
Vậy :
$m = 0,075.23 + 0,075.27 + 1,35 = 5,1(gam)$
Gọi nNa=a(mol)���=�(���)
2Na + 2H2O → 2NaOH + H2
a...........................a..........0,5a.....(mol)
2Al + 2NaOH + 2H2O → 2NaAlO2 + 3H2
..a...........a............................................1,5a....(mol)
Suy ra : 0,5a+1,5a=3,3622,4=0,15⇒a=0,0750,5�+1,5�=3,3622,4=0,15⇒�=0,075
Vậy :
m=0,075.23+0,075.27+1,35=5,1(gam)
a) nMg= 2,4/24=0,1(mol); nAl=5,4/27=0,2(mol)
PTHH: Mg + H2SO4 -> MgSO4 + H2
0,1__________0,1_____0,1____0,1(mol)
PTHH: 2Al + 3 H2SO4 -> Al2(SO4)3 +3 H2
0,2_________0,3_______0,1________0,3(mol)
nH2SO4(tổng)=nH2(tổng)=0,1+0,3=0,4(mol)
V(H2,đktc)=(0,1+0,3).22,4=8,96(l)
b) mH2SO4=39,2(g)
CMddH2SO4=0,3/0,1=3(M)
=> C%ddH2SO4= (CMddH2SO4 .M(H2SO4) ) /(10D)= (3.98)/(10.1,2)=24,5%
Chúc em học tốt!