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\(\text{1)}m_{KOH}=40.35\%=14\left(g\right)\\ \rightarrow n_{KOH}=\dfrac{14}{56}=0,25\left(mol\right)\\ PTHH:KOH+HCl\rightarrow KCl+H_2O\\ \text{Theo pthh}:n_{HCl}=n_{KOH}=0,25\left(mol\right)\\ \rightarrow V_{ddHCl}=0,25.0,5=0,125\left(l\right)\)
\(\text{2)}n_{Al}=\dfrac{4,05}{27}=0,15\left(mol\right)\\ n_{H_2SO_4}=200.14,7\%=29,4\left(g\right)\\ \rightarrow n_{H_2SO_4}=\dfrac{29,4}{98}=0,3\\ \text{PTHH}:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\\ \text{LTL}:\dfrac{0,15}{2}< \dfrac{0,3}{3}\rightarrow H_2SO_4\text{ dư}\)
\(\text{Theo pthh}:\left\{{}\begin{matrix}n_{H_2SO_4\left(pư\right)}=\dfrac{3}{2}n_{Al}=\dfrac{3}{2}.0,15=0,225\left(mol\right)\\n_{H_2}=n_{H_2SO_4\left(pư\right)}=0,225\left(mol\right)\\n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Al}=\dfrac{1}{2}.0,15=0,075\left(mol\right)\end{matrix}\right.\\ \rightarrow m_{dd\left(\text{sau phản ứng}\right)}=200+4,05-0,3.2=203,45\left(g\right)\)
\(\rightarrow\left\{{}\begin{matrix}C\%_{H_2SO_4\text{ dư}}=\dfrac{\left(0,3-0,225\right).98}{203,45}=3,61\%\\C\%_{Al_2\left(SO_4\right)_3}=\dfrac{342.0,075}{203,45}=12,61\%\end{matrix}\right.\)
`C1:`
`2NaOH+H_2 SO_4 ->Na_2 SO_4 +2H_2 O`
`n_[H_2 SO_4]=0,2.1=0,2(mol)`
`n_[NaOH]=[200.10]/[100.40]=0,5(mol)`
Ta có: `[0,2]/1 < [0,5]/2=>NaOH` dư, `H_2 SO_4` hết.
`=>` Quỳ tím chuyển xanh.
`C2:`
`SO_3 +H_2 O->H_2 SO_4`
`0,2` `0,2` `(mol)`
`n_[SO_3]=16/80=0,2(mol)`
`C_[M_[H_2 SO_4]]=[0,2]/[0,25]=0,8(M)`
\(a.Fe+2HCl\rightarrow FeCl_2+H_2\\ b.n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\\ TheoPT:n_{HCl}=2n_{Fe}=0,2\left(mol\right)\\ \Rightarrow CM_{HCl}=\dfrac{0,2}{0,2}=1M\)
a)b)c)d) mBaCl2=150.16,64%=24,96g
=>nBaCl2=0,12 mol
mH2SO4=100.14,7%=14,7g=>nH2SO4=0,15mol
BaCl2 + H2SO4 =>BaSO4 +2HCl
Bđ: 0,12 mol; 0,15 mol
Pứ: 0,12 mol=>0,12 mol=>0,12 mol=>0,24 mol
Dư: 0,03 mol
Dd ban đầu chứa BaCl2 0,12 mol và H2SO4 0,15 mol
Dd A sau phản ứng chứa HCl 0,24 mol và H2SO4 dư 0,03 mol
mHCl=0,24.36,5=8,76g
mH2SO4=0,03.98=2,94g
Kết tủa B là BaSO4 0,12 mol=>mBaSO4=0,12.233=27,96g
mddA=mddBaCl2+mddH2SO4-mBaSO4
=150+100-27,96=222,04g
C%dd HCl=8,76/222,04.100%=3,945%
C% dd H2SO4=2,94/222,04.100%=1,324%
e) HCl +NaOH =>NaCl +H2O
0,24 mol=>0,24 mol
H2SO4 +2NaOH =>Na2SO4 + 2H2O
0,03 mol=>0,06 mol
TÔNG nNaOH=0,3 mol
=>V dd NaOH=0,3/2=0,15 lit
\(n_{HCl}=0,1.0,2=0,02\left(mol\right)\)
Pt : \(2HCl+Ca\left(OH\right)_2\rightarrow CaCl_2+2H_2O\)
0,02---->0,01---------->0,01
a) Nồng độ mol đề cho rồi mà nhỉ
b) \(m_{muôi}=m_{CaCl2}=0,01.111=1,11\left(g\right)\)
\(n_{NaOH}=\dfrac{200\cdot4\%}{40}=0.2\left(mol\right)\)
\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+H_2O\)
\(0.2..............0.1..............0.1\)
\(V_{dd_{H_2SO_4}}=\dfrac{0.1}{0.2}=0.5\left(l\right)\)
\(m_{Na_2SO_4}=0.1\cdot142=14.2\left(g\right)\)
\(m_{dd}=200+510=710\left(g\right)\)
\(C\%_{Na_2SO_4}=\dfrac{14.2}{710}\cdot100\%=2\%\)
Ta có: mNaOH = 200.4% = 8 (g)
\(\Rightarrow n_{NaOH}=\dfrac{8}{40}=0,2\left(mol\right)\)
PT: \(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
_____0,2______0,1_______0,1 (mol)
a, \(V_{ddH_2SO_4}=\dfrac{0,1}{0,2}=0,5\left(l\right)\)
b, Chất có trong dd sau pư là Na2SO4.
Ta có: m dd sau pư = m dd NaOH + m dd H2SO4 = 200 + 510 = 710 (g)
\(\Rightarrow C\%_{Na_2SO_4}=\dfrac{0,1.142}{710}.100\%=2\%\)
Bạn tham khảo nhé!
\(n_{NaOH}=0,5.0,2=0,1\left(mol\right);n_{HCl}=0,5.0,3=0,15\left(mol\right)\)
PTHH: NaOH + HCl → NaCl + H2O
Mol: 0,1 0,1 0,1
Ta có: \(\dfrac{0,1}{1}< \dfrac{0,15}{1}\) ⇒ NaOH hết, HCl dư
Vdd sau pứ = 0,2 + 0,3 = 0,5 (l)
\(C_{M_{ddNaCl}}=\dfrac{0,1}{0,5}=0,2M\)
\(C_{M_{ddHCldư}}=\dfrac{0,15-0,1}{0,5}=0,1M\)
Bài 1:
\(a.n_{NaOH\left(tổng\right)}=0,05.1+0,2.0,2=0,09\left(mol\right)\\ V_{ddNaOH\left(tổng\right)}=50+200=250\left(ml\right)=0,25\left(l\right)\\ C_{MddNaOH\left(cuối\right)}=\dfrac{0,09}{0,25}=0,36\left(M\right)\\ b.n_{HCl}=0,5.0,02=0,01\left(mol\right)\\ n_{H_2SO_4}=0,08.0,2=0,016\left(mol\right)\\ V_{ddsau}=20+80=100\left(ml\right)=0,1\left(l\right)\\ C_{MddH_2SO_4}=\dfrac{0,016}{0,1}=0,16\left(M\right)\\ C_{MddHCl}=\dfrac{0,01}{0,1}=0,1\left(M\right)\)
Bài 2:
\(a.m_{H_2SO_4}=29,4.10\%=2,94\left(g\right)\\ b.n_{H_2SO_4}=\dfrac{2,94}{98}=0,03\left(mol\right)\\ n_{Fe}=\dfrac{0,56}{56}=0,01\left(mol\right)\\ Fe+H_2SO_4\rightarrow FeSO_4+H_2\\ Vì:\dfrac{0,01}{1}< \dfrac{0,03}{1}\Rightarrow H_2SO_4dư\\ n_{H_2SO_4\left(dư\right)}=0,03-0,01=0,02\left(mol\right)\\ m_{H_2SO_4\left(dư\right)}=0,02.98=1,96\left(g\right)\\ n_{H_2}=n_{Fe}=0,01\left(mol\right)\\ \Rightarrow V_{H_2\left(đktc\right)}=0,01.22,4=0,224\left(l\right)\)
Câu 1:
PTHH: \(NaOH+HCl\rightarrow NaCl+H_2O\)
Ta có: \(n_{HCl}=0,2\cdot2=0,4\left(mol\right)=n_{NaOH}\)
\(\Rightarrow C_{M_{NaOH}}=\dfrac{0,4}{0,2}=2\left(M\right)\)
Câu 2: Bạn xem lại đề !!
Chỗ 6g là số gam ạ!
Tại em đọc nhanh nên máy viết sai