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a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Zn}=0,2\left(mol\right)\Rightarrow V_{H_2}=0,2.22,4=4,48\left(l\right)\)
c, \(n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right)\Rightarrow m_{ZnCl_2}=0,2.136=27,2\left(g\right)\)
d, \(n_{HCl}=2n_{Zn}=0,4\left(mol\right)\Rightarrow m_{HCl}=0,4.36,5=14,6\left(g\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{14,6}{7,3\%}=200\left(g\right)\)
⇒ m dd sau pư = 13 + 200 - 0,2.2 = 212,6 (g)
\(\Rightarrow C\%_{ZnCl_2}=\dfrac{27,2}{212,6}.100\%\approx12,79\%\)
\(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\\ a,Fe+2HCl\rightarrow FeCl_2+H_2\\ b,n_{HCl}=0,4.2=0,8\left(mol\right)\\ m_{HCl}=0.8.36,5=29,2\left(g\right)\\ c,n_{H_2}=n_{FeCl_2}=n_{Fe}=0,4\left(mol\right)\\ m_{FeCl_2}=0,4.127=50,8\left(g\right)\\ d,V_{H_2\left(dktc\right)}=0,4.22,4=8,96\left(l\right)\)
\(n_{H_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\\
PTHH:Ba+2H_2O\rightarrow Ba\left(OH\right)_2+H_2\)
0,05 0,05
\(\rightarrow m=0,05.137=6,85\left(g\right)\)
\(n_{H_2}=\dfrac{4,032}{22,4}=0,18\left(mol\right)\)
PTHH: Fe + H2SO4 ---> FeSO4 + H2
0,18 <------------------------ 0,18
\(\rightarrow n_O=\dfrac{13,92-0,18.56}{16}=0,24\left(mol\right)\)
CTHH: FexOy
=> x : y = 0,18 : 0,24 = 3 : 4
CTHH Fe3O4
\(V_{H_2\left(đktc\right)}=\dfrac{4,032}{22,4}=0,18\left(mol\right)\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)
1 : 1 (mol)
0,18 : 0,18 (mol)
\(yCO+Fe_xO_y\rightarrow^{t^0}xFe+yCO_2\uparrow\)
1 : x (mol)
\(\dfrac{0,18}{x}\) 0,18 (mol)
\(M_{Fe_xO_y}=\dfrac{m}{n}=\dfrac{13,92}{\dfrac{0,18}{x}}=\dfrac{232}{3}x\)
\(\Rightarrow56x+16y=\dfrac{232}{3}x\)
\(\Rightarrow16y=\dfrac{64}{3}x\)
\(\Rightarrow\dfrac{x}{y}=\dfrac{16}{\dfrac{64}{3}}=\dfrac{3}{4}\Rightarrow x=3;y=4\)
-Vậy CTHH của oxit sắt là Fe3O4
\(n_{Zn}=\dfrac{13}{65}=0,2mol\)
\(n_{H_2SO_4}=\dfrac{49}{98}=0,5mol\)
\(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
0,2 < 0,5 ( mol )
0,2 0,2 0,2 ( mol )
\(V_{H_2}=0,2.22,4=4,48l\)
\(m_{ZnSO_4}=0,2.161=32,2g\)
Bn giải cho mk bài này nữa với