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\(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\\ m_{HCl}=\dfrac{100.18,25}{100}=18,25\left(g\right)\\
n_{HCl}=\dfrac{18,25}{36,5}=0,5\\ pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
0,125 0,125 (mol )
\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(l\right)\\
\)
\(C\%=\dfrac{8,125}{8,125+18,25}.100\%=30,8\%\)
Bài 18:
Ta có: \(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\)
\(m_{HCl}=100.18,25\%=18,25\left(g\right)\Rightarrow n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)
a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, Xét tỉ lệ: \(\dfrac{0,125}{1}< \dfrac{0,5}{2}\), ta được HCl dư.
Theo PT: \(n_{H_2}=n_{Zn}=0,125\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(g\right)\)
\(m_{H_2}=0,125.2=0,25\left(g\right)\)
c, Theo PT: \(\left\{{}\begin{matrix}n_{ZnCl_2}=n_{Zn}=0,125\left(mol\right)\\n_{HCl\left(pư\right)}=2n_{Zn}=0,25\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{HCl\left(dư\right)}=0,25\left(mol\right)\)
Có: m dd sau pư = 8,125 + 100 - 0,25 = 107,875 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,125.136}{107,875}.100\%\approx15,76\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,25.36,5}{107,875}.100\%\approx8,46\%\end{matrix}\right.\)
Bạn tham khảo nhé!
nNa = 6.9 : 23 = 0.3 mol
4Na + O2 ->2 Na2O
mol : 0.3 -> 0.15
Na2O + H2O -> 2NaOH
mol : 0.15 -> 0.3
mdd = 0.15 x 62 + 140.7 = 150g
C% NaOH = 0.3x40: 150 x 100% = 8%
mCuSO4= 12,8(g) ->nCuSO4=0,2(mol)
nNa=0,04(mol)
pthh: Na + H2O -> NaOH + 1/2 H2
-> nNaOH= 0,04(mol); nH2=0,02(mol)
=> V(A,đktc)=V(H2,đktc)=0,02.22,4=0,448(l)
2 NaOH + CuSO4 -> Cu(OH)2 + Na2SO4
Ta có: 0,04/2 < 0,2/1
=> CuSO4 dư, NaOH hết, tính theo nNaOH
=> nCu(OH)2=nCuSO4(p.ứ)=nNa2SO4=nNaOH/2=0,02(mol)
=> m(B)=mCu(OH)2=0,02.98=1,96(g)
b) mddC=mddCuSO4 + mNaOH - mCu(OH)2= 400+ 0,04.40- 1,96= 399,64(g)
mCuSO4(dư)= 0,18 x 160=28,8(g)
mNa2SO4=0,02.142= 2,84(g)
=> C%ddCuSO4(dư)= (28,8/399,64).100=7,206%
C%ddNa2SO4=(2,84/399,64).100=0,711%
a) \(n_{Na}=\dfrac{4,6}{23}=0,2\left(mol\right)\)
PTHH: 2Na + 2H2O ---> 2NaOH + H2 => ddA là NaOH
0,2----------------->0,2------>0,1
b) \(V_{H_2}=0,1.22,4=2,24\left(l\right)\)
c) \(C_{M\left(NaOH\right)}=\dfrac{0,2}{0,4}=0,5M\)
a) PTHH: \(BaCO_3+2HCl\rightarrow BaCl_2+H_2O+CO_2\uparrow\)
Ta có: \(\left\{{}\begin{matrix}n_{BaCO_3}=\dfrac{68,95}{197}=0,35\left(mol\right)\\n_{HCl}=0,25\cdot3,2=0,8\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,35}{1}< \dfrac{0,8}{2}\) \(\Rightarrow\) Axit còn dư
\(\Rightarrow n_{HCl\left(dư\right)}=0,8-0,35\cdot2=0,1\left(mol\right)\) \(\Rightarrow m_{HCl\left(dư\right)}=0,1\cdot36,5=3,65\left(g\right)\)
b+c) Theo PTHH: \(\left\{{}\begin{matrix}n_{CO_2}=n_{BaCl_2}=0,35\left(mol\right)\\n_{HCl\left(dư\right)}=0,1\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{CO_2}=0,35\cdot22,4=7,84\left(l\right)\\C_{M_{BaCl_2}}=\dfrac{0,35}{0,25}=1,4\left(M\right)\\C_{M_{HCl\left(dư\right)}}=\dfrac{0,1}{0,25}=0,4\left(M\right)\end{matrix}\right.\)
a. PTHH: Na2CO3 + 2HCl \(\rightarrow\) 2NaCl + H2O +CO2
Ta có : nNa2CO3 = \(\frac{200.10,6}{100.106}\) = 0,2 mol
nHCl = \(\frac{400.14,6}{100.36,5}\) = 1,6 mol
Tỉ số: \(\frac{0,2}{1}\) < \(\frac{1,6}{2}\) \(\Rightarrow\) Na2CO3 hết. HCl dư
THeo ptr: nCO2 = nNa2CO3 = 0,2 mol
\(\Rightarrow\) VCO2 = 0,2 . 22,4 = 4,48(l)
b. Dung dịch A gồm NaCl và HCl (dư)
Theo pt: nNaCl = 2.nNa2CO3= 2.0,2=0,4 mol
\(\Rightarrow\) mNaCl = 0,4.58,5= 23,4 g
mCO2 = 0,2 . 44= 8,8 (g)
Ta có : mdd A= mdd Na2Co3 + mdd HCl - m CO2
= 200 + 400 - 8,8 = 591,2(g)
\(\Rightarrow\) C%dd NaCl = \(\frac{23,4}{591,2}.100\) = 4%
Theo pt: nHCl ( p.ứ) = 2. nNa2CO3 = 2. 0,2 = 0,4 mol
\(\Rightarrow\) nHCl (dư) = 1,6 - 0,4 =1,2 mol
\(\Rightarrow\) mHCl ( dư) = 1,2 . 36,5 = 43,8(g)
C%dd HCl (dư)= \(\frac{43,8}{591,2}.100\) = 7,41 %
\(n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\\ m_{HCl}=\dfrac{109,5\cdot10\%}{100\%}=10,95\left(g\right)\\ \Rightarrow n_{HCl}=\dfrac{10,95}{36,5}=0,3\left(mol\right)\\ a,PTHH:Mg+2HCl\rightarrow MgCl_2+H_2\\ \text{Vì }\dfrac{n_{Mg}}{1}< \dfrac{n_{HCl}}{2}\text{ nên sau p/ứ }HCl\text{ dư}\\ \Rightarrow n_{H_2}=0,1\left(mol\right)\\ \Rightarrow V_{H_2\left(đktc\right)}=0,1\cdot22,4=2,24\left(l\right)\)
\(b,n_{MgCl_2}=0,1\left(mol\right)\\ \Rightarrow m_{CT_{MgCl_2}}=0,1\cdot95=9,5\left(g\right)\\ m_{H_2}=0,1\cdot2=0,2\left(mol\right)\\ m_{dd_{MgCl_2}}=2,4+109,5-0,2=111,7\left(g\right)\\ \Rightarrow C\%_{MgCl_2}=\dfrac{9,5}{111,7}\cdot100\%\approx8,5\%\)
2Na+2H2O->2NaOH+H2
0,3------0,3------0,3------0,15
n Na=\(\dfrac{6,9}{23}\)=0,3 mol
=>VH2=0,15.22,4=3,36l
=>C%NaCl=\(\dfrac{12}{6,9+90-0,15.2}\)=12,422 %