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Sửa đề : 11.2 g sắt
\(n_{Fe}=\dfrac{11.2}{56}=0.2\left(mol\right)\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
\(0.2....0.2.................0.2\)
\(m_{FeSO_4}=0.2\cdot152=30.4\left(g\right)\)
\(C_{M_{H_2SO_4}}=\dfrac{0.2}{0.05}=4\left(M\right)\)
Fe+2HCl->FeCl2+H2
0,3----0,6--0,3------0,3
n H2=0,3 mol
=>m Fe=0,3.56=16.8g
=>CM=0,6\0,1=6M
CuO+H2-tO>Cu+H2O
0.3---------------0,3
=>m Cu=0,3.64=19,2g
\(n_{H_2}=\dfrac{3,36}{22,4}=0,15(mol)\\ PTHH:Fe+H_2SO_4\to FeSO_4+H_2\\ \Rightarrow n_{H_2SO_4}=n_{H_2}=0,15(mol)\\ \Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,15}{0,05}=3M\\ PTHH:2H_2+O_2\xrightarrow{t^o}2H_2O\\ \Rightarrow n_{O_2}=\dfrac{1}{2}n_{H_2}=0,075(mol)\\ \Rightarrow V_{O_2}=0,075.22,4=1,68(l)\)
+n H2 = 11,2 / 22,4 = 0,5 mol
PT
Fe + H2SO4 -> FeSO4 + H2
0,5__0,5_____0,5______0,5 (mol)
-> mFe phản ứng = 0,5 * 65 = 28 (g)
gọi mdd H2SO4 = x (g)
-> mH2SO4 (dd đầu) = x*24,5%=0,245x (g)
->nH2S04 (dd đầu) = 0,245x /98 = 0,0025x mol
Theo PT nH2SO4 phản ứng = nH2 = 0,5 mol
-> m dd H2SO4 phản ứng = m H2S04 (dd đầu) phản ứng = 0,5 * 98 = 49 (g)
-> x = 0,5/ 0,0025= 200 (g)
m muối FeSO4 = 0,5 * 152 = 76 g
m H2 = 0,5 *2 = 1 (g)
m dd sau = m Fe + m dd H2SO4 - m H2
= 28 + 200 -1=227 g
C% FeSO4 (ddsau) = 76/227 *100% = 33,48%
2Al+3H2SO4->Al2(SO4)3+3H2
0,1----------------------0,075----0,15
n H2=0,15 mol
=>mAl=0,1.27=2,7g
=>m Al2(SO4)3=0,075.342=25,65g
a) PTHH: \(2Al+3H_2SO_2\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
b) \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
\(n_{Al}=\dfrac{2}{3}.0,15=0,1\left(mol\right)\)
\(m_{Al}=0,1.27=2,7\left(g\right)\)
c) \(n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}.0,1=0,05\left(mol\right)\)
\(m_{Al_2\left(SO_4\right)_3}=0,05.342=17,1\left(g\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{Fe}=n_{H_2}=\dfrac{9,9161}{24,79}\approx0,4\left(mol\right)\\ b,m_{Fe}\approx0,4.56\approx22,4\left(g\right)\\ c,n_{HCl}\approx0,4.2\approx0,8\left(mol\right)\\ C_{MddHCl}\approx\dfrac{0,8}{0,25}\approx3,2\left(M\right)\)
a) \(PT:CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\uparrow\)
\(HCl+NaOH\rightarrow NaOH+H_2O\)
b) \(m_{HCl}=\frac{200.10,95\%}{100\%}=21,9\left(g\right)\)
\(n_{HCl}=\frac{21,9}{36,5}=0,6\left(mol\right)\)
c) \(n_{NaOH}=2.0,05=0,1\left(mol\right)\Rightarrow n_{HCl\left(pưNaOH\right)}=0,1\left(mol\right)\)
\(\Rightarrow n_{HCl\left(pưCaCO_3\right)}=0,6-0,1=0,5\left(mol\right)\)
d) \(n_{CaCO_3}=\frac{1}{2}n_{HCl\left(pưCaCO_3\right)}=0,5.\frac{1}{2}=0,25\left(mol\right)\)
\(m_{CaCO_3}=0,25.100=25\left(g\right)\)
e) \(n_{CO_2}=n_{CaCO_3}=0,25\left(mol\right)\)
\(V_{CO_2}=0,25.22,4=5,6\left(l\right)\)
f) \(n_{CaCl_2}=n_{CaCO_3}=0,25\left(mol\right)\)
\(m_{ddA}=25+200-0,25.44=214\left(g\right)\)
\(C\%_{ddCaCl_2}=\frac{0,25.111}{214}.100\%=12,97\%\)
\(C\%_{ddHCldư}=\frac{0,1.36,5}{214}.100\%=1,71\%\)
\(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
PTHH: Fe + H2SO4 ---> FeSO4 + H2
0,3-->0,3----------->0,3
=> \(\left\{{}\begin{matrix}C_{M\left(H_2SO_4\right)}=\dfrac{0,3}{0,15}=2M\\m_{muối}=0,3.152=45,6\left(g\right)\end{matrix}\right.\)
a),b) Fe + 2HCl -> FeCl2 + H2
0,15 <- 0,15 <- 0,15 <- 0,15 /mol
nH2 = \(\frac{3,36}{22,4}=0,15\) (mol)
mFe p/ứ = 0,15 . 56 = 8,4 (g)
mFeCl2 thu được = 0,15 . 127 = 19,05 (g)
c) 50ml = 0,05(l)
\(C_MHCl=\frac{0,15}{0,05}=3\left(M\right)\)
tham khảo cái này nhé!!!
cre:internet