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PT: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\) (1)
\(2Fe+6H_2SO_{4\left(đ\right)}\underrightarrow{t^o}Fe_2\left(SO_4\right)_3+3SO_2+6H_2O\) (2)
\(5SO_2+2KMnO_4+2H_2O\rightarrow2MnSO_4+K_2SO_4+2H_2SO_4\) (3)
Ta có: \(n_{H_2}=0,2\left(mol\right)\)
Theo PT (1): \(n_{Fe}=n_{H_2}=0,2\left(mol\right)\)
Theo PT (2): \(n_{SO_2}=\dfrac{3}{2}n_{Fe}=0,3\left(mol\right)\)
\(\Rightarrow V_{SO_2}=0,3.22,4=6,72\left(l\right)\)
Theo PT (3): \(n_{KMnO_4}=\dfrac{2}{5}n_{SO_2}=0,12\left(mol\right)\)
\(\Rightarrow V_{KMnO_4}=\dfrac{0,12}{2}=0,06\left(l\right)\)
Bạn tham khảo nhé!
$n_{Al} = 0,2(mol) ; n_{Fe_3O_4} = 0,075(mol)$
$8Al + 3Fe_3O_4 \xrightarrow{t^o} 9Fe + 4Al_2O_3$
Vì $n_{Al} : 8 = n_{Fe_3O_4} : 3$ nên gọi hiệu suất là a
Suy ra: $n_{Al\ pư} = 0,2a(mol) ; n_{Al\ dư} = 0,2 - 0,2a(mol)$
$n_{Fe} = \dfrac{9}{8}n_{Al} = 0,225a(mol)$
Mà :
$n_{H_2} = 1,5n_{Al} + n_{Fe} = 1,5(0,2 - 0,2a) + 0,225a = \dfrac{5,376}{22,4}$
$\Rightarrow a = 0,8 = 80\%$
a) PTHH: \(SO_3+H_2O\rightarrow H_2SO_4\)
Ta có: \(n_{SO_3}=\dfrac{24}{80}=0,3\left(mol\right)=n_{H_2SO_4}\) \(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,3\cdot98}{20\%}=147\left(g\right)\)
\(\Rightarrow V_{ddH_2SO_4}=\dfrac{147}{1,14}\approx128,95\left(ml\right)\)
b) PTHH: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)
Theo PTHH: \(n_{Fe}=n_{H_2SO_4}=n_{H_2}=0,3\left(mol\right)=n_{FeSO_4}\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Fe}=0,3\cdot56=16,8\left(g\right)\\V_{H_2}=0,3\cdot24,76=7,428\left(l\right)\\m_{FeSO_4}=0,3\cdot152=45,6\left(g\right)\\m_{H_2}=0,3\cdot2=0,6\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{Fe}+m_{ddH_2SO_4}-m_{H_2}=163,2\left(g\right)\)
\(\Rightarrow C\%_{FeSO_4}=\dfrac{45,6}{163,2}\cdot100\%\approx27,94\%\)
a) \(2Fe\left(OH\right)_3-^{t^o}\rightarrow Fe_2O_3+3H_2O\)
\(Cu\left(OH\right)_2-^{t^o}\rightarrow CuO+H_2O\)
Gọi x,y lần lượt là số mol Fe(OH)3 và Cu(OH)2
=> \(\left\{{}\begin{matrix}107x+98y=20,5\\160.\dfrac{x}{2}+80y=16\end{matrix}\right.\)
=> x= 0,1 ; y=0,1
=> \(\%m_{Fe\left(OH\right)_3}=\dfrac{0,1.107}{20,5}.100=52,2\%\)
\(\%m_{Cu\left(OH\right)_2}=47,8\%\)
b) \(2Fe\left(OH\right)_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+6H_2O\)
\(Cu\left(OH\right)_2+H_2SO_4\rightarrow CuSO_4+2H_2O\)
\(n_{H_2SO_4}=0,1.\dfrac{3}{2}+0,1=0,25\left(mol\right)\)
\(m_{ddH_2SO_4}=\dfrac{0,25.98}{20\%}=122,5\left(g\right)\)
\(m_{ddsaupu}=20,5+122,5=143\left(g\right)\)
\(C\%_{Fe_2\left(SO_4\right)_3}=\dfrac{0,05.400}{143}.100=13,97\%\)
\(C\%_{CuSO_4}=\dfrac{0,1.160}{143}.100=11,19\%\)
c) \(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
\(n_{Fe_2O_3}=0,05\left(mol\right);n_{CuO}=0,1\left(mol\right)\)
=> \(n_{H_2SO_4}=0,05.3+0,1=0,25\left(mol\right)\)
\(m_{ddH_2SO_4\left(pứ\right)}=\dfrac{0,25.98}{20\%}=122,5\left(g\right)\)
=> \(m_{ddH_2SO_4\left(bđ\right)}=122,5.110\%=134,75\left(g\right)\)