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a.b.\(n_{H_2}=\dfrac{1,8.10^{23}}{6.10^{23}}=0,3mol\)
Gọi \(\left\{{}\begin{matrix}n_{Na}=x\\n_{Ba}=y\end{matrix}\right.\)
\(2Na+2H_2O\rightarrow2NaOH+H_2\)
x x 1/2 x ( mol )
\(Ba+2H_2O\rightarrow Ba\left(OH\right)_2+H_2\)
y 2y y ( mol )
Ta có:
\(\left\{{}\begin{matrix}23x+137y=22,9\\\dfrac{1}{2}x+y=0,3\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,4\\y=0,1\end{matrix}\right.\)
\(m_{H_2O}=\left[0,4+\left(2.0,1\right)\right].18=10,8g\)
c.\(m=22,9+10,8-0,3.2=33,1g\)
d.\(m_{Na}=0,4.23=9,2g\)
\(m_{Ba}=0,1.137=13,7g\)
Gọi số mol Mg, Zn là a, b (mol)
=> 24a + 65b = 15,75
\(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
PTHH: Mg + 2HCl --> MgCl2 + H2
a---------------->a---->a
Zn + 2HCl --> ZnCl2 + H2
b---------------->b----->b
=> a + b = 0,4
=> a = 0,25; b = 0,15
=> \(\left\{{}\begin{matrix}m_{MgCl_2}=0,25.95=23,75\left(g\right)\\m_{ZnCl_2}=0,15.136=20,4\left(g\right)\end{matrix}\right.\)
=> mmuối = 23,75 + 20,4 = 44,15 (g)
2Na+2H2O->2NaOH+H2
x-------------------x----------0,5x mol
Ba+2H2O->Ba(OH)2+H2
y---------------------y----------y mol
aTa có :)\(\left\{{}\begin{matrix}23x+137y=2,06\\0,5x+y=0,025\end{matrix}\right.\)
=>\(\left\{{}\begin{matrix}x=0,03\\y=0,01\end{matrix}\right.\)
=>mbazo=0,03.40+0,01.171=2,91g
=>m Na=0,03.23=0,69g
=>m Ba=0,01.137=1,27g
PTHH:
2X + 2mHCl ---> 2XClm (A) + mH2
2Y + 2nHCl ---> 2YCln (B) + nH2
\(n_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
Bảo toàn H: \(n_{HCl}=2n_{H_2}=2.0,6=1,2\left(mol\right)\)
\(\rightarrow m_{HCl}=1,2.36,5=43,8\left(g\right)\)
Bảo toàn khối lượng:
\(m_{muối\left(A,B\right)}=27,2+43,8-0,6.2=69,8\left(g\right)\)
a) Mg + 2HCl -> MgCl2 + H2
Al + 3HCl -> AlCl3 + 3/2H2
b) Gọi a, b lần lượt là số mol Mg, Al.
nH2 = 5,6/22,4 = 0,25 (mol)
Mg + 2HCl -> MgCl2 + H2
a 2a a a
Al + 3HCl -> AlCl3 + 3/2H2
b 3b b 3/2b
Ta có hệ pt:
mhh = 24a + 27b = 5,1 (g)
nH2 = a + 3/2b = 0,25 (mol)
=> a = 0,1 (mol)
b = 0,1 (mol)
200 ml = 0,2 l
nHCl = 2a + 3b = 0,2 + 0,3 = 0,5 (mol)
=> CM ddHCl = 0,5/0,2 = 2,5 (M)
%mMg = 24a/5,1*100% = 2,4/5,1*100% = 47,06%
%mAl = 100%-47,06% = 52,94%
\(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\\ 2K+2H_2O\rightarrow2KOH+H_2\\ 2Na+2H_2O\rightarrow2NaOH+H_2\\ KOH+HCl\rightarrow KCl+H_2O\\ NaOH+HCl\rightarrow NaCl+H_2O\\ n_{HCl}=n_{KOH}+n_{NaOH}=2.n_{H_2}=2.0,15=0,3\left(mol\right)\\ m_{HCl}=0,3.36,5=10,95\left(g\right)\)
2Na+2H2O->2NaOH+H2
x-------------------x---------0,5x
2K+2H2O->2KOH+H2
y-----------------y-----------0,5y
nH2O=2n H2
=>mH2O=\(\dfrac{4,48}{22,4}2.18\)=7,2g
Ta có :\(\left\{{}\begin{matrix}23x+39y=11,6\\0,5x+0,5y=0,2\end{matrix}\right.\)
=>x=0,25 mol, y=0,15 mol
=>m bazo=0,25.40+0,15.56=18,4g
d) m Na=0,25.23=5,75g
=>m K=0,15.39=5,85g
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
gọi nNa :a , nk :b (a,b>0)
=> 23a+39b=11,6(g)
\(2Na+2H_2O\rightarrow2NaOH+H_2\)
a \(\dfrac{1}{2}a\)
\(2K+2H_2O\rightarrow2KOH+H_2\)
b \(\dfrac{1}{2}b\)
=> \(\left\{{}\begin{matrix}23a+39b=11,6\\\dfrac{1}{2}a+\dfrac{1}{2}b=0,2\end{matrix}\right.\)
=> a= 0,25 , b = 0,15(mol)
theo pt nH2O = 0,4+0,4=0,8(mol)
=> mH2O = 0,8.18=14,4(g)
theo pthh : nKOH = 0,15 , nNaOH = 0,25
=> \(\left\{{}\begin{matrix}m_{KOH}=0,15.56=8,4\left(g\right)\\m_{NaOH}=0,25.40=10\left(g\right)\end{matrix}\right.\)
\(\left\{{}\begin{matrix}m_K=0,15.39=5,85\left(g\right)\\m_{Na}=0,25.23=5,75\left(g\right)\end{matrix}\right.\)