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\(a,BTKL:m_{Fe}+m_{O_2}=m_{Fe_3O_4}\\ \Rightarrow m_{O_2}=m_{Fe_3O_4}-m_{Fe}=23,2-16,8=6,4(g)\)
\(PTHH:3Fe+2O_2\xrightarrow{t^o}Fe_3O_4\\ BTKL:m_{O_2}=m_{Fe_3O_4}-m_{Fe}=23,2-16,8=6,4(g)\)
nFe = 33,6 : 56 = 0,6 (mol)
pthh : 3Fe + 2O2 -t--> Fe3O4
0,6--> 0,4------->0,2 (mol)
=> vO2 = 0,4.22,4 = 8,96 (mol)
=> mFe3O4 = 0,2.232 = 46,4 (g)
pthh : 2KClO3 -t--> 2KClO3 + 3O2
0,267<-----------------------0,4(mol)
mKClO3= 0,267 .122,5 = 32,67 (g)
a, \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b, Ta có: \(n_{Fe}=\dfrac{50,4}{56}=0,9\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{2}{3}n_{Fe}=0,6\left(mol\right)\Rightarrow V_{O_2}=0,6.22,4=13,44\left(l\right)\)
c, \(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=0,3\left(mol\right)\Rightarrow m_{Fe_3O_4}=0,3.232=69,6\left(g\right)\)
d, \(2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
Theo PT: \(n_{KClO_3}=\dfrac{2}{3}n_{O_2}=0,4\left(mol\right)\Rightarrow m_{KClO_3}=0,4.122,5=49\left(g\right)\)
\(n_{Fe}=\dfrac{m}{M}=\dfrac{50,4}{56}=0,9\left(mol\right)\)
\(a.PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
3 2 1
0,9 0,6 0,3
\(b.V_{O_2}=n.24,79=0,6.24,79=14,874\left(l\right)\)
\(c.m_{Fe_3O_4}=n.M=0,3.\left(56.3+16.4\right)=69,6\left(g\right)\)
\(d.V_{O_2}=14,874\left(l\right)\\ \Rightarrow n_{O_2}=\dfrac{V}{24,79}=\dfrac{14,874}{24,79}=0,6\left(mol\right)\\ PTHH:2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
2 2 3
0,6 0,6 0,9
\(m_{KClO_3}=n.M=0,6.\left(39+35,5+16.3\right)=55,5\left(g\right).\)
nFe = 16.8/56 = 0.3 (mol)
3Fe + 2O2 -to-> Fe3O4
0.3......0.2...........0.1
VO2 = 0.2*22.4 = 4.48 (l)
mFe3O4 = 0.1*232 = 23.2 (g)
PTHH: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
Ta có: \(\left\{{}\begin{matrix}n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\\n_{O_2}=\dfrac{12,8}{32}=0,4\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{3}< \dfrac{0,4}{2}\) \(\Rightarrow\) Oxi còn dư, Fe p/ứ hết
\(\Rightarrow n_{O_2\left(dư\right)}=0,4-\dfrac{2}{15}=\dfrac{4}{15}\left(mol\right)\)
+) Theo PTHH: \(\left\{{}\begin{matrix}n_{O_2}=\dfrac{2}{15}\left(mol\right)\\n_{Fe_3O_4}=\dfrac{1}{15}\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}V_{kk}=\dfrac{2}{15}\cdot22,4\cdot5\approx14,93\left(l\right)\\m_{Fe_3O_4}=\dfrac{1}{15}\cdot232\approx15,47\left(g\right)\end{matrix}\right.\)
nFe = 11.2/56=0.2 (mol)
3Fe + 2O2 -to-> Fe3O4
0.2____2/15____1/15
VO2 = 2/15 * 22.4 = 2.9867 (l)
mFe3O4 = 1/15 * 232 = 15.47 (g)
ta có pthh: 3Fe + 2O2 → Fe3O4
Ta có nFe=\(\dfrac{m}{M}\)=\(\dfrac{11,2}{56}\)=0,2(mol)
nO2=2nFe=2*\(\dfrac{0,2}{3}\)=\(\dfrac{2}{15}\)(mol)
VO2=n*M=16*\(\dfrac{2}{15}\)=2,13(l)
nFe3O4=\(\dfrac{0,2}{2}\)=0,1(mol)
mFe3O4=\(\dfrac{0,1}{168+64}\)=23,2(g)
a) Chất tham gia: Sắt (Fe), Oxi (O2)
Sản phẩm: Sắt từ (Fe3O4)
b) Theo ĐLBTKL
\(m_{Fe}+m_{O_2}=m_{Fe_3O_4}\) (1)
c) \(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\); \(n_{Fe_3O_4}=\dfrac{46,4}{232}=0,2\left(mol\right)\)
PTHH: 3Fe + 2O2 --to--> Fe3O4
______0,2----------------->\(\dfrac{0,2}{3}\) ________(mol)
=> vô lí ...