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\(Pt: Fe + 2HCl \rightarrow FeCl_2 + H_2\)
\(a.n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
Theo pt: \(nH_2 = nFe = 0,2 mol\)
\(\Rightarrow V_{H_2}=0,2.22,4=4,48l\)
\(b.n_{FeCl_2}=n_{Fe}=0,2\left(mol\right)\)
\(\Rightarrow m_{FeCl_2}=0,2.127=25.4g\)
\(c.n_{HCl}=2nFe=0,4mol\)
\(C_MHCl=\dfrac{0,4}{0,1}=4M\)
a/ Fe + 2HCl \(\rightarrow\) FeCl2 + H2
nH2 = \(\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
Theo PTHH: nH2 = nFe = 0,15 (mol) \(\Rightarrow m_{Fe}=0,15.56=8,4\left(g\right)\)
\(\Rightarrow m_{Cu}=11-8,4=2,6\left(g\right)\)
\(\Rightarrow\%m_{Fe}=\dfrac{8,4}{11}.100\%\approx76,4\%\)
\(\Rightarrow\%m_{Cu}=100-76,4\approx23,6\%\)
b/ Theo PTHH ta có: nHCl = 2nFe = 2.0,15 = 0,3 (mol)
\(\Rightarrow V_{ddHCl}=\dfrac{0,3}{2}=0,15\left(M\right)\)
c/ mHCl = 36,5 . 0,3 = 10,95(g)
\(\Rightarrow C\%_{HCl}=\dfrac{m_{HCl}}{m_{ddHCl}}.100\%=\dfrac{10,95}{200}.100\%=5,475\%\)
a, PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
Ta có: \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
Theo PT: \(n_{Fe}=n_{H_2}=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,15.56}{11}.100\%\approx76,36\%\\\%m_{Cu}\approx23,64\%\end{matrix}\right.\)
b, Theo PT: \(n_{HCl}=2n_{H_2}=0,3\left(mol\right)\)
\(\Rightarrow V_{ddHCl}=\dfrac{0,3}{2}=0,15\left(l\right)\)
c, \(C\%_{HCl}=\dfrac{0,3.36,5}{200}.100\%=5,475\%\)
a, \(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\)
\(m_{HCl}=109,5.10\%=10,95\left(g\right)\Rightarrow n_{HCl}=\dfrac{10,95}{36,5}=0,3\left(mol\right)\)
PTHH: 2Al + 6HCl → 2AlCl3 + 3H2
Mol: 0,1 0,3 0,1 0,15
Ta có: \(\dfrac{0,1}{2}=\dfrac{0,3}{6}\) ⇒ Al hết, HCl hết
\(V_{H_2}=0,15.22,4=3,36\left(l\right)\)
b, \(m_{AlCl_3}=0,1.133,5=13,35\left(g\right)\)
c, mdd sau pứ = 2,7 + 109,5 - 0,15.2 = 111,9 (g)
\(C\%_{ddAlCl_3}=\dfrac{13,35.100\%}{111,9}=11,93\%\)
PTHH: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
Ta có: \(\left\{{}\begin{matrix}n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\\n_{HCl}=\dfrac{109,5\cdot10\%}{36,5}=0,3\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,1}{2}=\dfrac{0,3}{6}\) \(\Rightarrow\) Al và HCl đều p/ứ hết
\(\Rightarrow\left\{{}\begin{matrix}n_{AlCl_3}=0,1\left(mol\right)\\n_{H_2}=0,15\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{AlCl_3}=0,1\cdot133,5=13,35\left(g\right)\\V_{H_2}=0,15\cdot22,4=3,36\left(l\right)\\m_{H_2}=0,15\cdot2=0,3\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{Al}+m_{ddHCl}-m_{H_2}=111,9\left(g\right)\)
\(\Rightarrow C\%_{AlCl_3}=\dfrac{13,35}{111,9}\cdot100\%\approx11,93\%\)
PTHH\(Na_2CO_3+2HCl\rightarrow2NaCl+H_2O+CO_2\)
tl............1................2.............2.............1.............1..(mol
br 0,1.................0,2......................................0,1(mol)
NaCl không phản ứng đc vsHCl
b)\(n_{CO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
\(C_{MHCl}=\dfrac{0,2}{0,4}=0,5\left(M\right)\)(đổi 400ml=0,4(l))
c)\(Tacom_{Na_2CO_3}=0,1.106=10,6\left(g\right)\)
\(\Rightarrow\%m_{Na_2CO_3}=\dfrac{10,6}{20}.100=53\%\)
\(\Rightarrow\%mNaCl=100\%-53\%=47\%\)
CaCO3 + 2HCl -> CaCl2 + CO2 + H2O
0,2...........0,4..............0,2.....0,2 (mol)
nCaCO3 = 0,2 (mol)
VCO2 = 4,48 (l)
m dung dịch HCl = \(\frac{0,4.36,5}{14,6\%}=100\left(g\right)\)
C%CaCl2 = \(\frac{111.0,2}{20+100-0,2.44}.100\%\approx19,96\%\)