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\(n_{Fe}=\dfrac{36,4}{56}=0,65\left(mol\right)\)
PTHH: Fe + 2HCl ---> FeCl2 + H2
0,65->1,3----->0,65--->0,65
=> \(\left\{{}\begin{matrix}a,V_{ddHCl}=\dfrac{1,3}{0,5}=2,6\left(l\right)\\b,V_{H_2}=0,65.22,4=14,56\left(l\right)\end{matrix}\right.\)
c, \(C_{M\left(FeCl_2\right)}=\dfrac{0,65}{2,6}=0,25M\)
`a)PTHH:`
`Zn + 2HCl -> ZnCl_2 + H_2`
`0,02` `0,02` `0,02` `(mol)`
`n_[Zn]=[1,3]/65=0,02(mol)`
`b)V_[H_2]=0,02.22,4=0,448(l)`
`c)C%_[ZnCl_2]=[0,02.136]/[1,3+50-0,02.2].100~~5,31%`
\(n_{Zn}=\dfrac{1,3}{65}=0,02\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,02 0,04 0,02 0,02 ( mol )
\(V_{H_2}=0,02.22,4=0,448\left(l\right)\)
\(C\%_{ZnCl_2}=\dfrac{0,02.136}{1,3+50-0,02.2}.100=5,3\%\)
a) pt: 2Al + 6HCl \(\rightarrow\) 2AlCl3 + 3H2
nAl = \(\dfrac{5,4}{27}=0,2mol\)
Theo pt: nH2 = \(\dfrac{3}{2}nAl=0,3mol\)
=> VH2 = 0,3.22,4 = 6,72lit
c) nHCl = 3nAl = 0,6mol
=> mHCl = 21,9g
=> C% = \(\dfrac{21,9}{200}.100\%=10,95\%\)
d) Bảo toàn khối lượng
mdung dich muối = mAl + mHCl - mH2
= 5,4 + 200 - 0,3.2 = 204,8g
Theo pt:nAlCl3 = nAl = 0,2mol
=> mAlCl3 = 0,2.133,5 = 26,7g
=> C%dd muối = \(\dfrac{26,7}{204,8}.100\%=13,03\%\)
e) H2 + CuO \(\xrightarrow[]{t^o}\) Cu + H2O
nCu = nH2 = 0,3mol
=> mCu = 0,3.64 = 19,2g
a, \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
PTHH: Zn + 2HCl ---> ZnCl2 + H2
0,1--->0,2------->0,1----->0,1
VH2 = 0,1.22,4 = 2,24 (l)
b, \(C_{M\left(HCl\right)}=\dfrac{0,2}{0,2}=1M\)
c, \(C_{M\left(ZnCl_2\right)}=\dfrac{0,1}{0,2}=0,5M\)
a) Zn + 2HCl → ZnCl2 + H2
b) n H2 = n Zn = 1,95/65 = 0,03(mol)
V H2 = 0,03.22,4 = 0,672(lít)
c) n ZnCl2 = n Zn = 0,03(mol)
=> m dd sau pư = 1,95 + 120 - 0,03.2 = 121,89(gam)
C% ZnCl2 = 0,03.136/121,89 .100% = 3,35%
a) nZn=0,03(mol)
PTHH: Zn + 2 HCl -> ZnCl2 + H2
nH2=nZnCl2=nZn=0,03(mol)
b) V(H2,đktc)=0,03.22,4=0,672(l)
c) mZnCl2=136.0,03=4,08(g)
mddA=mddZnCl2=1,95+ 120 - 0,03.2= 121,89(g)
=> C%ddZnCl2=(4,08/121,89).100=3,347%
\(n_{Fe}=\dfrac{11,2}{56}=0,2mol\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
0,2 0,2 0,2 0,2
a)\(V_{H_2}=0,2\cdot22,4=4,48l\)
b)\(C_{M_{H_2SO_4}}=\dfrac{0,2}{0,5}=0,4M\)
c)\(C_{M_{FeSO_4}}=\dfrac{0,2}{0,5}=0,4M\)
\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
pthh : \(Fe+H_2SO_4->FeSO_4+H_2\)
0,2 0,2
=> \(V_{H_2}=0,2.22,4=4,48\left(L\right)\)
\(m_{H_2SO_4}=\dfrac{0,5}{22,4}.98\approx2,188\left(g\right)\)
=> mdd=11,2+2,188=13,388(g)
C%=\(\dfrac{2,188}{13,388}.100\%=16,3\%\)
\(n_{Zn}=\dfrac{26}{65}=0,4\left(mol\right)\\ pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
0,4 0,8 0,4 0,4
\(a,V_{H_2}=0,4.22,4=8,96\left(l\right)\\ b,C\%_{HCl}=\dfrac{0,8.36,5}{150}.100\%=19,5\%\\ c,m_{\text{dd}}=26+150-\left(0,4.2\right)=175,2\left(g\right)\\ C\%_{ZnCl_2}=\dfrac{0,4.136}{175,2}.100\%=31\%\)
a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
\(m_{HCl}=100.14,6\%=14,6\left(g\right)\Rightarrow n_{HCl}=\dfrac{14,6}{36,5}=0,4\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,1}{1}< \dfrac{0,4}{2}\), ta được HCl dư.
Theo PT: \(n_{H_2}=n_{Zn}=0,1\left(mol\right)\Rightarrow V_{H_2}=0,1.22,4=2,24\left(l\right)\)
b, Theo PT: \(\left\{{}\begin{matrix}n_{HCl\left(pư\right)}=2n_{Zn}=0,2\left(mol\right)\\n_{ZnCl_2}=n_{Zn}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{HCl\left(dư\right)}=0,4-0,2=0,2\left(mol\right)\)
Ta có: m dd sau pư = 6,5 + 100 - 0,1.2 = 106,3 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,1.136}{106,3}.100\%\approx12,79\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,2.36,5}{106,3}.100\%\approx6,87\%\end{matrix}\right.\)
`Zn + 2HCl -> ZnCl_2 + H_2`
`0,1` `0,2` `0,1` `(mol)`
`n_[Zn]=[6,5]/65=0,1(mol)`
`a)V_[H_2]=0,1.22,4=2,24(l)`
`b)C%_[HCl]=[0,2.36,5]/200 . 100 =3,65%`
`Zn + HCl -> ZnCl_2 + H_2` `\uparrow`
`n_(Zn) = (6,5)/65 = 0,1 mol`.
`n_(H_2) = 0,1 mol`.
`V(H_2) = 0,1 xx 22,4 = 2,24l`.
`C%(HCl) = (0,2.36,5)/200 xx 100 = 36,5%`.
\(a,n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\)
PTHH: Zn + 2HCl ---> ZnCl2 + H2
0,125->0,25----->0,125->0,125
\(\Rightarrow\left\{{}\begin{matrix}a,V_{ddHCl}=\dfrac{0,25}{0,5}=0,5\left(l\right)\\b,V_{H_2}=0,125.22,4=2,8\left(l\right)\\c,C_{M\left(ZnCl_2\right)}=\dfrac{0,125}{0,5}=0,25M\end{matrix}\right.\)