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a) Gọi \(n_{Cu}=a\left(mol\right)\rightarrow n_{Fe}=\dfrac{3}{2}a=1,5a\left(mol\right)\)
PTHH:
\(CuO+H_2\xrightarrow[]{t^o}Cu+H_2O\)
a<------a<------a
\(Fe_3O_4+4H_2\xrightarrow[]{t^o}3Fe+4H_2O\)
0,5a<-----2a<------1,5a
\(\rightarrow80a+0,5a.232=39,2\\ \Leftrightarrow a=0,2\left(mol\right)\)
\(\rightarrow\left\{{}\begin{matrix}m_{CuO}=0,2.80=16\left(g\right)\\m_{Fe_3O_4}=0,5.0,2.232=23,2\left(g\right)\end{matrix}\right.\)
b) \(V_{H_2}=\left(0,2.2+0,2\right).22,4=13,44\left(l\right)\)
a) Đặt \(n_{Cu}=a\left(mol\right)\)
\(\rightarrow n_{Fe}=1,5a\left(mol\right)\)
PTHH:
\(Fe_3O_4+4H_2\xrightarrow[]{t^o}3Fe+4H_2O\)
0,5a<---2a<------1,5a
\(CuO+H_2\xrightarrow[]{t^o}Cu+H_2O\)
a------>a------->a
Theo bài ra, ta có PT: \(0,5a.232+80a=39,2\)
\(\Leftrightarrow a=0,2\left(mol\right)\)
\(\rightarrow\left\{{}\begin{matrix}m_{Fe_3O_4}=0,5.0,2.232=23,2\left(g\right)\\m_{CuO}=0,2.80=16\left(g\right)\end{matrix}\right.\)
b) \(V_{H_2}=\left(0,2.2+0,2\right).22,4=13,44\left(l\right)\)
Gọi số mol Fe3O4, PbO là a, b
=> 232a + 223b= 78,95
PTHH: Fe3O4 + 4H2 --to--> 3Fe + 4H2O
a------>4a---------->3a
PbO + H2 --to--> Pb + H2O
b--->b--------->b
=> 56.3a + 207.b = 68,55
=> a = 0,1; b = 0,25
=> \(\left\{{}\begin{matrix}\%Fe_3O_4=\dfrac{232.0,1}{78,95}.100\%=29,386\%\\\%PbO=\dfrac{0,25.223}{78,95}.100\%=70,614\%\end{matrix}\right.\)
nH2 = 4a + b = 0,65 (mol)
=> VH2 = 0,65.22,4 = 14,56 (l)
Fe3O4+4H2-to>3Fe+4H2O
x---------\(\dfrac{3}{4}x\)
CuO+H2-to>Cu+H2O
y--------y mol
Ta có :
\(\left\{{}\begin{matrix}x+y=0,5\\\dfrac{3}{4}x.56+64y=23,2\end{matrix}\right.\)
=>x=0,4 mol, y=0,1 mol
=>% m Fe3O4=\(\dfrac{0,4.232}{0,4.232+0,1.80}.100\)=92,1%
=>%m CuO=100-92,1=7,9%
\(n_{H_2}=\dfrac{11,2}{22,4}=0,5mol\)
\(Fe_3O_4+4H_2\rightarrow3Fe+4H_2O\)
x 4x 3x
\(CuO+H_2\rightarrow Cu+H_2O\)
y y y
\(\Rightarrow\left\{{}\begin{matrix}4x+y=0,5\\3\cdot56x+64y=23,2\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,1\end{matrix}\right.\)
\(\%m_{Fe_2O_3}=\dfrac{0,1\cdot232}{0,1\cdot232+0,1\cdot80}\cdot100\%=74,36\%\)
\(\%m_{CuO}=100\%-74,36\%=25,64\%\)
\(m_{Cu}=\dfrac{29,6-4}{2}=12,8(g)\\ \Rightarrow m_{Fe}=12,8+4=16,8(g)\\ PTHH:CuO+H_2\xrightarrow{t^o}Cu+H_2O\\ Fe_3O_4+4H_2\xrightarrow{t^o}3Fe+4H_2O\\ \Rightarrow \Sigma n_{H_2}=n_{Cu}+3n_{Fe}=\dfrac{12,8}{64}+\dfrac{3}{4}.\dfrac{16,8}{56}=0,6(mol)\\ \Rightarrow V_{H_2}=0,6.22,4=13,44(l)\)
Ta có: \(\left\{{}\begin{matrix}m_{Fe}=\dfrac{59,2+8}{2}=33,6\left(g\right)\\m_{Cu}=59,2-33,6=25,6\left(g\right)\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}n_{Fe}=\dfrac{33,6}{56}=0,6\left(mol\right)\\n_{Cu}=\dfrac{25,6}{64}=0,4\left(mol\right)\end{matrix}\right.\)
PTHH:
\(Fe_3O_4+4H_2\xrightarrow[]{t^o}3Fe+4H_2O\)
0,8<----0,3
\(CuO+H_2\xrightarrow[]{t^o}Cu+H_2O\)
0,4<---0,4
`=> V_{H_2} = (0,4 + 0,8).22,4 = 26,88 (l)`
\(m_{Cu}=12g\Rightarrow n_{Cu}=\dfrac{12}{64}=0,1875mol\)
\(\Rightarrow m_{Fe}=m_{kl}-m_{Cu}=24-12=12g\Rightarrow n_{Fe}=\dfrac{3}{14}mol\)
\(CuO+H_2\rightarrow Cu+H_2O\)
\(\dfrac{12}{64}\) \(\dfrac{12}{64}\)
\(Fe_2O_3+3H_2\rightarrow2Fe+3H_2O\)
\(\dfrac{9}{28}\) \(\dfrac{3}{14}\)
\(\Rightarrow\Sigma n_{H_2}=\dfrac{12}{64}+\dfrac{9}{28}=\dfrac{57}{112}mol\)
\(\Rightarrow V_{H_2}=\dfrac{57}{112}\cdot22,4=11,4l\)
Ta có: \(m_{Fe}\) + \(m_{Cu}\) = 29,6
hay\(m_{Cu}\) +4 + \(m_{Cu}\) = 29,6
2\(m_{Cu}\) = 25,6
\(m_{Cu}\) =12,8(g)
=> \(m_{Fe}\) = 16,8(g)
Số mol của 12,8 g Cu:
\(\frac{12,8}{64}\)= 0,2(mol)
Số mol của 16,8g Fe:
\(\frac{16,8}{56}\)=0,3(mol)
CO + CuO \(\rightarrow\) Cu + C\(O_2\)
1(mol) 1(mol)
0,2(mol) 0,2(mol)
4CO + \(Fe_3\)\(O_4\) \(\rightarrow\) 3Fe + 4C \(O_2\)
4(mol) 3(mol)
0,4(mol) 0,3(mol)
Thể tích CO cần dùng:
(0,2+0,4).22,4= 13,44(l)
PTHH: Fe3O4+4Co->3Fe+4Co2 (1)
CuO+Co->Cu+Co2 (2)
Lại có: mFe+mCu=29,6
mFe-mCu=4
=>mFe=16,8=> nFe=0.3mol
mCu=12,8g=>nCu=0.2mol
Theo PTHH(1)
nFe:nCo= 3:4=> nCo=0,3.4/3=0,4mol
nCu:nCo= 1:1 => nCo= 0,2mol
=> nCo=0,6mol=13,44(l)
PTHH: Cuo+H2->Cu+H2O (1)
FeO+H2->Fe+H2O (2)
đặt số mol của Cuo và Feo lần lượt là x,y
theo PTHH (1): nCuO=nCu=x mol
(2) : nFeO=nFe=y mol
Ta có HPT: 64x+56y=29,6
56y-64x=4
giải HPT => x=0,2; y=0,3
từ đây bạn tự giải tiếp nhé :)