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\(Coi: n_{Cl_2} = 1(mol) \to n_{O_2} = 2(mol)\\ \%V_{Cl_2} = \dfrac{1}{1+2}.100\% = 33,33\%\\ \%V_{O_2} = 100\% -33,33\% = 66,67\%\\ M_A = \dfrac{1.71+2.32}{1+2}=45(g/mol)\\ d_{A/H_2} = \dfrac{45}{2} = 22,5\)
\(\text{Trong 6,72 lít khí A : }m_A = 45.\dfrac{6,72}{22,4}=13,5(gam)\)
Giả sử có 1 mol khí Cl2, 2 mol khí O2
a) \(\left\{{}\begin{matrix}\%V_{Cl_2}=\dfrac{1}{1+2}.100\%=33,33\%\\\%V_{O_2}=\dfrac{2}{1+2}.100\%=66,67\%\end{matrix}\right.\)
\(\left\{{}\begin{matrix}\%m_{Cl_2}=\dfrac{1.71}{1.71+2.32}.100\%=52,59\%\\\%m_{O_2}=\dfrac{2.32}{1.71+2.32}.100\%=47,41\%\end{matrix}\right.\)
b) \(\overline{M}=\dfrac{1.71+2.32}{1+2}=45\left(g/mol\right)\)
=> \(d_{A/H_2}=\dfrac{45}{2}=22,5\)
c) \(n_A=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
=> mA = 0,3.45 = 13,5 (g)
a)
$n_{Cl_2} : n_{O_2} = 1 : 2$
Suy ra :
$\%V_{Cl_2} = \dfrac{1}{1 + 2}.100\% = 33,33\%$
$\%V_{O_2} = \dfrac{2}{1 + 2}.100\% = 66,67\%$
b)
Coi $n_{Cl_2} = 1 (mol) \Rightarrow n_{O_2} = 2(mol)$
$\%m_{Cl_2} = \dfrac{1.71}{1.71 + 2.32}.100\% = 52,59\%$
$\%m_{O_2} = 100\% -52,59\% = 47,41\%$
c)
$M_A = \dfrac{71.1 + 32.2}{1 + 2} = 45(g/mol)$
$d_{A/B} = \dfrac{45}{28} = 1,607$
Gọi số mol của CO là \(a\left(mol\right)\) \(\Rightarrow\left\{{}\begin{matrix}n_{H_2}=2a\left(mol\right)=n_{NH_3}\\n_{O_2}=5,5a\left(mol\right)\end{matrix}\right.\)
Theo đề bài: \(a+2a+2a+5,5a=\dfrac{2,352}{22,4}=0,105\left(mol\right)\) \(\Rightarrow a=0,01\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{CO}=\dfrac{0,01}{0,105}\approx9,52\%\\\%V_{H_2}=\%V_{NH_3}=\dfrac{2\cdot0,01}{0,105}\approx19,05\%\\\%V_{O_2}=52,38\%\end{matrix}\right.\)
Mặt khác: \(\overline{M}_{khí}=\dfrac{0,01\cdot28+0,02\cdot2+0,02\cdot17+0,055\cdot32}{0,105}=23,05\) \(\Rightarrow d_{A/H_2}=\dfrac{23,05}{2}=11,525\)
*Phần tính % khối lượng bạn tự làm nhé, mình tính số mol ra rồi
Áp dụng quy tắc đường chéo:
\(a.\\ \Rightarrow\dfrac{V_{Cl_2}}{V_{O_2}}=\dfrac{15,6}{23,4}=\dfrac{2}{3}\\ \Rightarrow\left\{{}\begin{matrix}\%V_{Cl_2}=40\%\\\%V_{O_2}=60\%\end{matrix}\right.\)
\(b.\)
Ta có: \(\dfrac{n_{Cl_2}}{n_{O_2}}=\dfrac{2}{3}\Leftrightarrow\dfrac{m_{Cl_2}}{m_{O_2}}=\dfrac{71.2}{32.3}=\dfrac{71}{48}\Leftrightarrow48m_{Cl_2}-71m_{O_2}=0\)
Mặt khác: \(m_{Cl_2}+m_{O_2}=5,95\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Cl_2}=3,55\left(g\right)\\m_{O_2}=2,4\left(g\right)\end{matrix}\right.\)
a) \(\overline{M}_A=5,875.2=11,75\left(g/mol\right)\)
b) Gọi số mol N2, H2 là a, b (mol)
\(\overline{M}_A=\dfrac{28a+2b}{a+b}=11,75\left(g/mol\right)\)
=> 16,25a = 9,75b
=> a = 0,6b
\(\left\{{}\begin{matrix}\%n_{N_2}=\dfrac{a}{a+b}.100\%=\dfrac{0,6b}{0,6b+b}.100\%=37,5\%\\\%n_{H_2}=\dfrac{b}{a+b}.100\%=\dfrac{b}{0,6b+b}.100\%=62,5\%\end{matrix}\right.\)
c)
1 mol hỗn hợp A chứa \(\left\{{}\begin{matrix}n_{N_2}=\dfrac{1.37,5}{100}=0,375\left(mol\right)\\n_{H_2}=\dfrac{1.62,5}{100}=0,625\left(mol\right)\end{matrix}\right.\)
\(\overline{M}_B=\dfrac{0,375.28+0,625.2+17x}{1+x}=6,4.2=12,8\left(g/mol\right)\)
=> x = 0,25 (mol)
a) \(\left\{{}\begin{matrix}n_{Cl_2}+n_{O_2}=\dfrac{6,72}{22,4}=0,3\\\overline{M}=\dfrac{71.n_{Cl_2}+32.n_{O_2}}{n_{Cl_2}+n_{O_2}}=2.29=58\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}n_{Cl_2}=0,2\left(mol\right)\\n_{O_2}=0,1\left(mol\right)\end{matrix}\right.\)
\(\left\{{}\begin{matrix}\%V_{Cl_2}=\dfrac{0,2}{0,3}.100\%=66,67\%\\\%V_{O_2}=\dfrac{0,1}{0,3}.100\%=33,33\%\end{matrix}\right.\)
b) \(\left\{{}\begin{matrix}m_{Cl_2}=0,2.71=14,2\left(g\right)\\m_{O_2}=0,1.32=3,2\left(g\right)\end{matrix}\right.\)
nA = 6.72/22.4 = 0.3 (mol)
=> nH2 = 0.1 ( mol )
nO2 = 0.2 ( mol )
%VH2 = 0.1 / 0.3 * 100% = 33.33%
%VO2 = 66.67%
%mH2 = 0.1 * 2 / ( 0.1 * 2 + 0.2 * 32 ) * 100% = 3.03%
%mO2 = 96.67%
d A / H2 = ( 0.1 * 2 + 0.2 * 32) / 0.3 : 2 = 11