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nKClO3 - 12.25/122.5 = 0.1 (mol)
2KClO3 -to-> 2KCl + 3O2
0.1_______________0.15
VO2 = 0.15*22.4 = 3.36 (l)
nH2 = 4.48/22.4 = 0.2 (mol)
2H2 + O2 -to-> 2H2O
0.2___0.1______0.2
=> O2 dư
mH2O = 0.2*18 = 3.6(g)
n KClO3=m/M=12,25/122,5=0,1 (mol)
a/ 2KClO3 --> 2KCl +3O2
TPT: 2 2 3 (mol)
TĐB:0,1 0,1 0,15 (mol)
b/ V O2=n*22,4=0,15*22,4=3,36 ( l)
c/ n H2=V/22,4=4,48/22,4=0,2 (mol)
PTHH: 2H2 +O2 --> 2H2O
TPT: 2 1 2 (mol)
TĐB: 0,2 0,15 (mol)
Xét tỉ lệ 0,2/2 < 0,15/1
=> H2 pư hết O2 pư dư
n H2O= 0,2*2/2=0,2 (mol)
m H2O = n*M=0,2 *18=3,6 (g)
Mik chắc chắn đúng tại mik học sinh chuyên hóa
\(n_{KClO_3\left(bd\right)}=\dfrac{55,125}{122,5}=0,45\left(mol\right)\)
=> \(n_{KClO_3\left(pư\right)}=\dfrac{0,45.85}{100}=0,3825\left(mol\right)\)
PTHH: 2KClO3 --to,MnO2--> 2KCl + 3O2
0,3825------------------->0,57375
=> \(V_{O_2}=0,57375.22,4=12,852\left(l\right)\)
Câu 3.
a.b.\(n_{KClO_3}=\dfrac{24,5}{122,5}=0,2mol\)
\(2KClO_3\rightarrow\left(t^o,MnO_2\right)2KCl+3O_2\)
0,2 0,3 ( mol )
\(V_{O_2}=0,3.22,4=6,72l\)
c.\(n_{Al}=\dfrac{5,4}{27}=0,2mol\)
\(4Al+3O_2\rightarrow\left(t^o\right)2Al_2O_3\)
0,2 < 0,3 ( mol )
0,2 0,1 ( mol )
\(m_{Al_2O_3}=0,1.102=10,2g\)
Câu 4.
a.b.
\(n_{KClO_3}=\dfrac{12,25}{122,5}=0,1mol\)
\(2KClO_3\rightarrow\left(t^o,MnO_2\right)2KCl+3O_2\)
0,1 0,15 ( mol )
\(V_{O_2}=0,15.22,4=3,36l\)
c.\(n_{Fe}=\dfrac{8,4}{56}=0,15mol\)
\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)
0,15 < 0,15 ( mol )
0,15 0,05 ( mol )
\(m_{Fe_3O_4}=0,05.232=11,6g\)
\(a.2KClO_3-^{t^o}\rightarrow2KCl+3O_2\\ n_{O_2}=\dfrac{3}{2}n_{KClO_3}=0,6\left(mol\right)\\ \Rightarrow V_{O_2}=0,6.22,4=13,44\left(l\right)\\ n_{KCl}=n_{KClO_3}=0,4\left(mol\right)\\ \Rightarrow m_{KCl}=0,4.74,5=29,8\left(g\right)\)
= 
a.\(n_{KClO_3}=\dfrac{m_{KClO_3}}{M_{KClO_3}}=\dfrac{12,25}{122,5}=0,1mol\)
\(2KClO_3\rightarrow\left(t^o\right)2KCl+3O_2\)
2 2 3 ( mol )
0,1 0,15
\(V_{O_2}=n_{O_2}.22,4=0,15.22,4=3,36l\)
b.\(V_{kk}=V_{O_2}.5=3,36.5=16,8l\)
c.\(n_{Fe}=\dfrac{m_{Fe}}{M_{Fe}}=\dfrac{28}{56}=0,5mol\)
\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)
3 2 1 ( mol )
0,5 > 0,15 ( mol )
0,225 0,15 ( mol )
\(m_{Fe\left(du\right)}=n_{Fe\left(du\right)}.M_{Fe}=\left(0,5-0,225\right).56=15,4g\)
2KClO3-to>2KCl+3O2
0,2---------------------0,3
4P+5O2-to->2P2O5
--0,3-------0,12 mol
n KClO3=\(\dfrac{24,5}{122,5}=0,2mol\)
=>VO2=0,3.22,4=6,72l
=>m P2O5=0,12.142=17,04g
=>Vkk=6.72.5=33,6l
nKClO3 = 24,5 : 122,5 = 0,2 (mol)
pthh : 2KClO3 -t--> 2KCl +3 O2
0,2---------------------> 0,3(MOL)
VO2 = 0,3 .22,4 = 6,72 (L)
pthh : 4P+5O2-t--> 2P2O 5
0,3---> 0,12 (mol)
=> mP2O5 = 0,12 . 142 = 17,04 (g)
ta co : Vkk = VO2:21% = 6,72 : 21% 32 (l)
nO2 = 11,2/22,4 = 0,5 (mol)
PTHH: 2KClO3 -> (t°, MnO2) 2KCl + 3O2
Mol: 1/3 <--- 1/3 <--- 0,5
nKClO3 (ban đầu) = 61,25/122,5 = 0,5 (mol)
H = (1/3)/0,5 = 66,66%
\(a.2KClO_3-^{t^o}\rightarrow2KCl+3O_2\\ b.n_{O_2}=\dfrac{3}{2}n_{KClO_3}=\dfrac{3}{2}.\dfrac{12,5}{122,5}=\dfrac{15}{98}\left(mol\right)\\ \Rightarrow V_{O_2}=\dfrac{15}{98}.22,4=\dfrac{24}{7}\left(l\right)\approx3,24\left(l\right)\)