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a+b+c) PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
Ta có: \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)=n_{ZnCl_2}=n_{H_2}\)
\(\Rightarrow\left\{{}\begin{matrix}m_{ZnCl_2}=0,1\cdot136=13,6\left(g\right)\\V_{H_2}=0,1\cdot22,4=2,24\left(l\right)\end{matrix}\right.\)
d) PTHH: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Theo PTHH: \(n_{H_2}=n_{Cu}=0,1\left(mol\right)\)
\(\Rightarrow m_{Cu}=0,1\cdot64=6,4\left(g\right)\)
a) 2Al + 6HCl \(\rightarrow\) 2AlCl3 + 3H2
Fe + 2HCl \(\rightarrow\) FeCl2 + H2
b) Gọi nAl = x, nFe = y
=> 27x + 56y = 11 (1)
Theo pt: \(\Sigma\)nH2 = 1,5x + y = \(\dfrac{8,96}{22,4}=0,4mol\)(2)
Từ 1 + 2 => x = 0,2 , y = 0,1
=> mAl = 0,2.27 = 5,4 => %mAl = \(\dfrac{5,4}{11}.100\%\approx49,09\%\)
%mFe = 100 - 49,09 = 50,91%
c) Theo pt: nHCl = 2nH2 = 0,8 mol
=> mHCl = 0,8 . 36,5 = 29,2g
=> \(m_{dd}\)HCl = 29,2 : 10% = 292g
d) mdd sau phản ứng = m A + mHCl = 11 + 292 = 303g
Theo pt: nAlCl3 = nAl = 0,2 mol => m AlCl3 = 26,7g
=> C%AlCl3 = \(\dfrac{26,7}{303}.100\%\) = 8,81%
tương tự nFeCl2 = 0,1 mol => C%FeCl2 = 4,19%
\(n_{Fe}=\dfrac{22,4}{56}=0,4\) (mol) (1)
Phương trình hóa học :
Fe + 2HCl ---> FeCl2 + H2 (2)
Từ (1) và (2) ta có \(n_{FeCl_2}=n_{H_2}=0,4\) (mol) ; \(n_{HCl}=0,8\left(mol\right)\)
b) => \(m_{\text{muối}}=0,4.\left(56+35,5.2\right)=50.8\left(g\right)\)
c) \(V_{\text{khí}}=0,4.22,4=8,96\left(l\right)\)
d) \(m_{HCl}=0,8.36.5=29,2\left(g\right)\)
\(\Rightarrow C\%=\dfrac{29,2}{200}.100\%=14,6\%\)
\(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right);n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\\ 2Al+6HCl\rightarrow2AlCl_3+3H_2\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{H_2\left(tổng\right)}=\dfrac{3}{2}.n_{Al}+n_{Fe}=\dfrac{3}{2}.0,2+0,3=0,6\left(mol\right)\\ a,V=V_{H_2\left(đktc\right)}=0,6.22,4=13,44\left(l\right)\\ b,n_{HCl}=\dfrac{6}{2}.n_{Al}+2.n_{Fe}=\dfrac{6}{2}.0,2+2.0,3=1,2\left(mol\right)\\ \Rightarrow m_{HCl}=1,2.36,5=43,8\left(g\right)\\ c,n_{O_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\\ 2H_2+O_2\rightarrow\left(t^o\right)2H_2O\\ Vì:\dfrac{0,6}{2}>\dfrac{0,25}{1}\Rightarrow H_2dư,O_2hết\\ n_{H_2O}=2.n_{O_2}=2.0,25=0,5\left(mol\right)\\ \Rightarrow m_{H_2O}=0,5.18=9\left(g\right)\)
Mg + H2SO4 => MgSO4 + H2
nMg = m/M = 2.4/24 = 0.1 (mol)
nH2SO4 = m/M = 39.2/98 = 0.4 (mol)
Lập tỉ số: 0.1/1 < 0.4/1 => H2SO4 dư, Mg hết
=> nH2 = 0.1 (mol) => VH2 = 0.1 x 22.4 = 2.24 (l)
nMgSO4 = 0.1 (mol)
=> mMgSO4 = n.M = 0.1 x 120 = 12 (g)
nH2SO4 dư = 0.4 - 0.1 = 0.3 (mol)
mH2SO4 dư = n.M = 0.3 x 98 = 29.4 (g)
\(n_{Al}=\dfrac{5.4}{27}=0.2\left(mol\right)\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(0.2..........0.3...............0.1...........0.3\)
\(m_{H_2SO_4}=0.3\cdot98=29.4\left(g\right)\)
\(V_{H_2}=0.3\cdot22.4=6.72\left(l\right)\)
\(m_{dd_{H_2SO_4}}=\dfrac{29.4\cdot100}{20}=147\left(g\right)\)
\(m_{Al_2\left(SO_4\right)_3}=0.1\cdot342=34.2\left(g\right)\)
\(m_{\text{dung dịch sau phản ứng }}=5.4+147-0.3\cdot2=151.8\left(g\right)\)
\(C\%_{Al_2\left(SO_4\right)_3}=\dfrac{34.2}{151.8}\cdot100\%=22.53\%\)
\(n_{Fe_2O_3}=\dfrac{3,2}{160}=0,02mol\)
\(n_{Cu}=\dfrac{8}{80}=0,1mol\)
\(Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\)
0,02 0,06 0,04 ( mol )
\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\)
0,1 0,1 0,1 ( mol )
\(m_{Fe}=0,04.56=2,24g\)
\(m_{Cu}=0,1.64=6,4g\)
\(n_{H_2}=0,06+0,1=0,16mol\)
\(n_{Fe_2O_3}=\dfrac{3,2}{160}=0,02mol\)
\(m_{CuO}=\dfrac{8}{80}=0,1mol\)
\(Fe_2O_3+3H_2\rightarrow2Fe+3H_2O\)
\(CuO+H_2\rightarrow Cu+H_2O\)
\(m_{Fe}=0,02\cdot2\cdot56=2,24g\)
\(m_{Cu}=0,1\cdot64=6,4g\)
\(\Sigma n_{H_2}=0,02\cdot3+0,1=0,16mol\Rightarrow V_{H_2}=3,584l\)
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\ pthh:Fe+2HCl\rightarrow FeCl_2+H_2\)
0,1 0,1 0,1
=> \(m_{Fe}=0,1.56=5,6\left(g\right)\\ m_{FeCl_2}=0,1.127=12,7\left(G\right)\)
nH2 = 2,24/22,4= 0,1 mol
PTHH : Fe + HCl => FeCl2 + H2
theo pt => nFe = nH2 = 0,1 mol
mFe = 0,1 x56 = 5,6 g
theo pt => nH2 = nFeCl2 = 0,1 mol
mFeCl2 = 0,1 x 127 = 12,7 g