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nO2 = 3,36 : 22,4 = 0,15 (mol)
pthh : 2Mg + O2 -t--> 2MgO
0,3<----0,15---> 0,3 (mol)
=> mMg= 0,3 . 24 = 7,2 (g)
=> mMgO = 0,3 . 40 =12 (g)
pthh : 2KMnO4 -t--> K2MnO4 + MnO2 + O2
0,3<-------------------------------------0,15 (mol)
=> mKMnO4 = 0,3 . 158 = 47,4 (g)
\(n_{Mg}=\dfrac{13}{24}=0,54mol\)
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
0,54 0,54 ( mol )
\(m_{MgCl_2}=0,54.95=51,3g\)
\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\)
0,54 0,54 ( mol )
\(m_{Cu}=0,54.64=34,56g\)
\(n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\\
pthh:Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
0,1 0,1 0,1
\(m_{MgSO_4}=120.0,1=12\left(g\right)\\
n_{CuO}=\dfrac{48}{80}=0,6\left(mol\right)\\
pthh:CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
\(LTL:\dfrac{0,6}{1}>\dfrac{0,1}{1}\)
=> CuO dư
\(n_{CuO\left(P\text{Ư}\right)}=n_{H_2}=0,1\left(mol\right)\\
m_{CuO\left(d\right)}=\left(0,6-0,1\right).80=40\left(g\right)\)
nMg=2,424=0,1(mol)pthh:Mg+H2SO4→MgSO4+H2nMg=2,424=0,1(mol)pthh:Mg+H2SO4→MgSO4+H2
0,1 0,1 0,1
mMgSO4=120.0,1=12(g)nCuO=4880=0,6(mol)pthh:CuO+H2to→Cu+H2OmMgSO4=120.0,1=12(g)nCuO=4880=0,6(mol)pthh:CuO+H2to→Cu+H2O
mMg = 3.6/24 = 0.15 (mol)
2Mg + O2 -to-> 2MgO
0.15__0.075____0.15
mMgO= 0.15*40 = 6 (g)
VO2 = 0.075*22.4 = 1.68 (l)
2KClO3 -to-> 2KCl + 3O2
0.05_______________0.075
mKClO3 = 0.05*122.5 = 6.125 (g)
PTHH: \(2Mg+O_2\underrightarrow{t^o}2MgO\)
a+b) Ta có: \(n_{Mg}=\dfrac{3,6}{24}=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{O_2}=0,075\left(mol\right)\\n_{MgO}=0,15\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{O_2}=0,075\cdot22,4=1,68\left(l\right)\\m_{MgO}=0,15\cdot40=6\left(g\right)\end{matrix}\right.\)
c) PTHH: \(2KClO_3\xrightarrow[MnO_2]{t^o}2KCl+3O_2\uparrow\)
Theo PTHH: \(n_{KClO_3}=0,05\left(mol\right)\)
\(\Rightarrow m_{KClO_3}=0,05\cdot122,5=6,125\left(g\right)\)
a. \(PTHH:Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
\(n_{Mg}=\dfrac{m_{Mg}}{M_{Mg}}=\dfrac{12}{24}=0,5\left(mol\right)\)
- Mol theo PTHH : \(1:2:1:1\)
- Mol theo phản ứng : \(0,5\rightarrow1\rightarrow0,5\rightarrow0,5\)
\(\Rightarrow n_{H_2}=0,5\left(mol\right)\)
\(\Rightarrow V_{H_2}=n_{H_2}.22,4=0,5.22,4=11,2\left(l\right)\)
b. Từ a. \(\Rightarrow n_{HCl}=1\left(mol\right)\)
\(\Rightarrow m_{HCl}=n_{HCl}.M_{HCl}=1.\left(1+35,5\right)=36,5\left(g\right)\)
c. \(n_{O_2}=\dfrac{V_{O_2}}{22,4}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
\(PTHH:2H_2+O_2\underrightarrow{t^o}2H_2O\)
- Mol theo PTHH : \(2:1:2\)
- Mol theo phản ứng : \(0,6\leftarrow0,3\rightarrow0,6\)
\(\Rightarrow n_{H_2O}=0,6\left(mol\right)\)
\(\Rightarrow m_{H_2O}=n_{H_2O}.M_{H_2O}=0,6.\left(2+16\right)=10,8\left(g\right)\)
a)\(n_{Mg}=\dfrac{35,6}{24}=1,483\left(mol\right)\)
\(V_{O2\left(đktc\right)}=\dfrac{21,504}{22,4}=0,96\left(mol\right)\)
pt: 2Mg + O2 → 2MgO (1)
mol: 2 1 2
mol:1,483 0,96
Tỉ lệ: \(\dfrac{1,483}{2}=0,7415< \dfrac{0,96}{1}=0,96\)
Mg tác dụng hết. O2 dư
theo PTHH có
\(n_{O2p\intư}=\dfrac{1,843x1}{2}=0,7415\left(mol\right)\)
nO2 dư=1,843-0,7415=1,1015 (mol)
mO2dư= 1,1015 x 32 = 35,48 (g)
b)theo PTHH có
\(n_{MgO}=\dfrac{1,843x2}{2}=1,843\left(mol\right)\)
nMgO = 1,843 X 40 = 73,72 (g)
c)
nMg PT(1)=nMgPT(2)=1,843 (mol)
pt: Mg + H2SO4 ➝ MgSO4 + H2 (2)
mol: 1 1 1 1
mol: 1,843
Theo PTHH có
\(n_{H2}=\dfrac{1,843x1}{1}=1,843\) (mol)
mH2=1,843 x 2 = 3,686 (g)