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a, \(m_{CH_3COOH}=100.6\%=6\left(g\right)\Rightarrow n_{CH_3COOH}=\dfrac{6}{60}=0,1\left(mol\right)\)
PT: \(CH_3COOH+NaHCO_3\rightarrow CH_3COONa+CO_2+H_2O\)
Theo PT: \(n_{NaHCO_3}=n_{CH_3COONa}=n_{CO_2}=n_{CH_3COOH}=0,1\left(mol\right)\)
\(\Rightarrow m_{NaHCO_3}=0,1.84=8,4\left(g\right)\)
\(V_{CO_2}=0,1.22,4=2,24\left(l\right)\)
b, Ta có: m dd sau pư = 100 + 8,4 - 0,1.44 = 104 (g)
\(\Rightarrow C\%_{CH_3COONa}=\dfrac{0,1.82}{104}.100\%\approx7,88\%\)
a)
$AgNO_3 + HCl \to AgCl + HNO_3$
Theo PTHH :
$n_{AgCl} = n_{HCl} = n_{AgNO_3} = \dfrac{340.10\%}{170} =0,2(mol)$
$m_{dd\ HCl} = \dfrac{0,2.36,5}{7,3\%} = 100(gam)$
b)
$m_{AgCl} = 0,2.143,5 = 28,7(gam)$
c)
$m_{dd\ sau\ pư} = 340 + 100 -28,7 = 411,3(gam)$
$n_{HNO_3} = n_{AgNO_3} = 0,2(mol)$
$\Rightarrow C\%_{HNO_3} = \dfrac{0,2.63}{411,3}.100\% = 3,06\%$
\(n_{FeCl_3}=\dfrac{48,75}{162,5}=0,3(mol)\\ 3NaOH+FeCl_3\to Fe(OH)_3\downarrow+3NaCl\\ \Rightarrow n_{Fe(OH)_3}=0,3(mol);n_{NaOH}=n_{NaCl}=0,9(mol)\\ a,m_{Fe(OH)_3}=0,3.107=32,1(g)\\ b,m_{dd_{NaOH}}=\dfrac{0,9.40}{10\%}=360(g)\\ c,C\%_{NaCl}=\dfrac{0,9.58,5}{360+48,75-32,1}.100\%=13,98\%\\ \)
\(d,2Fe(OH)_3+3H_2SO_4\to Fe_2(SO_4)_3+6H_2O\\ \Rightarrow n_{H_2SO_4}=0,45(mol)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{0,45.98}{20\%}=220,5(g)\\ \Rightarrow V_{dd_{H_2SO_4}}=\dfrac{220,5}{1,14}=193,42(ml)\)
mCH3COOH= 150*6/100=9g
nCH3COOH= 9/60=0.15 mol
CH3COOH + NaHCO3 --> CH3COONa + CO2 + H2O
0.15_________0.15__________0.15______0.15
mNaHCO3= 0.15*84=12.6g
mdd NaHCO3= 12.6*100/8.4=150g
m dung dịch sau phản ứng=mdd CH3COOH + mdd NaHCO3 - mCO2= 150+150-0.15*44==293.4g
C%CH3COONa= 12.3/293.4*100%= 4.19%
CH3COOH + NaHCO3 => CH3COONa + CO2 + H2O
mCH3COOH = 150 x 6/100 = 9 (g)
===> nCH3COOH = m/M = 9/60 = 0.15 (mol)
Theo phương trình ==> nNaHCO3 = 0.15 (mol)
mNaHCO3 = n.M = 0.15 x 84 = 12.6 (g)
===> mddNaHCO3 = 12.6 x 100/8.4 = 150 (g)
mdd sau pứ = 150 + 150 - 0.3 = 299.7 (g)
mCH3COONa = n.M = 0.15 x 82 = 12.3 (g)
C%ddCH3COONa = 4.104 %
a, \(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\)
\(FeCl_3+3KOH\rightarrow3KCl+Fe\left(OH\right)_{3\downarrow}\)
\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
Theo PT: \(n_{HCl}=6n_{Fe_2O_3}=0,6\left(mol\right)\)
\(\Rightarrow m_{HCl}=0,6.36,5=21,9\left(g\right)\)
b, \(n_{Fe\left(OH\right)_3}=n_{FeCl_3}=2n_{Fe_2O_3}=0,2\left(mol\right)\)
\(\Rightarrow m_{Fe\left(OH\right)_3}=0,2.107=21,4\left(g\right)\)
\(n_{KOH}=3n_{FeCl_3}=0,6\left(mol\right)\)
\(\Rightarrow C_{M_{KOH}}=\dfrac{0,6}{0,2}=3\left(M\right)\)
\(n_{H_2SO_4}=1.0,2=0,2(mol)\\ H_2SO_4+BaCl_2\to BaSO_4\downarrow+2HCl\\ \Rightarrow n_{BaSO_4}=n_{BaCl_2}=0,2(mol)\\ a,m_{BaSO_4}=0,2.233=46,6(g)\\ b,V_{dd_{BaCl_2}}=\dfrac{0,2}{1,5}\approx 0,13(l)\\ c,n_{HCl}=0,4(mol)\\ \Rightarrow C_{M_{HCl}}=\dfrac{0,4}{0,2+0,13}\approx 1,21M\)
\(d,\) Dd sau p/ứ là HCl nên làm quỳ tím hóa đỏ
\(n_{H_2SO_4}=0,2.1=0,2\left(mol\right)\\ H_2SO_4+BaCl_2\rightarrow BaSO_4+2HCl\\ n_{BaCl_2}=n_{BaSO_4}=n_{H_2SO_4}=0,2\left(mol\right)\\ n_{HCl}=2.0,2=0,4\left(mol\right)\\ a,m_{\downarrow}=m_{BaSO_4}=0,2.233=46,6\left(g\right)\\ b,V_{\text{dd}BaCl_2}=\dfrac{0,2}{1,5}=\dfrac{2}{15}\left(l\right)\\ c,C_{M\text{dd}HCl}=\dfrac{0,4}{\dfrac{2}{15}+0,2}=1,2\left(M\right)\\ d,V\text{ì}.c\text{ó}.\text{dd}.HCl\Rightarrow Qu\text{ỳ}.ho\text{á}.\text{đ}\text{ỏ}\)
nFe = 11.2/56 = 0.2 (mol)
Fe + H2SO4 => FeSO4 + H2
0.2____0.2_______0.2___0.2
mH2SO4 = 0.2*98 = 19.6 (g)
mdd H2SO4 = 19.6*100/10 = 196 (g)
m dd sau phản ứng = 11.2 + 196 - 0.4 = 206.8 (g)
mFeSO4 = 0.2*152 = 30.4 (g)
C% FeSO4 = 30.4/206.8 * 100% = 14.7%
Vdd H2SO4 = mdd H2SO4 / D = 196 / 1.14 = 171.9 (ml)
CM FeSO4 = 0.2 / 0.1719 = 1.16 M
\(CH3COOH+NaHCO3→CH3COONa+H2O+CO2\)
\(a. mct của Ch3COOH=\dfrac{200.6}{100} = 12g\)
\(n của CH3COOH= m/M= 12/60= 0,2 mol\)
\(mct của NaHCO3= nxM= 0,2 x 84= 16,8g\)
\(mdd của NaHCO3= 16,8 x 100/ 10= 168g\)
\(b. mct của CH2COONa = nxM= 0,2 x 82= 16,4g\)
\(mdd sau pứ= 200 + 168 - ( 0,2 x 44) =359,2g\)
C%\( dd sau pứ= (16,4 : 359,2) .100% xấp xỉ 4,56%\) % xấp xỉ 4,56%