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\(n_{Fe}=\dfrac{0,224}{22,4}=0,01\left(mol\right)\)
Pt : \(Fe+2HCl\rightarrow FeCl_2+H_2|\)
1 2 1 1
0,01 0,02 0,01
a) \(n_{Fe}=\dfrac{0,01.1}{1}=0,01\left(mol\right)\)
\(m_{Fe}=0,01.56=0,56\left(g\right)\)
\(m_{Cu}=1,2-0,56=0,64\left(g\right)\)
0/0Fe = \(\dfrac{0,56.100}{1,2}=46,67\)0/0
0/0Cu = \(\dfrac{0,64.100}{1,2}=53,33\)0/0
b) \(n_{HCl}=\dfrac{0,01.2}{1}=0,02\left(mol\right)\)
⇒ \(m_{HCl}=0,02.36,5=0,73\left(g\right)\)
\(C_{ddHCl}=\dfrac{0,73.100}{10}=7,3\)0/0
Chúc bạn học tốt
a, Ta có: 27nAl + 56nFe = 22 (1)
PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}+n_{Fe}=\dfrac{19,832}{24,79}=0,8\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}m_{Al}=0,4\left(mol\right)\\n_{Fe}=0,2\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,4.27}{22}.100\%\approx49,09\%\\\%m_{Fe}\approx50,91\%\end{matrix}\right.\)
b, \(n_{HCl}=2n_{H_2}=1,6\left(mol\right)\)
\(\Rightarrow C_{M_{HCl}}=\dfrac{1,6}{0,5}=3,2\left(M\right)\)
\(n_{Cu} = a ; n_{Al} = b ; n_{Fe} = c(mol)\\ \Rightarrow 64a + 27b + 56c = 28,6(1)\\ 2Al + 6HCl \to 2AlCl_3 + 3H_2\\ Fe + 2HCl \to FeCl_2 + H_2\\ n_{H_2} = 1,5b + c = \dfrac{13,44}{22,4} = 0,6(2)\\ \text{Mặt khác} : n_{O_2} = \dfrac{8,96}{22,4} = 0,4(mol)\\ 2Cu + O_2 \xrightarrow{t^o} 2CuO\\ 4Al + 3O_2 \xrightarrow{t^o} 2Al_2O_3\\ 4Fe + 3O_2 \xrightarrow{t^o} 2Fe_2O_3\\ \)
Ta có :
\(\dfrac{n_X}{n_{O_2}}=\dfrac{a+b+c}{0,5a +0,75b + 0,75c} = \dfrac{0,6}{0,4}(3)\\ (1)(2)(3)\Rightarrow a = \dfrac{317}{1460} ; b = \dfrac{121}{365}; c = \dfrac{15}{146}\\ \%m_{Cu} = \dfrac{\dfrac{317}{1460}.64}{28,6}.100\% = 48,59\%\\ \%m_{Al} = \dfrac{\dfrac{121}{365}.27}{28,6}.100\% = 31,3\%\\ \%m_{Fe} = 100\% - 41,59\% - 31,3\% = 27,11\%\)
a/ Fe + 2HCl \(\rightarrow\) FeCl2 + H2
nH2 = \(\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
Theo PTHH: nH2 = nFe = 0,15 (mol) \(\Rightarrow m_{Fe}=0,15.56=8,4\left(g\right)\)
\(\Rightarrow m_{Cu}=11-8,4=2,6\left(g\right)\)
\(\Rightarrow\%m_{Fe}=\dfrac{8,4}{11}.100\%\approx76,4\%\)
\(\Rightarrow\%m_{Cu}=100-76,4\approx23,6\%\)
b/ Theo PTHH ta có: nHCl = 2nFe = 2.0,15 = 0,3 (mol)
\(\Rightarrow V_{ddHCl}=\dfrac{0,3}{2}=0,15\left(M\right)\)
c/ mHCl = 36,5 . 0,3 = 10,95(g)
\(\Rightarrow C\%_{HCl}=\dfrac{m_{HCl}}{m_{ddHCl}}.100\%=\dfrac{10,95}{200}.100\%=5,475\%\)
a, PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
Ta có: \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
Theo PT: \(n_{Fe}=n_{H_2}=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,15.56}{11}.100\%\approx76,36\%\\\%m_{Cu}\approx23,64\%\end{matrix}\right.\)
b, Theo PT: \(n_{HCl}=2n_{H_2}=0,3\left(mol\right)\)
\(\Rightarrow V_{ddHCl}=\dfrac{0,3}{2}=0,15\left(l\right)\)
c, \(C\%_{HCl}=\dfrac{0,3.36,5}{200}.100\%=5,475\%\)
Ta có: \(\left\{{}\begin{matrix}n_{Fe\left(P_1\right)}=n_{Fe\left(P_2\right)}=\dfrac{11,2}{56.2}=0,1\left(mol\right)\\n_{Cu\left(P_1\right)}=n_{Cu\left(P_2\right)}=\dfrac{6,4}{64.2}=0,05\left(mol\right)\end{matrix}\right.\)
- Phần 1:
PTHH: `Fe + 2HCl -> FeCl_2 + H_2`
Theo PT: `n_{HCl} = 2n_{Fe} = 0,2 (mol)`
`=>` \(C\%_{HCl}=\dfrac{0,2.36,5}{109,5}.100\%=6,67\%\)
- Phần 2:
\(3Fe+2O_2\xrightarrow[]{t^o}Fe_3O_4\)
\(2Cu+O_2\xrightarrow[]{t^o}2Cu\)
\(Fe_3O_4+4H_2\xrightarrow[]{t^o}3Fe+4H_2O\)
\(CuO+H_2\xrightarrow[]{t^o}Cu+H_2O\)
Vậy sau các phản ứng Fe, Cu vẫn không thay đổi
`=> Y: Fe, Cu`
`=> m_Y = 0,1.56 + 0,05.64 = 8,8 (g)`