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\(a)n_{H_2}=\dfrac{8,96}{22,4}=0,4mol\\ n_{Fe}=a;n_{Al}=b\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(\Rightarrow\left\{{}\begin{matrix}56a+27b=11\\a+1,5b=0,4\end{matrix}\right.\\ \Rightarrow a=0,1;b=0,2\)
\(\%m_{Fe}=\dfrac{0,1.56}{11}\cdot100=50,91\%\\ \%m_{Al}=100-50,91=49,09\%\)
\(b)Fe+2HCl\rightarrow FeCl_2+H_2\)
0,1 0,2 0,1 0,1
\(2Al+6HCl\rightarrow2AlCl_2+3H_2\)
0,2 0,6 0,2 0,3
\(m_{HCl}=\dfrac{\left(0,2+0,6\right).36,5}{9,125}\cdot100=320g\)
\(c)m_{dd}=320+11-0,1.2-0,3.2=308,2g\)
\(C_{\%FeCl_2}=\dfrac{0,1.127}{308,2}\cdot100=4,12\%\\ C_{\%AlCl_3}=\dfrac{0,2.133,5}{308,2}\cdot100=8,66\%\)
thôi thì mình làm cho bn vậy, câu a ko làm dc đâu, làm câu b thôi, làm sao biết dc chất nào dư khi chỉ có số mol 1 chất?
nK2SO3=0.1367(mol)
mddH2SO4=Vdd.D=200.1,04=208(g)
K2SO3+H2SO4-->K2SO4+H2O+SO2
0.1367----0.1367----0.1367---------0.1367 (mol)
mddspu=100+208-0,1367.64=299.2512(g) ; mK2SO4=0,1367.174=23.7858(g)
==>C%=23.7858.100/299.512=7.94%
2)pt bn tự ghi nhé
ta có hệ pt: 56a+27b=11 và a+3b/2=8.96/22.4==>a=0.1, b=0.2
==>%Fe=0.1x56x100/11=50.9%
%Al=100%-50.9%=49.1%
b)nH2SO4= 0.7(mol)==>VddH2SO4=0.7/2=0.35(L)
a)
Gọi $n_{Fe} = a(mol) ; n_{Al} =b (mol) \Rightarrow 56a + 27b = 11(1)$
$Fe + 2HCl \to FeCl_2 + H_2$
$2Al + 6HCl \to 2AlCl_3 + 3H_2$
Theo PTHH : $n_{H_2} = a + 1,5b = \dfrac{8,96}{22,4} = 0,4(2)$
Từ (1)(2) suy ra : a = 0,1 ; b = 0,2
$\%m_{Fe} = \dfrac{0,1.56}{11}.100\% = 50,9\%$
$\%m_{Al} = 100\% - 50,9\% = 49,1\%$
b) $n_{HCl} = 2n_{H_2} = 0,8(mol)$
$\Rightarrow C_{M_{HCl}} = \dfrac{0,8}{0,4} = 2M$
c)
$C_{M_{FeCl_2}} = \dfrac{0,1}{0,4} = 0,25M$
$C_{M_{AlCl_3}} =\dfrac{0,2}{0,4} = 0,5M$
a) \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
Gọi \(\left\{{}\begin{matrix}n_{Al}:x\left(mol\right)\\n_{Fe}:y\left(mol\right)\end{matrix}\right.\)
Ta có : \(\left\{{}\begin{matrix}27x+56y=11\\1,5x+y=0,4\end{matrix}\right.\)
=> x=0,2 ; y=0,1
\(\%m_{Al}=\dfrac{0,2.27}{11}.100==49,09\%\)
\(\%m_{Fe}=50,91\%\)
b) \(\Sigma n_{HCl}=3x+2y=0,8\left(mol\right)\)
=> \(V_{HCl}=\dfrac{0,8}{2}=0,4\left(lít\right)\)
c) \(CM_{AlCl_3}=\dfrac{0,2}{0,4}=0,5M\)
\(CM_{FeCl_2}=\dfrac{0,1}{0,4}=0,25M\)
\(\text{Đặt }n_{Al}=x(mol);n_{Fe}=y(mol)\\ \Rightarrow 27x+56y=13,9(1)\\ n_{H_2}=\dfrac{7,84}{22,4}=0,35(mol)\\ a,PTHH:2Al+6HCl\to 2AlCl_3+3H_2(1)\\ Fe+2HCl\to FeCl_2+H_2(2)\\ b,\text{Từ 2 PT: }1,5x+y=0,35(2)\\ (1)(2)\Rightarrow x=0,1(mol);y=0,2(mol)\\ \Rightarrow m_{Al}=0,1.27=2,7(g)\\ m_{Fe}=0,2.56=11,2(g)\)
\(c,n_{HCl(1)}=3n_{Al}=0,3(mol);n_{AlCl_3}=0,1(mol);n_{H_2(1)}=0,15(mol)\\ \Rightarrow m_{dd_{HCl(1)}}=\dfrac{0,3.36,5}{14,6\%}=75(g)\\ \Rightarrow C\%_{AlCl_3}=\dfrac{0,1.133,5}{2,7+75-0,15.2}.100\%=17,25\%\)
\(n_{HCl(2)}=2n_{Fe}=0,4(mol);n_{FeCl_2}=n_{H_2(2)}=n_{Fe}=0,2(mol)\\ \Rightarrow m{dd_{HCl(2)}}=\dfrac{0,4.36,5}{14,6\%}=100(g)\\ \Rightarrow C\%_{FeCl_2}=\dfrac{0,2.127}{11,2+100-0,2.2}.100\%=22,92\%\)
a) 2Al + 6HCl --> 2AlCl3 + 3H2
Fe + 2HCl --> FeCl2 + H2
b) Gọi số mol Al, Fe lần lượt là a,b
=> 27a + 56b = 13,9
\(n_{H_2}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\)
2Al + 6HCl --> 2AlCl3 + 3H2
a----->3a--------->a------->1,5a______(mol)
Fe + 2HCl --> FeCl2 + H2
b------>2b-------->b----->b__________(mol)
=> 1,5a + b = 0,35
=> \(\left\{{}\begin{matrix}a=0,1=>m_{Al}=0,1.27=2,7\left(g\right)\\b=0,2=>m_{Fe}=0,2.56=11,2\left(g\right)\end{matrix}\right.\)
c) nHCl = 3a + 2b = 0,7 (mol)
=> mHCl = 0,7.36,5 = 25,55(g)
=> \(m_{ddHCl}=\dfrac{25,55.100}{14,6}=175\left(g\right)\)
\(m_{dd\left(saupu\right)}=13,9+175-2.0,35=188,2\left(g\right)\)
\(\left\{{}\begin{matrix}m_{AlCl_3}=0,1.133,5=13,35\left(g\right)\\m_{FeCl_2}=0,2.127=25,4\left(g\right)\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}C\%\left(AlCl_3\right)=\dfrac{13,35}{188,2}.100\%=7,1\%\\C\%\left(FeCl_2\right)=\dfrac{25,4}{188,2}.100\%=13,5\%\end{matrix}\right.\)
PTHH: \(CaO+2HCl\rightarrow CaCl_2+H_2O\) (1)
\(CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\uparrow\) (2)
a) Ta có: \(n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)=n_{CaCO_3}\)
\(\Rightarrow m_{CaCO_3}=0,2\cdot100=20\left(g\right)\) \(\Rightarrow\%m_{CaCO_3}=\dfrac{20}{25,6}\cdot100\%=78,125\%\)
\(\Rightarrow\%m_{CaO}=21,875\%\)
b) Theo 2 PTHH: \(\left\{{}\begin{matrix}n_{HCl\left(2\right)}=2n_{CaCO_3}=0,4mol\\n_{HCl\left(1\right)}=2n_{CaO}=2\cdot\dfrac{25,6-20}{56}=0,2mol\end{matrix}\right.\)
\(\Rightarrow\Sigma n_{HCl}=0,6mol\) \(\Rightarrow C\%_{HCl}=\dfrac{0,6\cdot36,5}{210\cdot1,05}\cdot100\%\approx9,93\%\)