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Đặt: \(n_{Zn}=a\left(mol\right);n_{ZnO}=b\left(mol\right)\left(a,b>0\right)\)
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
\(a.Zn+2HCl\rightarrow ZnCl_2+H_2\\ ZnO+2HCl\rightarrow ZnCl_2+H_2O\\ \Rightarrow\left\{{}\begin{matrix}65a+81b=14,6\\a=0,1\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\\ b.m_{Zn}=0,1.65=6,5\left(g\right)\\ m_{ZnO}=0,1.81=8,1\left(g\right)\\ d.m_{ddHCl}=\dfrac{\left(0,1+0,1\right).2.36,5.100}{7,3}=200\left(g\right)\)
a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)
b, Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Theo PT: \(n_{Zn}=n_{H_2}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,1.65}{10}.100\%=65\%\\\%m_{ZnO}=35\%\end{matrix}\right.\)
c, \(n_{HCl}=0,1.0,5=0,05\left(mol\right)\)
\(n_{NaOH}=0,03.1=0,03\left(mol\right)\)
PT: \(HCl+NaOH\rightarrow NaCl+H_2O\)
Xét tỉ lệ: \(\dfrac{0,05}{1}>\dfrac{0,03}{1}\), ta được HCl dư.
→ Quỳ tím chuyển đỏ do acid dư.
nH2=0,1(mol)
PTHH: Mg + 2 HCl -> MgCl2 + H2
0,1__________0,2___________0,1(mol)
MgO + 2 HCl -> MgCl2 + H2O
0,05____0,1___0,05(mol)
mMg=0,1. 24= 2,4(g) -> mMgO=4,4-2,4= 2(g) -> nMgO=0,05((mol)
b) %mMg= (2,4/4,4).100=54,545%
=> %mMgO=45,455%
c) nHCl=0,3(mol) -> mHCl=0,3.36,5=10,95(g)
=> mddHCl=(10,95.100)/7,3=150(g)
\(n_{H2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Pt : \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2|\)
1 1 1 1
0,1 0,1 0,1
\(ZnO+H_2SO_4\rightarrow ZnSO_4+H_2O|\)
1 1 1 1
0,1 0,1
a) \(n_{Zn}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)
\(m_{Zn}=0,1.65=6,5\left(g\right)\)
\(m_{ZnO}=14,6-6,5=8,1\left(g\right)\)
b) Có : \(m_{MgO}=8,1\left(g\right)\)
\(n_{ZnO}=\dfrac{8,1}{81}=0,1\left(mol\right)\)
\(n_{H2SO4\left(tổng\right)}=0,1+0,1=0,2\left(mol\right)\)
\(V_{ddH2SO4}=\dfrac{0,2}{2}=0,1\left(l\right)\)
Chúc bạn học tốt
C32:
a, \(n_C=\dfrac{2,4}{12}=0,2\left(mol\right)\)
PT: \(C+O_2\underrightarrow{t^o}CO_2\)
Theo PT: \(n_{CO_2}=n_C=0,2\left(mol\right)\Rightarrow V_{CO_2}=0,2.22,4=4,48\left(l\right)\)
b, \(n_{NaOH}=0,3.1=0,3\left(mol\right)\)
\(\Rightarrow\dfrac{n_{NaOH}}{n_{CO_2}}=1,5\) → Pư tạo NaHCO3 và Na2CO3
PT: \(CO_2+NaOH\rightarrow NaHCO_3\)
\(CO_2+2NaOH\rightarrow Na_2CO_3+H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{CO_2}=n_{NaHCO_3}+n_{Na_2CO_3}=0,2\\n_{NaOH}=n_{NaHCO_3}+2n_{Na_2CO_3}=0,3\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}n_{NaHCO_3}=0,1\left(mol\right)\\n_{Na_2CO_3}=0,1\left(mol\right)\end{matrix}\right.\)
⇒ mNaHCO3 = 0,1.84 = 8,4 (g)
mNa2CO3 = 0,1.106 = 10,6 (g)
c, \(C_{M_{NaHCO_3}}=C_{M_{Na_2CO_3}}=\dfrac{0,1}{0,3}=\dfrac{1}{3}\left(M\right)\)
Lần sau bạn đăng tách câu hỏi ra nhé.
C31:
a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)
b, \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Theo PT: \(n_{Zn}=n_{H_2}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,1.65}{14,6}.100\%\approx44,52\%\\\%m_{ZnO}\approx55,48\%\end{matrix}\right.\)
c, \(n_{ZnO}=\dfrac{14,6-0,1.65}{81}=0,1\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{Zn}+2n_{ZnO}=0,4\left(mol\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{0,4.36,5}{10\%}=146\left(g\right)\)
a) $Zn + 2HCl \to ZnCl_2 + H_2$
$ZnO + 2HCl \to ZnCl_2 + H_2O$
b)
Theo PTHH : $n_{Zn} = n_{H_2} = \dfrac{4,48}{22,4} = 0,2(mol)$
$m_{Zn} = 0,2.65 = 13(gam)$
$m_{ZnO} = 21,1 - 13 = 8,1(gam)$
c) $n_{ZnO} = 0,1(mol)$
Theo PTHH : $n_{HCl} = 2n_{Zn} + 2n_{ZnO} = 0,6(mol)$
$m_{dd\ HCl} = \dfrac{0,6.36,5}{16,6\%} = 132(gam)$
d) $m_{dd\ sau\ pư} = 21,1 + 132 - 0,2.2 = 152,7(gam)$
$n_{ZnCl_2} = n_{Zn} + n_{ZnO} = 0,3(mol)$
$C\%_{ZnCl_2} = \dfrac{0,3.136}{152,7}.100\% = 26,72\%$
\(a,PTHH:Zn+2HCl\to ZnCl_2+H_2\\ ZnO+2HCl\to ZnCl_2+H_2O\\ b,n_{H_2}=\dfrac{3,36}{22,4}=0,15(mol)\\ \Rightarrow n_{Zn}=0,15(mol)\Rightarrow m_{Zn}=0,15.65=9,75(g)\\ \Rightarrow \%_{Zn}=\dfrac{9,75}{25,95}.100\%=37,57\%\\ \Rightarrow \%_{ZnO}=(100-37,57)\%=62,43\%\\ c,n_{ZnO}=\dfrac{25,95-9,75}{81}=0,2(mol)\\ \Rightarrow n_{HCl}=2.0,15+2.0,2=0,7(mol)\\ \Rightarrow m_{dd_{HCl}}=\dfrac{0,7.36,5}{12\%}=212,92(g)\)
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
a.
\(CuO+2HCl\rightarrow CuCl_2+H_2O\)
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
b.
\(n_{Mg}=n_{H_2}=0,1\left(mol\right)\Rightarrow m_{Mg}=0,1.24=2,4\left(g\right),m_{CuO}=12-2,4=9,6\left(g\right)\)
c.
\(m_{muối}=m_{CuCl_2}+m_{MgCl_2}=0,12.135+95.0,1=25,7\left(g\right)\)
nH2=0,1mol
Zn + 2HCl -----> ZnCl2 + H2
0,1 mol 0,1 mol
mZn=0,1.65=6,5g
mZnO=14,6-6,5=8,1g
%mZn=\(\frac{6,5}{14,6}\).100=44,5%
%mZnO=55,5%