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a,Fe + 2HCl → FeCl + H2 (1)
FeO + 2HCl → FeCl + H2O (2)
nH2 = 3,36/ 22,4 = 0,15 ( mol)
Theo (1) nH2 = nFe = 0,15 ( mol)
mFe = 0,15 x 56 = 8.4 (g)
m FeO = 12 - 8,4 = 3,6 (g)
a, \(n_{H_2}=\frac{3,36}{22,4}=0,15\left(mol\right)\)
\(Fe+2HCl->FeCl_2+H_2\left(1\right)\)
\(FeO+2HCl->FeCl_2+H_2O\left(2\right)\)
theo (1) \(n_{Fe}=n_{H_2}=0,15\left(mol\right)\)
=> \(m_{Fe}=0,15.56=8,4\left(g\right)\)
=> \(m_{FeO}=12-8,4=3,6\left(g\right)\)
ta thấy : nFe =nH2 = 0,15
=> mFe =0,15 x 56 = 8,4g
%Fe=8,4/12 x 100 = 70%
=>%FeO = 100 - 70 = 30%
b) BTKLra mdd tìm mct of HCl
c) tìm mdd sau pứ -mH2 nha bạn
a) \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
b) Gọi x,y là số mol Al, Fe
\(n_{H_2}=\dfrac{0,448}{22,4}=0,02\left(mol\right)\)
Ta có hệ : \(\left\{{}\begin{matrix}27x+56y=0,83\\\dfrac{3}{2}x+y=0,02\end{matrix}\right.\)
=> \(x=\dfrac{29}{5700};y=\dfrac{47}{3800}\)
\(\%m_{Al}=\dfrac{\dfrac{27}{5700}.27}{0,83}.100=16,55\%\); \(\%m_{Fe}=100-16,55=83,45\%\)
c)Bảo toàn nguyên tố H: \(n_{H_2SO_4}=n_{H_2}=0,02\left(mol\right)\)
=> \(C\%_{H_2SO_4}=\dfrac{0,02.98}{200}.100=0,98\%\)
Gọi \(\left\{{}\begin{matrix}n_{Zn}=a\left(mol\right)\\n_{Fe}=b\left(mol\right)\end{matrix}\right.\)
\(n_{H_2}=\dfrac{15,68}{22,4}=0,7\left(mol\right)\\ m_{HCl}=200.27,375\%=54,75\left(g\right)\\ n_{HCl}=\dfrac{54,75}{36,5}=1,5\left(mol\right)\)
PTHH:
Zn + 2HCl ---> ZnCl2 + H2
a ----> 2a --------> a -----> a
Fe + 2HCl ---> FeCl2 + H2
b ---> 2b -------> b ------> b
Hệ pt \(\left\{{}\begin{matrix}65a+56b=43,7\\a+b=0,7\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,5\left(mol\right)\\b=0,2\left(mol\right)\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}m_{Zn}=0,5.65=32,5\left(g\right)\\m_{Fe}=0,2.56=11,2\left(g\right)\end{matrix}\right.\)
\(m_{dd}=43,7+200-0,7.2=242,3\left(g\right)\\ \rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,5.136}{242,3}=28,06\%\\C\%_{FeCl_2}=\dfrac{0,2.127}{242,3}=10,48\%\\C\%_{HCl\left(dư\right)}=\dfrac{\left(1,5-0,5.2-0,2.2\right).36,5}{242,3}=1,51\%\end{matrix}\right.\)
\(n_{H_2}=\dfrac{15,68}{22,4}=0,7\left(mol\right)\\
pthh:\left\{{}\begin{matrix}Zn+H_2SO_4->ZnSO_4+H_2\\Fe+H_2SO_4->FeSO_{\text{ 4 }}+H_2\end{matrix}\right.\)
gọi số mol Zn là x , số mol Fe là y
=> 65x+56y=43,7
=> a+b=0,7
=>a=0,5 , b =0,2
=> \(m_{Zn}=0,5.65=32,5\\ m_{Fe}=43,7-32,5=11,2\left(G\right)\)
\(2Al+6HCl\to 2AlCl_3+3H_2\\ Fe+2HCl\to FeCl_2+H_2\\ n_{HCl}=0,2.4=0,8(mol)\\ \Rightarrow \begin{cases} 56.n_{Fe}+27.n_{Al}=22\\ 2.n_{Fe}+3.n_{Al}=0,8 \end{cases}\Rightarrow \begin{cases} n_{Fe}=0,39(mol)\\ n_{Al}=0,007(mol) \end{cases}\\ \Rightarrow \begin{cases} \%m_{Fe}=\dfrac{0,39.56}{22}.100\%=99,27\%\\ \%m_{Al}=100\%-99,27\%=0,73\% \end{cases}\)
A) Gọi x,y tương ứng là số mol của Al và Fe:
Ta có: 27x+56y=11 (1)
\(n_{H_2}\)=0,4 mol
1,5x+y=0,4 (2)
Giải hệ(1),(2):x=0,2;y=0,1
\(m_{Al}=0,2.27=5,4g\)
%Al=\(^{\frac{5,4.100}{11}}=49,09\%\)
\(m_{Fe=0,1.56=5,6g}\)
%Fe=\(50,91\%\)
B)Nồng độ phần trăm của dd \(H_2SO_4\) là:
C%=\(\frac{m_{ct}}{m_{dd}}\times100\%\)=\(\frac{16,6}{200}\times100=8,3\%\)
a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
Gọi: \(\left\{{}\begin{matrix}n_{Zn}=x\left(mol\right)\\n_{Al}=y\left(mol\right)\end{matrix}\right.\) ⇒ 65x + 27y = 17,05 (1)
Ta có: \(n_{H_2}=\dfrac{9,52}{22,4}=0,425\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Zn}+\dfrac{3}{2}n_{Al}=x+\dfrac{3}{2}y=0,425\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Zn}=0,2\left(mol\right)\\n_{Al}=0,15\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Zn}=0,2.65=13\left(g\right)\\m_{Al}=0,15.27=4,05\left(g\right)\end{matrix}\right.\)
b, Theo PT: \(\left\{{}\begin{matrix}n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right)\\n_{AlCl_3}=n_{Al}=0,15\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{ZnCl_2}}=\dfrac{0,2}{0,5}=0,4\left(M\right)\\C_{M_{AlCl_3}}=\dfrac{0,15}{0,5}=0,3\left(M\right)\end{matrix}\right.\)
c, Ta có: m dd HCl = 1,05.500 = 525 (g)
m dd sau pư = mhh + m dd HCl - mH2 = 541,2 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,2.136}{541,2}.100\%\approx5,03\%\\C\%_{AlCl_3}=\dfrac{0,15.133,5}{541,2}.100\%\approx3,7\%\end{matrix}\right.\)
1) 2Na+2H2O → 2NaOH+H2
2) H2+CuOto→ Cu+H2O
Có nCuO=\(\dfrac{40}{80}\)=0,5 mol
Dựa vào PTHH 2) nH2=nCuO=0,5mol
Dựa vào PTHH 1) nNaOH=2nH2=0,5.2=1moll
Vậy mNaOH=1.40=40
→C%NaOH=\(\dfrac{40}{160}\).100%=25%
1.
Fe + 2HCl\(\rightarrow\)FeCl2 + H2
nFe=\(\dfrac{22,4}{56}=0,4\left(mol\right)\)
Theo PTHH ta có:
nH2=nFe=0,4(mol)
VH2=22,4.0,4=8,96(lít)
b;Theo PTHH ta có:
nFeCl2=nFe=0,4(mol)
nHCl=2nFe=0,8(mol)
mFeCl2=127.0,4=50,8(g)
mHCl=36,5.0,8=29,2(g)
mdd HCl=\(29,2:\dfrac{7,3}{100}=400\left(g\right)\)
C% dd FeCl2=\(\dfrac{50,8}{22,4+400}.100\%=12\%\)
2Al + 6HCl \(\rightarrow\)2AlCl3 + 3H2 (1)
Fe + 2HCl \(\rightarrow\)FeCl2 + H2 (2)
mHCl trong dd=\(175.\dfrac{7,3}{100}=12,775\left(g\right)\)
nHCl=\(\dfrac{12,775}{36,5}=0,35\left(mol\right)\)
Đặt nAl=a
nFe=b
Ta có:
\(\left\{{}\begin{matrix}27a+56b=4,1\\3a+2b=0,35\end{matrix}\right.\)
a=0,1;b=0,025
mAl=27.0,1=2,7(g)
% Al=\(\dfrac{2,7}{4,1}.100\%=65,85\%\)
%Fe=100-65,85=34,15%
b;Theo PTHH 1 và 2 ta có:
nAl=nAlCl3=0,1(mol)
nFe=nFeCl2=0,025(mol)
mAlCl3=133,5.0,1=13,35(g)
mFeCl2=0,025.127=3,175(g)
C% dd AlCl3=\(\dfrac{13,35}{4,1+175-0,175.2}.100\%=7,46\%\)
C% FeCl2=\(\dfrac{3,175}{4,1+175-0,175.2}.100\%=1,77\%\)