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Bài 1:
\(a.n_{NaOH\left(tổng\right)}=0,05.1+0,2.0,2=0,09\left(mol\right)\\ V_{ddNaOH\left(tổng\right)}=50+200=250\left(ml\right)=0,25\left(l\right)\\ C_{MddNaOH\left(cuối\right)}=\dfrac{0,09}{0,25}=0,36\left(M\right)\\ b.n_{HCl}=0,5.0,02=0,01\left(mol\right)\\ n_{H_2SO_4}=0,08.0,2=0,016\left(mol\right)\\ V_{ddsau}=20+80=100\left(ml\right)=0,1\left(l\right)\\ C_{MddH_2SO_4}=\dfrac{0,016}{0,1}=0,16\left(M\right)\\ C_{MddHCl}=\dfrac{0,01}{0,1}=0,1\left(M\right)\)
Bài 2:
\(a.m_{H_2SO_4}=29,4.10\%=2,94\left(g\right)\\ b.n_{H_2SO_4}=\dfrac{2,94}{98}=0,03\left(mol\right)\\ n_{Fe}=\dfrac{0,56}{56}=0,01\left(mol\right)\\ Fe+H_2SO_4\rightarrow FeSO_4+H_2\\ Vì:\dfrac{0,01}{1}< \dfrac{0,03}{1}\Rightarrow H_2SO_4dư\\ n_{H_2SO_4\left(dư\right)}=0,03-0,01=0,02\left(mol\right)\\ m_{H_2SO_4\left(dư\right)}=0,02.98=1,96\left(g\right)\\ n_{H_2}=n_{Fe}=0,01\left(mol\right)\\ \Rightarrow V_{H_2\left(đktc\right)}=0,01.22,4=0,224\left(l\right)\)
\(n_{NaOH}=\dfrac{25.4\%}{40}=0,025\left(mol\right)\)
\(n_{H_2SO_4}=0,052.0,2=0,0104\left(mol\right)\)
PTHH : \(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
Theo đề: 0,025..........0,0104
Lập tỉ lệ: \(\dfrac{0,025}{2}>\dfrac{0,0104}{1}\) => Sau phản ứng NaOH dư, H2SO4 hết
\(m_{ddsaupu}=25+51=76\left(g\right)\)
\(C\%_{NaOH\left(dư\right)}=\dfrac{(0,025-0,0104\cdot2).40}{76}.100=0,22\%\)
\(C\%_{Na_2SO_4}=\dfrac{0,0104.142}{76}.100=1,94\%\)
mNaOH=25.4%=1g
=>nNaOH=1/40=0,025 mol
nH2SO4=0,2.52/1000=0,0104 mol
2NaOH +H2SO4=>Na2SO4 +2H2O
Bđ:0,025 mol
Pứ:0,0208 mol<=0,0104 mol=>0,0104 mol
Dư:4,2.10^(-3) mol
mNaOH dư=4,2.10^(-3).40=0,168g
mNa2SO4=0,0104.142=1,4768g
mdd sau pứ=25+51=76g
C%dd NaOH dư=0,168/76.100%=0,22%
C%dd Na2SO4=1,4768/76.100%=1,943%
nNaOH=0,5. 1,8=0,9(mol)
nFeCl3=0,8.0,5=0,4(mol)
PTHH: 3 NaOH + FeCl3 -> Fe(OH)3 + 3 NaCl
Vì: 0,9/3 < 0,4/1
=>FeCl3 dư, NaOH hết, tính theo nNaOH
Ta có: nFe(OH)3= nFeCl3(p.ứ)=nNaOH/3=0,9/3=0,3(mol)
nNaCl=nNaOH=0,9(mol)
nFeCl3(dư)=0,4-0,3=0,1(mol)
=>m(rắn)=mFe(OH)3= 108. 0,3= 32,4(g)
Vddsau=0,5+0,5=1(l)
=>CMddFeCl3(dư)=0,1/1=0,1(M)
CMddNaCl=0,9/1=0,9(M)
\(a,n_{HCl}=\dfrac{7,3}{36,5}=0,2\left(mol\right)\\ C_{M\left(HCl\right)}=\dfrac{0,2}{0,4}=0,5M\\ b,n_{H_2SO_4}=\dfrac{73,5}{98}=0,75\left(mol\right)\\ C_{M\left(H_2SO_4\right)}=\dfrac{0,75}{0,5}=1,5M\\ n_{NaOH}=\dfrac{16}{40}=0,4\left(mol\right)\\ C_{M\left(NaOH\right)}=\dfrac{0,4}{0,25}=1,6M\\ n_{Ba\left(OH\right)_2}=\dfrac{34,2}{171}=0,2\left(mol\right)\\ C_{M\left(Ba\left(OH\right)_2\right)}=\dfrac{0,2}{0,8}=0,25M\)
a, \(Na_2O+H_2SO_4\rightarrow Na_2SO_4+H_2O\)
b, Số mol \(H_2SO_4\) là: \(n_1=V.C_M=0,5.0,5=0,25\) (mol)
Số mol \(Na_2SO_4\) là \(n_2=\dfrac{28,4}{142}=0,2\) (mol)
Do \(n_2< n_1\) nên \(H_2SO_4\) còn dư
Suy ra số mol \(Na_2O\) tham gia phản ứng là: \(n=n_2=0,2\) (mol)
Khối lượng là: \(m_{Na_2O}=0,2.62=12,4g\)
\(n_{NaOH}=0,5.0,2=0,1\left(mol\right)\\ n_{H_2SO_4}=0,3.0,1=0,03\left(mol\right)\\ PTHH:2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\\ Vì:\dfrac{0,1}{2}>\dfrac{0,03}{1}\Rightarrow NaOHdư\\ \Rightarrow ddA:NaOH\left(dư\right),Na_2SO_4\\ n_{Na_2SO_4}=n_{H_2SO_4}=0,03\left(mol\right)\\ n_{NaOH\left(dư\right)}=0,1-0,03.2=0,04\left(mol\right)\\ V_{ddA}=V_{ddNaOH}+V_{ddH_2SO_4}=0,5+0,3=0,8\left(l\right)\\ C_{MddNaOH\left(dư\right)}=\dfrac{0,04}{0,8}=0,05\left(M\right)\\ C_{MddNa_2SO_4}=\dfrac{0,03}{0,8}=0,0375\left(M\right)\)