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a, PT: \(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
b, Ta có: \(n_P=\dfrac{6,2}{31}=0,2\left(mol\right)\)
\(V_{O_2}=18,48.\dfrac{1}{5}=3,696\left(l\right)\Rightarrow n_{O_2}=\dfrac{3,696}{22,4}=0,165\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,2}{4}>\dfrac{0,165}{5}\), ta được P dư.
Theo PT: \(n_{P_2O_5}=\dfrac{2}{5}n_{O_2}=0,066\left(mol\right)\)
\(\Rightarrow m_{P_2O_5}=0,066.142=9,372\left(g\right)\)
a) \(n_P=\dfrac{6,2}{31}=0,2\left(mol\right)\)
PTHH: 4P + 5O2 --to--> 2P2O5
0,2-->0,25
=> VO2 = 0,25.22,4 = 5,6 (l)
=> Vkk = 5,6.5 = 28 (l)
b)
PTHH: 2KMnO4 --to--> K2MnO4 + MnO2 + O2
0,5<-----------------------------0,25
=> \(m_{KMnO_4}=0,5.158=79\left(g\right)\)
nP=\(\dfrac{62}{31}\)=0,2(mol)
nO2=\(\dfrac{7,84}{22,4}\)=0,35(mol)
PTHH:4P+5O2to→2P2O5
tpứ: 0,2 0,35
pứ: 0,2 0,25 0,1
spứ: 0 0,1 0,1
a)chất còn dư là oxi
mO2dư=0,1.32=3,2(g)
b)mP2O5=n.M=0,1.142=14,2(g)
\(a.n_P=0,2\left(mol\right);n_{O_2}=0,35\left(mol\right)\\ 4P+5O_2-^{t^o}\rightarrow2P_2O_5\\ LTL:\dfrac{0,2}{4}< \dfrac{0,35}{5}\\ \Rightarrow SauphảnứngO_2dư\\ n_{O_2\left(pứ\right)}=\dfrac{5}{4}n_P=0,25\left(mol\right)\\ \Rightarrow m_{P\left(dư\right)}=\left(0,35-0,25\right).32=3,2\left(g\right)\\ b.n_{P_2O_5}=\dfrac{1}{2}n_P=0,1\left(mol\right)\\ \Rightarrow m_{P_2O_5}=0,1.142=14,2\left(g\right)\)
a) nFe = 16,8/56 = 0,3 (mol)
PTHH: 3Fe + 2O2 -> (t°) Fe3O4
Mol: 0,3 ---> 0,2 ---> 0,1
mFe3O4 = 0,1 . 232 = 23,2 (g)
b) VO2 = 0,2 . 22,4 = 4,48 (l)
Vkk = 4,48 . 5 = 22,4 (l)
c) H = 100% - 20% = 80%
nO2 (LT) = 0,2 : 80% = 0,25 (mol)
PTHH: 2KMnO4 -> (t°) K2MnO4 + MnO2 + O2
nKMnO4 = 0,25 . 2 = 0,5 (mol)
mKMnO4 = 0,5 . 158 = 79 (g)
PTHH: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
Ta có: \(\left\{{}\begin{matrix}n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\\n_{O_2}=\dfrac{12,8}{32}=0,4\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{3}< \dfrac{0,4}{2}\) \(\Rightarrow\) Oxi còn dư, Fe p/ứ hết
\(\Rightarrow n_{O_2\left(dư\right)}=0,4-\dfrac{2}{15}=\dfrac{4}{15}\left(mol\right)\)
+) Theo PTHH: \(\left\{{}\begin{matrix}n_{O_2}=\dfrac{2}{15}\left(mol\right)\\n_{Fe_3O_4}=\dfrac{1}{15}\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}V_{kk}=\dfrac{2}{15}\cdot22,4\cdot5\approx14,93\left(l\right)\\m_{Fe_3O_4}=\dfrac{1}{15}\cdot232\approx15,47\left(g\right)\end{matrix}\right.\)
\(n_{P_2O_5}=\dfrac{21,3}{142}=0,15\left(mol\right)\)
PTHH: 4P + 5O2 --to--> 2P2O5
0,3 0,375 0,15
\(\rightarrow\left\{{}\begin{matrix}m_P=0,3.31=9,3\left(g\right)\\V_{O_2}=0,375.22,4=8,4\left(l\right)\\V_{kk}=8,4.5=42\left(l\right)\end{matrix}\right.\)
PTHH: 2KClO3 --to--> 2KCl + 3O2
0,25 0,375
=> mKClO3 = 0,25.122,5 = 30,625 (g)
\(nP_2O_5=\dfrac{21,3}{142}=0,15\left(mol\right)\)
\(pthh:4P+5O_2-t^o->2P_2O_5\)
0,3 0,375 0,15
=> \(m_P=0,3.31=9,3\left(g\right)\)
=>\(V_{O_2}=0,375.22,4=8,4\left(L\right)=>V_{KK}=8,4:20\%=42\left(L\right)\)
\(pthh:2KMnO_4-t^o->K_2MnO_4+MnO_2+O_2\)
0,75 0,75
=> mKMnO4 = 0,75 . 158 = 118,5 (G)
a)
\(4P + 5O_2 \xrightarrow{t^o} 2P_2O_5\)
Sản phẩm : Điphotpho pentaoxit.
b)
\(n_P = \dfrac{6,2}{31} = 0,2(mol)\\ \Rightarrow n_{P_2O_5} = \dfrac{1}{2}n_P = 0,1(mol)\\ \Rightarrow m_{P_2O_5} = 0,1.142 = 14,2(gam)\)
c)
\(n_{O_2} = \dfrac{5}{4}n_P = 0,125(mol)\\ \Rightarrow V_{O_2} = 0,125.22,4 = 2,8(lít)\)
d)
\(V_{không\ khí} = \dfrac{2,8}{20\%} = 14(lít)\)
a) \(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
\(n_{O_2}=\dfrac{10,08}{22,4}=0,45\left(mol\right)\)
PTHH: 2H2 + O2 --to--> 2H2O
Xét tỉ lệ: \(\dfrac{0,5}{2}< \dfrac{0,45}{1}\) => H2 hết, O2 dư
PTHH: 2H2 + O2 --to--> 2H2O
0,5-->0,25----->0,5
=> \(m_{O_2\left(dư\right)}=\left(0,45-0,25\right).32=6,4\left(g\right)\)
b) \(m_{H_2O}=0,5.18=9\left(g\right)\)
c)
PTHH: 2KMnO4 --to--> K2MnO4 + MnO2 + O2
0,5<-----------------------------------0,25
=> \(m_{KMnO_4}=0,5.158=79\left(g\right)\)
a, \(2Zn+O_2\underrightarrow{t^o}2ZnO\)
b, \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{1}{2}n_{Zn}=0,1\left(mol\right)\Rightarrow V_{O_2}=0,1.22,4=2,24\left(l\right)\)
\(\Rightarrow V_{kk}=5V_{O_2}=11,2\left(l\right)\)
c, \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
Theo PT: \(n_{KMnO_4}=2n_{O_2}=0,2\left(mol\right)\Rightarrow m_{KMnO_4}=0,2.158=31,6\left(g\right)\)
a. \(n_P=\frac{6,2}{31}=0,2mol\)
\(V_{O_2}=V_{kk}.\frac{1}{5}=\frac{18,48}{5}=3,696l\)
\(n_{O_2}=\frac{3,696}{22,4}=0,165mol\)
PTHH: \(4P+5O_2\xrightarrow{t^o}2P_2O_5\)
Tỷ lệ \(\frac{0,2}{4}>\frac{0,165}{5}\)
Vậy P dư
\(n_{P\left(\text{phản ứng }\right)}=\frac{4}{5}n_{O_2}=0,132mol\)
\(n_{P\left(dư\right)}=0,2-0,132=0,068mol\)
\(\rightarrow m_{P\left(dư\right)}=0,068.31=2,108g\)
b. \(n_{P_2O_5}=\frac{2}{5}n_{O_2}=0,066mol\)
\(\rightarrow m_{P_2O_5}=0,066.142=9,372g\)
c. PTHH: \(2KClO_3\xrightarrow{t^o}2KCl+3O_2\)
\(n_{KClO_3}=\frac{2}{3}n_{O_2}=0,11mol\)
\(\rightarrow m_{KClO_3}=0,11.122,5=13,475g\)