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a, \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
Ta có: \(n_{C_2H_4}+n_{C_2H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\left(1\right)\)
Theo PT: \(n_{Br_2}=n_{C_2H_4}+2n_{C_2H_2}=0,25.2=0,5\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{C_2H_4}=0,3\left(mol\right)\\n_{C_2H_2}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,3.22,4}{8,96}.100\%=75\%\\\%V_{C_2H_2}=25\%\end{matrix}\right.\)
b, Theo PT: \(\left\{{}\begin{matrix}n_{C_2H_4Br_2}=n_{C_2H_4}=0,3\left(mol\right)\\n_{C_2H_2Br_4}=n_{C_2H_2}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{C_2H_4Br_2}=0,3.188=56,4\left(g\right)\\m_{C_2H_2Br_4}=0,1.346=34,6\left(g\right)\end{matrix}\right.\)
\(n_{Br_2}=\dfrac{m_{Br_2}}{M_{Br_2}}=\dfrac{56}{160}=0,35mol\)
Gọi \(n_{C_2H_4}\) là x \(\Rightarrow V_{C_2H_4}=22,4x\)
\(n_{C_2H_2}\) là y \(\Rightarrow V_{C_2H_2}=22,4y\)
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
x x ( mol )
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
y 2y ( mol )
Ta có:
\(\left\{{}\begin{matrix}22,4x+22,4y=5,6\\x+2y=0,35\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,15\\y=0,1\end{matrix}\right.\)
\(\Rightarrow V_{C_2H_4}=22,4.0,15=3,36l\)
\(\Rightarrow V_{C_2H_2}=22,4.0,1=2,24l\)
\(\%V_{C_2H_4}=\dfrac{3,36}{5,6}.100=60\%\)
\(\%V_{C_2H_2}=\dfrac{2,24}{5,6}.100=40\%\)
nhh khí = 5,6/22,4 = 0,25 (mol)
Gọi nC2H4 = a (mol); nC2H2 = b (mol)
a + b = 0,25 (1)
nBr2 = 56/160 = 0,35 (mol)
PTHH:
C2H4 + Br2 -> C2H4Br2
Mol: a ---> a
C2H2 + 2Br2 -> C2H2Br4
Mol: b ---> 2b
a + 2b = 0,35 (2)
(1)(2) => a = 0,15 (mol); b = 0,1 (mol)
%VC2H2 = 0,15/0,25 = 60%
%VC2H4 = 100% - 60% = 40%
\(n_{HCl}=2.0,4=0,8(mol)\\ n_{Fe}=x(mol);n_{Al}=y(mol)\\ \Rightarrow 56x+27y=11(1)\\ Fe+2HCl\to FeCl_2+H_2\\ 2Al+6HCl\to 2AlCl_3+3H_2\\ \Rightarrow 2x+3y=0,8(2)\\ (1)(2)\Rightarrow x=0,1(mol);y=0,2(mol)\)
\(a,\Sigma n_{H_2}=x+1,5y=0,4(mol)\\ \Rightarrow V_{H_2}=0,4.22,4=8,96(l)\\ b,m_{Fe}=0,1.56=5,6(g);m_{Al}=0,2.27=5,4(g)\\ c,m_{dd_{HCl}}=400.1,12=448(g)\\ n_{FeCl_2}=0,1(mol);n_{AlCl_3}=0,2(mol)\\ \Rightarrow C\%_{FeCl_2}=\dfrac{0,1.127}{5,6+448-0,1.2}.100\%=2,8\%\\ C\%_{AlCl_3}=\dfrac{0,2.133,5}{5,4+448-0,3.2}.100\%=5,9\%\)
a)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
b)
Gọi số mol C2H2, C2H4 là a, b
=> \(a+b=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
\(n_{Br_2}=\dfrac{22,4}{160}=0,14\left(mol\right)\)
PTHH:\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
a---->2a
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
b--->b
=> 2a + b = 0,14
=> a = 0,04; b = 0,06
\(\left\{{}\begin{matrix}\%V_{C_2H_2}=\dfrac{0,04}{0,1}.100\%=40\%\\\%V_{C_2H_4}=\dfrac{0,06}{0,1}.100\%=60\%\end{matrix}\right.\)
a)
\(n_{Br_2}=\dfrac{8}{160}=0,05\left(mol\right)\)
PTHH: C2H4 + Br2 --> C2H4Br2
0,05<--0,05
=> \(V_{C_2H_4}=0,05.22,4=1,12\left(l\right)\)
=> \(V_{CH_4}=4,48-1,12=3,36\left(l\right)\)
b) \(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{1,12}{4,48}.100\%=25\%\\\%V_{CH_4}=\dfrac{3,36}{4,48}.100\%=75\%\end{matrix}\right.\)
a)
Khí còn lại là CH4
\(n_{CH_4}=\dfrac{0,448}{22,4}=0,02\left(mol\right)\)
=> \(n_{C_2H_4}=\dfrac{1,16-0,02.16}{28}=0,03\left(mol\right)\)
\(\%V_{CH_4}=\dfrac{0,02}{0,02+0,03}.100\%=40\%\)
\(\%V_{C_2H_4}=\dfrac{0,03}{0,02+0,03}.100\%=60\%\)
b)
PTHH: CH4 + 2O2 --to--> CO2 + 2H2O
0,02-------------->0,02
C2H4 + 3O2 --to--> 2CO2 + 2H2O
0,03------------->0,06
=> nCO2 = 0,02 + 0,06 = 0,08 (mol)
PTHH: Ca(OH)2 + CO2 --> CaCO3 + H2O
0,08----->0,08
=> mCaCO3 = 0,08.100 = 8 (g)
\(\left\{{}\begin{matrix}C_2H_4:x\left(mol\right)\\C_2H_2:y\left(mol\right)\end{matrix}\right.\)⇒ x + y = \(\dfrac{6,72}{22,4}=0,3\left(1\right)\)
\(C_2H_4 + Br_2 \to C_2H_4Br_2\\ C_2H_2 + 2Br_2 \to C_2H_2Br_4\)
Theo PTHH :
x + 2y = \(\dfrac{64}{160} = 0,4(2)\)
Từ (1)(2) suy ra: x = 0,2 ; y = 0,1
Vậy :
\(\%V_{C_2H_4} = \dfrac{0,2}{0,3}.100\% = 66,67\%\\ \%V_{C_2H_2} = 100\% - 66,67\% = 33,33\%\)
\(n_{CO_2}=0.3\left(mol\right)\)
\(Đặt:n_{C_2H_2}=a\left(mol\right),n_{C_2H_4}=b\left(mol\right)\)
\(n_{Br_2}=\dfrac{64}{160}=0.4\left(mol\right)\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(\left\{{}\begin{matrix}a+b=0.3\\2a+b=0.4\end{matrix}\right.\)
\(\Leftrightarrow\left\{{}\begin{matrix}a=0.1\\b=0.2\end{matrix}\right.\)
\(\%V_{C_2H_2}=\dfrac{0.1}{0.3}\cdot100\%=33.33\%\)
\(\%V_{C_2H_4}=66.67\%\)
C2H4 + Br2--> C2H4Br2
C2H2 + 2Br2---> C2H2Br4
Gọi nC2H4 =a , nC2H2=b
=> a+b=6,72/22,4=0,3
a+2b=0,2.2=0,4
=> a=0,2 ; b=0,1
=> %VC2H4=66,666%
%VC2H2=33,334%
đổi 200ml = 0,2 l
nBr2 = 0,2 . 2 = 0,4 (mol)
nhỗn hợp = \(\frac{6,72}{22,4}\) = 0,3 (mol)
gọi số mol của C2H4 là x (mol )
gọi số mol của C2H2 là y (mol )
ta có : nhỗn hợp = nC2H4 + nC2H2
hay x+y=0,3 (*)
có PTHH : C2H4 +Br2 \(\rightarrow\) C2H4Br2 (1)
(mol) x x x
có PTHH : C2H2 +2Br2 \(\rightarrow\) C2H2Br4 (2)
(mol ) y 2y y
lại có : nBr2 t/g =nBr2 (1) +nBr2(2)
hay : x+2y = 0,4 (**)
từ (*) và (**) ta có hệ phương trình
\(\left\{{}\begin{matrix}x+y=0,3\\x+2y=0,4\end{matrix}\right.\)
giải hệ phương trình ta được : x =0,2 ; y=0,1
phần trăm thể tích từng khí là :
%VC2H4=\(\frac{0,2.22,4}{6,72}.100\%\)=66,67%
%VC2H2\(\frac{0,1.224}{6,72}.100\%\)=33,33%