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\(n_{CuCl_2}=0,25.0,1=0,025(mol)\\ CuCl_2+2NaOH\to Cu(OH)_2\downarrow+2NaCl\\ \Rightarrow n_{Cu(OH)_2}=0,025(mol);n_{NaOH}=0,05(mol)\\ a,m_{Cu(OH)_2}=0,025.98=2,45(g)\\ b,C_{M_{NaOH}}=\dfrac{0,05}{0,2}=0,025M\\ 2NaCl+H_2SO_4\to Na_2SO_4+2HCl\\ \Rightarrow n_{H_2SO_4}=0,025(mol)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{0,025.98}{36,5\%}\approx 6,712(g)\)
\(a)n_{H_2}=\dfrac{2,24}{22,4}=0,1mol\\
Fe+2HCl\rightarrow FeCl_2+H_2\)
0,1 0,2 0,1 0,1
\(n_{Fe_2O_3}=\dfrac{21,6-56.0,1}{160}=0,1mol\\
Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2\)
0,1 0,6 0,2 0,3
\(V_{ddHCl}=\dfrac{0,2+0,6}{1}=0,8l\\
b.C_{M_{FeCl_2}}=\dfrac{0,1}{0,8}=0,125M\\
C_{M_{FeCl_3}}=\dfrac{0,2}{0,8}=0,25M\)
PTHH: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\)
\(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
a+b) Ta có: \(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)=n_{H_2SO_4}=n_{ZnSO_4}\)
\(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,3}{0,2}=1,5\left(M\right)=C_{M_{ZnSO_4}}\)
c) Theo PTHH: \(n_{H_2}=n_{Zn}=0,3mol\) \(\Rightarrow V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\)
d) Theo PTHH: \(n_{Fe}=\dfrac{2}{3}n_{H_2}=0,2mol\)
\(\Rightarrow m_{Fe}=0,2\cdot56=11,2\left(g\right)\)
a)
$K_2SO_4 + BaCl_2 \to BaSO_4 + 2KCl$
b)
$n_{K_2SO_4} = 0,2.2 = 0,4(mol)$
$n_{BaCl_2} = 0,3.1 = 0,3(mol)$
Ta thấy :
$n_{K_2SO_4} : 1 > n_{BaCl_2} : 1$ nên $K_2SO_4$ dư
$n_{BaSO_4} = n_{BaCl_2} = 0,3(mol)$
$m_{BaSO_4} = 0,3.233 = 69,9(gam)$
c) $n_{K_2SO_4} = 0,4 - 0,3 = 0,1(mol)$
$V_{dd\ sau\ pư} = 0,2 + 0,3 = 0,5(lít)$
$C_{M_{K_2SO_4} } = \dfrac{0,1}{0,5} = 0,2M$
$C_{M_{KCl}} = \dfrac{0,6}{0,5} = 1,2M$
a) CT oxit \(AO\)
\(AO+2HCl\rightarrow ACl_2+H_2\\ n_{HCl}=0,4\left(mol\right)\\ n_A=\dfrac{1}{2}n_{HCl}=0,2\left(mol\right)\\ \Rightarrow M_{AO}=A+16=\dfrac{8}{0,2}=40\\ \Rightarrow A=24\left(Mg\right)\)
b)\(n_{MgSO_3}=\dfrac{10,4}{104}=0,1\left(mol\right)\\ n_{H_2SO_4}=\dfrac{200.24,5\%}{98}=0,5\left(mol\right)\\ MgSO_3+H_2SO_4\rightarrow MgSO_4+SO_2+H_2O\\ LTL:\dfrac{0,1}{1}< \dfrac{0,5}{1}\\ \Rightarrow H_2SO_4dưsauphảnứng\\ n_{H_2SO_4\left(pứ\right)}=n_{SO_2}=n_{MgSO_4}=n_{MgSO_3}=0,1\left(mol\right)\\ n_{H_2SO_4\left(dư\right)}=0,5-0,1=0,4\left(mol\right)\\ m_{ddsaupu}=10,4+200-0,1.64=204\left(g\right)\\ C\%_{MgSO_4}=\dfrac{0,1.120}{204}.100=5,88\%\\ C\%_{H_2SO_4\left(dư\right)}=\dfrac{0,4.98}{204}=19,22\%\)
\(a,n_{AO}=\dfrac{8}{M_A+16}(mol);n_{HCl}=1.0,4=0,4(mol)\\ PTHH:AO+2HCl\to ACl_2+H_2O\\ \Rightarrow n_{AO}=\dfrac{1}{2}n_{HCl}=0,2(mol)\\ \Rightarrow M_{AO}=\dfrac{8}{0,2}=40(g/mol)\\ \Rightarrow M_{A}=40-16=24(g/mol)\\ \text {Vậy A là magie(Mg) và CTHH oxit là }MgO\\\)
\(b,n_{MgSO_3}=\dfrac{10,4}{104}=0,1(mol)\\ m_{H_2SO_4}=\dfrac{200.24,5\%}{100\%}=49(g)\\ \Rightarrow n_{H_2SO_4}=\dfrac{49}{98}=0,5(mol)\\ PTHH:MgSO_3+H_2SO_4\to MgSO_4+SO_2\uparrow +H_2O \)
Vì \(\dfrac{n_{MgSO_3}}{1}<\dfrac{n_{H_2SO_4}}{1}\) nên \(H_2SO_4\) dư
\(\Rightarrow n_{MgSO_4}=n_{SO_2}=n_{H_2O}=n_{MgSO_3}=0,1(mol)\\ \Rightarrow \begin{cases} m_{CT_{MgSO_4}}=0,1.120=12(g)\\ m_{SO_2}=0,1.64=6,4(g)\\ m_{H_2O}=0,1.18=1,8(g) \end{cases}\\ \Rightarrow m_{dd_{MgSO_4}}=10,4+200-6,4-1,8=202,2(g)\\ \Rightarrow C\%_{MgSO_4}=\dfrac{12}{202,2}.100\%\approx 5,93\%\)
⇒ Chọn A.