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\(n_{Fe}=\dfrac{12.6}{56}=0.225\left(mol\right)\)
\(n_{O_2}=\dfrac{4.2}{22.4}=0.1875\left(mol\right)\)
\(3Fe+2O_2\underrightarrow{^{^{t^0}}}Fe_3O_4\)
\(3.........2\)
\(0.225......0.1875\)
Lập tỉ lệ : \(\dfrac{0.225}{3}< \dfrac{0.1875}{2}\Rightarrow O_2dư\)
\(m_{O_2\left(dư\right)}=\left(0.1875-0.225\cdot\dfrac{2}{3}\right)\cdot32=1.2\left(g\right)\)
\(m_{Fe_3O_4}=\dfrac{0.225}{3}\cdot232=17.4\left(g\right)\)
a. 4Al + 3O2 -> 2Al2O3
0.3 0.225 0.15
b.\(n_{Al}=\dfrac{8.1}{27}=0.3mol\)
\(V_{O_2}=0.225\times22.4=5.04l\)
c.\(m_{Al_2O_3}=0.15\times102=15.3g\)
1. a. \(PTHH:2Mg+O_2\overset{t^o}{--->}2MgO\left(1\right)\)
b. Ta có: \(n_{Mg}=\dfrac{24}{24}=1\left(mol\right)\)
Theo PT(1): \(n_{O_2}=\dfrac{1}{2}.n_{Mg}=\dfrac{1}{2}.0,1=0,5\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,5.22,4=11,2\left(lít\right)\)
c. \(PTHH:2KClO_3\xrightarrow[t^o]{MnO_2}2KCl+3O_2\left(2\right)\)
Theo PT(2): \(n_{KClO_3}=\dfrac{2}{3}.n_{O_2}=\dfrac{2}{3}.0,5=\dfrac{1}{3}\left(mol\right)\)
\(\Rightarrow m_{KClO_3}=\dfrac{1}{3}.122,5=40,83\left(g\right)\)
2. \(PTHH:3Fe+2O_2\overset{t^o}{--->}Fe_3O_4\)
Ta có: \(n_{Fe_3O_4}=\dfrac{2,32}{232}=0,01\left(mol\right)\)
a. Theo PT: \(n_{Fe}=3.n_{Fe_3O_4}=0,01.3=0,03\left(mol\right)\)
\(\Rightarrow m_{Fe}=0,03.56=1,68\left(g\right)\)
b. Theo PT: \(n_{O_2}=2.n_{Fe_3O_4}=2.0,01=0,02\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,02.22,4=0,448\left(lít\right)\)
nFe = 33,6 : 56 = 0,6 (mol)
pthh : 3Fe + 2O2 -t--> Fe3O4
0,6--> 0,4------->0,2 (mol)
=> vO2 = 0,4.22,4 = 8,96 (mol)
=> mFe3O4 = 0,2.232 = 46,4 (g)
pthh : 2KClO3 -t--> 2KClO3 + 3O2
0,267<-----------------------0,4(mol)
mKClO3= 0,267 .122,5 = 32,67 (g)
a, \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b, Ta có: \(n_{Fe}=\dfrac{50,4}{56}=0,9\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{2}{3}n_{Fe}=0,6\left(mol\right)\Rightarrow V_{O_2}=0,6.22,4=13,44\left(l\right)\)
c, \(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=0,3\left(mol\right)\Rightarrow m_{Fe_3O_4}=0,3.232=69,6\left(g\right)\)
d, \(2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
Theo PT: \(n_{KClO_3}=\dfrac{2}{3}n_{O_2}=0,4\left(mol\right)\Rightarrow m_{KClO_3}=0,4.122,5=49\left(g\right)\)
\(n_{Fe}=\dfrac{m}{M}=\dfrac{50,4}{56}=0,9\left(mol\right)\)
\(a.PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
3 2 1
0,9 0,6 0,3
\(b.V_{O_2}=n.24,79=0,6.24,79=14,874\left(l\right)\)
\(c.m_{Fe_3O_4}=n.M=0,3.\left(56.3+16.4\right)=69,6\left(g\right)\)
\(d.V_{O_2}=14,874\left(l\right)\\ \Rightarrow n_{O_2}=\dfrac{V}{24,79}=\dfrac{14,874}{24,79}=0,6\left(mol\right)\\ PTHH:2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
2 2 3
0,6 0,6 0,9
\(m_{KClO_3}=n.M=0,6.\left(39+35,5+16.3\right)=55,5\left(g\right).\)
a, PT: \(2Zn+O_2\underrightarrow{t^o}2ZnO\) - pư hóa hợp.
b, \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{1}{2}n_{Zn}=0,1\left(mol\right)\Rightarrow V_{O_2}=0,1.22,4=2,24\left(l\right)\)
c, \(n_{H_2SO_4}=\dfrac{9,8}{98}=0,1\left(mol\right)\)
PT: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
Xét tỉ lệ: \(\dfrac{0,2}{1}>\dfrac{0,1}{1}\), ta được Zn dư.
Theo PT: \(n_{H_2}=n_{H_2SO_4}=0,1\left(mol\right)\Rightarrow V_{H_2}=0,1.22,4=2,24\left(l\right)\)
\(n_{ZnSO_4}=n_{H_2SO_4}=0,1\left(mol\right)\Rightarrow m_{ZnSO_4}=0,1.161=16,1\left(g\right)\)
\(n_P=\dfrac{7,44}{31}=0,24mol\)
\(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
0,24 0,3 0,12
\(V_{O_2}=0,3\cdot22,4=6,72l\)
\(2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
0,2 0,3
\(m_{KClO_3}=0,2\cdot122,5=24,5g\)
a: \(4P+5O_2\rightarrow2P_2O_5\)
a, 4P + 5O2 \(\underrightarrow{t^o}\) 2P2O5
b,
\(n_{O_2}=\dfrac{5,04}{22,4}=0,225mol\\ m_{O_2}=0,225.32=7,2g\)
Theo ĐLBTKL, ta có:
mP + \(m_{O_2}\) = m\(P_2O_5\)
\(m\)\(P_2O_5\) \(=4,65+7,2=11,85g\)