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Ta có: \(n_{H_2}=\dfrac{10,08}{22,4}=0,45\left(mol\right)\)
PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
a, \(n_{Fe}=n_{H_2}=0,45\left(mol\right)\Rightarrow m_{Fe}=0,45.56=25,2\left(g\right)\)
b, \(n_{HCl}=2n_{H_2}=0,9\left(mol\right)\) \(\Rightarrow C_{M_{HCl}}=\dfrac{0,9}{0,15}=6\left(M\right)\)
c, \(FeCl_2+2NaOH\rightarrow Fe\left(OH\right)_2+2NaCl\)
\(4Fe\left(OH\right)_2+O_2\underrightarrow{t^o}2Fe_2O_3+4H_2O\)
Theo PT: \(n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_2}=\dfrac{1}{2}n_{FeCl_2}=\dfrac{1}{2}n_{H_2}=0,225\left(mol\right)\)
\(\Rightarrow m_{Fe_2O_3}=0,225.160=36\left(g\right)\)
\(m_{NaOH}=\dfrac{200\cdot8}{100}=16\left(g\right)\Rightarrow n_{NaOH}=\dfrac{16}{40}=0,4mol\)
\(NaOH+HCl\rightarrow NaCl+H_2O\)
0,4 0,4 0,4 0,4
a)\(m_{HCl}=0,4\cdot36,5=14,6\left(g\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{14,6}{7,3}\cdot100=200\left(g\right)\)
b)\(m_{NaCl}=0,4\cdot58,5=23,4\left(g\right)\)
\(m_{H_2O}=0,4\cdot18=7,2\left(g\right)\)
\(m_{ddsau}=200+200-7,2=392,8\left(g\right)\)
\(\Rightarrow C\%=\dfrac{23,4}{392,8}\cdot100=5,96\%\)
c) \(n_{SO_2}=\dfrac{6,72}{22,4}=0,3mol\)
\(2NaOH+SO_2\rightarrow Na_2SO_4+H_2O\)
0,4 0,3 0,3 0,3
\(m_{Na_2SO_4}=0,3\cdot142=42,6\left(g\right)\)
\(CH_3COOH+NaCl\rightarrow CH_3COONa+HCl\)
\(2CH_3COOH+CaCO_3\rightarrow\left(CH_3COO\right)_2Ca+H_2O+CO_2\)
2 1 1 1 1 (mol)
0,08 0,04 0,04 0,04 0,04 (mol)
\(nCO_2=\dfrac{0,896}{22,4}=0,04\left(mol\right)\)
\(mCaCO_3=0,04.100=4\left(g\right)\)
=> \(mNaCl=12,5-4=8,5\left(g\right)\)
( không thấy hh B )
c ) .
\(CO_2+2NaOH\rightarrow Na_2CO_3+H_2O\)
1 2 1 1 (mol)
0,04 0,08 0,04 0,04 (mol)
\(mNa_2CO_3=0,04.106=4,24\left(g\right)\)
\(mNa_2CO_{3\left(thựctế\right)}=\)\(\dfrac{4,24.85\%}{100\%}=3,604\left(g\right)\)
\(PTHH:CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\uparrow\\ CO_2+2NaOH\rightarrow Na_2CO_3+H_2O\\ n_{CO_2}=\dfrac{26,88}{22,4}=1,2\left(mol\right)\\ \Rightarrow n_{Na_2CO_3}=1,2\left(mol\right)\\ \Rightarrow m_{muối}=m_{Na_2CO_3}=1,2\cdot106=127,2\left(g\right)\)
a) \(n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH: 2HCl + CaCO3 → CaCl2 + CO2 + H2O
Mol: 0,4 0,2 0,2
b) \(C\%_{ddHCl}=\dfrac{0,4.36,5.100\%}{100}=14,6\%\)
c) \(m_{CaCl_2}=0,2.101=20,2\left(g\right)\)
a) \(n_{CO_2}=\dfrac{0,4958}{24,79}=0,02\left(mol\right);n_{HCl}=0,6.1=0,6\left(mol\right)\)
PTHH: \(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\)
0,02<------0,04<----0,02<-----0,02
\(\Rightarrow n_{HCl\left(p\text{ư}\right)}< n_{HCl\left(b\text{đ}\right)}\left(0,04< 0,6\right)\Rightarrow HCl\) dư, \(CaCO_3\) tan hết
\(\Rightarrow\left\{{}\begin{matrix}m_{CaCO_3}=0,02.100=2\left(g\right)\\m_{CaSO_4}=5-2=3\left(g\right)\end{matrix}\right.\)
b) dd sau phản ứng có: \(\left\{{}\begin{matrix}n_{HCl\left(d\text{ư}\right)}=0,6-0,04=0,56\left(mol\right)\\n_{CaCl_2}=0,02\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}C_{M\left(HCl\left(d\text{ư}\right)\right)}=\dfrac{0,56}{0,6}=\dfrac{14}{15}M\\C_{M\left(CaCl_2\right)}=\dfrac{0,02}{0,6}=\dfrac{1}{30}M\end{matrix}\right.\)