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\(a.Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right);n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\\ LTL:\dfrac{0,2}{1}< \dfrac{0,5}{2}\Rightarrow HCldư\\ n_{HCl\left(pứ\right)}=2n_{Zn}=0,4\left(mol\right)\\\Rightarrow m_{HCl\left(dư\right)}=\left(0,5-0,4\right).36,5=3,65\left(g\right)\\ b.n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right)\\ \Rightarrow m_{ZnCl_2}=0,2.136=27,2\left(g\right)\\ c.n_{H_2}=n_{Zn}=0,2\left(mol\right)\\ \Rightarrow V_{H_2}=0,2.22,4,=4,48\left(l\right)\\ d.3H_2+Fe_2O_3-^{t^o}\rightarrow2Fe+3H_2O \\ n_{Fe_2O_3}=\dfrac{19,2}{160}=0,12\left(mol\right)\\ LTL:\dfrac{0,2}{3}< \dfrac{0,12}{1}\Rightarrow Fe_2O_3dưsauphảnứng\\ \Rightarrow n_{Fe}=\dfrac{2}{3}n_{H_2}=\dfrac{2}{15}\left(mol\right)\\ \Rightarrow m_{Fe}=\dfrac{2}{15}.56=7,467\left(g\right)\)
a) n\(Zn\)=\(\dfrac{m}{M}\)=\(\dfrac{13}{65}\)=0,2(mol)
n\(HCl\)=\(\dfrac{m}{M}\)=\(\dfrac{18,25}{36,5}=\)0,5(mol)
PTHH : Zn + 2HCl->ZnCl\(2\) + H\(2\)
0,2 0,5
Lập tỉ lệ mol : \(^{\dfrac{0,2}{1}}\)<\(\dfrac{0,5}{2}\)
n\(Zn\) hết , n\(HCl\) dư
-->Tính theo số mol hết
Zn + 2HCl->ZnCl\(2\) + H\(2\)
0,2 -> 0,4 0,2 0,2
n\(HCl\) dư= n\(HCl\)(đề) - n\(HCl\)(pt)= 0,5 - 0,4 = 0,1(mol)
m\(HCl\) dư= 0,1.36,5 = 3,65(g)
b) m\(ZnCl2\) = n.M= 0,2.136= 27,2 (g)
c)V\(H2\)=n.22,4=0,2.22,4=4,48(l)
d) n\(Fe\)\(2\)O\(3\)=\(\dfrac{m}{M}\)=\(\dfrac{19,2}{160}\)=0,12 (mol)
3H2 +Fe2O3 → 2Fe + 3H2O
0,2 0,12
Lập tỉ lệ mol: \(\dfrac{0,2}{3}\)<\(\dfrac{0,12}{1}\)
nH2 hết .Tính theo số mol hết
\(HCl\)
3H2 +Fe2O3 → 2Fe + 3H2O
0,2-> 0,2
m\(Fe\)=n.M= 0,2.56= 11,2(g)
\(n_{Zn}=\dfrac{6.5}{65}=0.1\left(mol\right)\)
\(n_{HCl}=\dfrac{100\cdot14.6\%}{36.5}=0.4\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(1........2\)
\(0.1......0.4\)
\(LTL:\dfrac{0.1}{1}< \dfrac{0.4}{2}\Rightarrow HCldư\)
\(V_{H_2}=0.1\cdot22.4=2.24\left(l\right)\)
\(m_{\text{dung dịch sau phản ứng}}=6.5+100-0.1\cdot2=106.3\left(g\right)\)
\(C\%ZnCl_2=\dfrac{0.1\cdot136}{106.3}\cdot100\%=12.79\%\)
\(C\%HCl\left(dư\right)=\dfrac{\left(0.4-0.2\right)\cdot36.5}{106.3}\cdot100\%=6.87\%\%\)
1)
a) Fe + 2HCl --> FeCl2 + H2
b) \(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
0,15->0,3--->0,15-->0,15
=> VH2 = 0,15.22,4 = 3,36 (l)
c) mdd sau pư = 8,4 + 250 - 0,15.2 = 258,1 (g)
=> \(C\%_{FeCl_2}=\dfrac{0,15.127}{258,1}.100\%=7,38\%\)
2)
a) Zn + 2HCl --> ZnCl2 + H2
b) \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
PTHH: Zn + 2HCl --> ZnCl2 + H2
0,2-->0,4---->0,2--->0,2
=> VH2 = 0,2.22,4 = 4,48 (l)
mZnCl2 = 0,2.136 = 27,2 (g)
c) \(C_{M\left(dd.HCl\right)}=\dfrac{0,4}{0,2}=2M\)
d)
PTHH: A + 2HCl --> ACl2 + H2
0,2<--0,4
=> \(M_A=\dfrac{4,8}{0,2}=24\left(g/mol\right)\)
=> A là Mg(Magie)
\(n_{Zn}=\dfrac{13}{65}=0.2\left(mol\right)\)
\(n_{HCl}=\dfrac{182.5\cdot10}{100\cdot36.5}=0.5\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(0.2......0.4..........0.2........0.2\)
\(n_{HCl\left(dư\right)}=0.5-0.4=0.1\left(mol\right)\)
\(m_{HCl\left(dư\right)}=0.1\cdot36.5=3.65\left(g\right)\)
\(V_{H_2}=0.2\cdot22.4=4.48\left(l\right)\)
\(m_{\text{dung dịch sau phản ứng}}=13+182.5-0.2\cdot2=195.1\left(g\right)\)
\(C\%_{HCl\left(dư\right)}=\dfrac{3.65}{195.1}\cdot100\%=1.87\%\)
\(C\%_{ZnCl_2}=\dfrac{0.2\cdot136}{195.1}\cdot100\%=13.94\%\)
a)
$2Al +3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2$
b)
$n_{H_2} = n_{H_2SO_4} = \dfrac{300.9,8\%}{98} = 0,3(mol)$
$V_{H_2} = 0,3.22,4 = 6,72(lít)$
c)
$n_{Al_2(SO_4)_3} = \dfrac{1}{3}n_{H_2SO_4} = 0,1(mol)$
$m_{Al_2(SO_4)_3} = 0,1.342 = 34,2(gam)$
d)
$n_{Al} = \dfrac{2}{3}n_{H_2SO_4} = 0,2(mol)$
$m_{dd} = 0,2.27 + 300 - 0,3.2 = 304,8(gam)$
$C\%_{Al_2(SO_4)_3} = \dfrac{34,2}{304,8}.100\% = 11,22\%$
nH2SO4=0,3(mol)
PTHH: 2Al + 3 H2SO4 -> Al2(SO4)3 + 3 H2
a) 0,2_______0,3______0,1______0,3(mol)
b) V(H2,đktc)=0,3.22,4=6,72(l)
c) a=mAl=0,2.27=5,4(g)
=>a=5,4(g)
d) mAl2(SO4)3=342.0,1=34,2(g)
e) mddAl2(SO4)3= 5,4+ 300 - 0,3.2= 304,8(g)
=>C%ddAl2(SO4)3= (34,2/304,8).100=11,22%
\(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\)
\(m_{HCl}=\dfrac{150.18,25}{100}=27,375\left(g\right)\)
\(n_{HCl}=\dfrac{27,375}{36,5}=0,75\left(mol\right)\)
PTHH :
\(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
trc p/u : 0,3 0,75
p/u: 0,3 0,6 0,3 0,3
sau p/u : 0 0,15 0,3 0,3
---> Sau p/ư HCl dư
\(a,V_{H_2}=0,3.22,4=6,72\left(l\right)\)
\(b,m_{ddHCl}=0,6.36,5=21,9\left(g\right)\)
\(c,m_{ZnCl_2}=0,3.136=40,8\left(g\right)\)
\(m_{ddZnCl_2}=19,5+150-\left(0,3.2\right)=168,9\left(g\right)\)
\(C\%=\dfrac{40,8}{168,9}.100\%\approx24,16\%\)
mH2SO4=9,8%.300=29,4(g)
=> nH2SO4=0,3(mol)
a) PTHH: 2Al +3 H2SO4 -> Al2(SO4)3 + 3 H2
0,2<-------------0,3----------->0,1------------->0,3(mol)
b) a=mAl=0,2.27=5,4(g)
c) V(H2,đktc)=0,3.22,4=6,72(l)
d) mAl2(SO4)3=0,1.342=34,2(g)
e) mddAl2(SO4)3=mAl+mddH2SO4- mH2= 5,4+300-0,3.2= 304,8(g)
=> C%ddAl2(SO4)3=(34,2/304,8).100=11,22%
a) 2Al+ 3H2SO4→ Al2(SO4)3+ 3H2
(mol) 0,2 0,3 0,1 0,3
b) m H2SO4= 300. 9,8%= 29,4(g)
n H2SO4= \(\dfrac{m}{M}=\dfrac{29,4}{98}=0,3\)(mol)
c) V H2= n.22,4= 0,3.22,4= 6,72(lít)
m H2= n.m= 0,3.2= 0,6(g)
d) m Al2(SO4)3= n.M= 0,1.342= 34,2(g)
e) mAl= n.M= 0,2.27= 5,4(g)
mddsau phản ứng= mAl+ mdd H2SO4- m H2
= 5,4+300-0,6= 304,8(g)
=> C%ddsau phản ứng= \(\dfrac{34,2}{304,8}.100\%=11,22\%\)
\(\begin{array} {l} a)\\ Zn+H_2SO_4\to ZnSO_4+H_2\\ b)\\ n_{Zn}=\dfrac{32,5}{65}=0,5(mol)\\ n_{H_2SO_4}=\dfrac{100.39,2\%}{98}=0,4(mol)\\ \text{Vì }n_{H_2SO_4}<n_{Zn}\to Zn\text{ dư}\\ \text{Theo PT: }n_{H_2}=n_{H_2SO_4}=0,4(mol)\\ \to V_{H_2}=0,4.22,4=8,96(l)\\ c)\\ \text{Theo PT: }n_{ZnSO_4}=n_{H_2SO_4}=0,4(mol)\\ \to m=m_{ZnSO_4}=0,4.161=64,4(g) \end{array}\)
\(n_{Zn}=\dfrac{32,6}{65}=0,5\left(mol\right)\\ n_{H_2SO_4}=\dfrac{100.39,2\%}{98}=0,4\left(mol\right)\\ pthh:Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\)
\(\dfrac{0,5}{1}>\dfrac{0,4}{1}\)
=>Zn dư
\(n_{H_2}=n_{H_2SO_4}=0,4\left(mol\right)\\ V_{H_2}=0,4.22,4=8,96\left(l\right)\)
\(n_{ZnSO_4}=n_{H_2SO_4}=0,4\left(mol\right)\\
m_{ZnSO_4}=0,4.161=64,4\left(g\right)\)
\(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\\ m_{HCl}=\dfrac{100.18,25}{100}=18,25\left(g\right)\\ n_{HCl}=\dfrac{18,25}{36,5}=0,5\\ pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
0,125 0,125 (mol )
\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(l\right)\\ \)
\(C\%=\dfrac{8,125}{8,125+18,25}.100\%=30,8\%\)
Bài 18:
Ta có: \(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\)
\(m_{HCl}=100.18,25\%=18,25\left(g\right)\Rightarrow n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)
a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, Xét tỉ lệ: \(\dfrac{0,125}{1}< \dfrac{0,5}{2}\), ta được HCl dư.
Theo PT: \(n_{H_2}=n_{Zn}=0,125\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(g\right)\)
\(m_{H_2}=0,125.2=0,25\left(g\right)\)
c, Theo PT: \(\left\{{}\begin{matrix}n_{ZnCl_2}=n_{Zn}=0,125\left(mol\right)\\n_{HCl\left(pư\right)}=2n_{Zn}=0,25\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{HCl\left(dư\right)}=0,25\left(mol\right)\)
Có: m dd sau pư = 8,125 + 100 - 0,25 = 107,875 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,125.136}{107,875}.100\%\approx15,76\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,25.36,5}{107,875}.100\%\approx8,46\%\end{matrix}\right.\)
Bạn tham khảo nhé!