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nZn = 13/65 = 0,2 (mol)
nO2 = 4,48/22,4 = 0,2 (mol)
PTHH: 2Zn + O2 -> (t°) 2ZnO
LTL: 0,2/2 < 0,2 => O2 dư
nO2 (p/ư) = 0,2/2 = 0,1 (mol)
mO2 (dư) = (0,2 - 0,1) . 32 = 3,2 (g)
nZnO = nZn = 0,2 (mol)
mZnO = 0,2 . 81 = 16,2 (g)
\(a.n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\ Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{ZnCl_2}=n_{H_2}=n_{Zn}=0,2\left(mol\right)\\ m_{ZnCl_2}=0,2.136=27,2\left(g\right)\\ V_{H_2}=0,2.22,4=4,48\left(l\right)\\ b.n_{CuO}=\dfrac{12}{80}=0,15\left(mol\right)\\ CuO+H_2-^{t^o}\rightarrow Cu+H_2O\\ LTL:\dfrac{0,15}{1}< \dfrac{0,2}{1}\\ \Rightarrow H_2dưsauphảnứng\\ n_{Cu}=n_{H_2\left(pứ\right)}=n_{H_2O}=n_{CuO}=0,15\left(mol\right)\\ m_{Cu}=0,15.64=9,6\left(g\right)\\ m_{H_2\left(dư\right)}=\left(0,2-0,15\right).2=0,1\left(g\right)\\ m_{H_2O}=0,15.18=2,7\left(g\right)\)
\(n_P=\dfrac{6,2}{31}=0,2\left(mol\right)\\ n_{O_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\\ PTHH:4P+5O_2\underrightarrow{t^o}2P_2O_5\\ LTL:\dfrac{0,2}{4}< \dfrac{0,4}{5}\Rightarrow O_2dư\)
\(n_{O_2\left(pư\right)}=\dfrac{5}{4}n_P=\dfrac{5}{4}.0,2=0,25\left(mol\right)\\ n_{O_2\left(dư\right)}=0,4-0,25=0,15\left(mol\right)\)
\(n_{P_2O_5\left(lt\right)}=\dfrac{1}{2}n_P=\dfrac{1}{2}.0,2=0,1\left(mol\right)\\ m_{P_2O_5\left(lt\right)}=0,1.142=14,2\left(g\right)\\ m_{P_2O_5\left(tt\right)}=0,1.142.80\%=11,36\left(g\right)\)
\(1,2H_2+O_2\underrightarrow{t}2H_2O\)
\(2Mg+O_2\underrightarrow{t}2MgO\)
\(2Cu+O_2\underrightarrow{t}2CuO\)
\(S+O_2\underrightarrow{t}SO_2\)
\(4Al+3O_2\underrightarrow{t}2Al_2O_3\)
\(C+O_2\underrightarrow{t}CO_2\)
\(4P+5O_2\underrightarrow{t}2P_2O_5\)
\(2,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(a,n_{O_2}=0,2\left(mol\right)\Rightarrow n_{CO_2}=0,2\left(mol\right)\Rightarrow m_{CO_2}=8,8\left(g\right)\)
\(b,n_C=0,3\left(mol\right)\Rightarrow n_{CO_2}=0,3\left(mol\right)\Rightarrow m_{CO_2}=13,2\left(g\right)\)
c, Vì\(\frac{0,3}{1}>\frac{0,2}{1}\)nên C phản ửng dư, O2 phản ứng hết, Bài toán tính theo O2
\(n_{O_2}=0,2\left(mol\right)\Rightarrow n_{CO_2}=0,2\left(mol\right)\Rightarrow m_{CO_2}=8,8\left(g\right)\)
\(3,PTHH:CH_4+2O_2\underrightarrow{t}CO_2+2H_2O\)
\(C_2H_2+\frac{5}{2}O_2\underrightarrow{t}2CO_2+H_2O\)
\(C_2H_6O+3O_2\underrightarrow{t}2CO_2+3H_2O\)
\(4,a,PTHH:4P+5O_2\underrightarrow{t}2P_2O_5\)
\(n_P=1,5\left(mol\right)\Rightarrow n_{O_2}=1,2\left(mol\right)\Rightarrow m_{O_2}=38,4\left(g\right)\)
\(b,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(n_C=2,5\left(mol\right)\Rightarrow n_{O_2}=2,5\left(mol\right)\Rightarrow m_{O_2}=80\left(g\right)\)
\(c,PTHH:4Al+3O_2\underrightarrow{t}2Al_2O_3\)
\(n_{Al}=2,5\left(mol\right)\Rightarrow n_{O_2}=1,875\left(mol\right)\Rightarrow m_{O_2}=60\left(g\right)\)
\(d,PTHH:2H_2+O_2\underrightarrow{t}2H_2O\)
\(TH_1:\left(đktc\right)n_{H_2}=1,5\left(mol\right)\Rightarrow n_{O_2}=0,75\left(mol\right)\Rightarrow m_{O_2}=24\left(g\right)\)
\(TH_2:\left(đkt\right)n_{H_2}=1,4\left(mol\right)\Rightarrow n_{O_2}=0,7\left(mol\right)\Rightarrow m_{O_2}=22,4\left(g\right)\)
\(5,PTHH:S+O_2\underrightarrow{t}SO_2\)
\(n_{O_2}=0,46875\left(mol\right)\)
\(n_{SO_2}=0,3\left(mol\right)\)
Vì\(0,46875>0,3\left(n_{O_2}>n_{SO_2}\right)\)nên S phản ứng hết, bài toán tính theo S.
\(a,\Rightarrow n_S=n_{SO_2}=0,3\left(mol\right)\Rightarrow m_S=9,6\left(g\right)\)
\(n_{O_2}\left(dư\right)=0,16875\left(mol\right)\Rightarrow m_{O_2}\left(dư\right)=5,4\left(g\right)\)
\(6,a,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_C=1,5\left(mol\right)\Rightarrow m_C=18\left(g\right)\)
\(b,PTHH:2H_2+O_2\underrightarrow{t}2H_2O\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_{H_2}=0,75\left(mol\right)\Rightarrow m_{H_2}=1,5\left(g\right)\)
\(c,PTHH:S+O_2\underrightarrow{t}SO_2\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_S=1,5\left(mol\right)\Rightarrow m_S=48\left(g\right)\)
\(d,PTHH:4P+5O_2\underrightarrow{t}2P_2O_5\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_P=1,2\left(mol\right)\Rightarrow m_P=37,2\left(g\right)\)
\(7,n_{O_2}=5\left(mol\right)\Rightarrow V_{O_2}=112\left(l\right)\left(đktc\right)\);\(V_{O_2}=120\left(l\right)\left(đkt\right)\)
\(8,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(m_C=0,96\left(kg\right)\Rightarrow n_C=0,08\left(kmol\right)=80\left(mol\right)\Rightarrow n_{O_2}=80\left(mol\right)\Rightarrow V_{O_2}=1792\left(l\right)\)
\(9,n_p=0,2\left(mol\right);n_{O_2}=0,3\left(mol\right)\)
\(PTHH:4P+5O_2\underrightarrow{t}2P_2O_5\)
Vì\(\frac{0,2}{4}< \frac{0,3}{5}\)nên P hết O2 dư, bài toán tính theo P.
\(a,n_{O_2}\left(dư\right)=0,05\left(mol\right)\Rightarrow m_{O_2}\left(dư\right)=1,6\left(g\right)\)
\(b,n_{P_2O_5}=0,1\left(mol\right)\Rightarrow m_{P_2O_5}=14,2\left(g\right)\)
nZn = 13/65 = 0,2 (mol)
PTHH: Zn + 2HCl -> ZnCl2 + H2
Mol: 0,2 ---> 0,4 ---> 0,2 ---> 0,2
mZnCl2 = 0,2 . 136 = 27,2 (g)
VH2 = 0,2 . 22,4 = 4,48 (l)
nCuO = 12/80 = 0,15 (mol)
PTHH: CuO + H2 -> (t°) Cu + H2O
LTL: 0,15 < 0,2 => H2 dư
nCuO (p/ư) = nCu = nH2O = nCuO = 0,15 (mol)
mCu = 0,15 . 64 = 9,6 (g)
mH2O = 0,15 . 18 = 2,7 (g)
mCuO (dư) = (0,2 - 0,15) . 80 = 4 (g)
Bài 1:
PT: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
a, Ta có: \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
\(n_{O_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,1}{3}< \dfrac{0,1}{2}\), ta được O2 dư.
Theo PT: \(n_{O_2\left(pư\right)}=\dfrac{2}{3}n_{Fe}=\dfrac{1}{15}\left(mol\right)\)
\(\Rightarrow n_{O_2\left(dư\right)}=0,1-\dfrac{1}{15}=\dfrac{1}{30}\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}m_{O_2\left(dư\right)}=\dfrac{1}{30}.32\approx1,067\left(g\right)\\V_{O_2\left(dư\right)}=\dfrac{1}{30}.2,24\approx0,746\left(l\right)\end{matrix}\right.\)
b, Theo PT: \(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=\dfrac{1}{30}\left(mol\right)\)
\(\Rightarrow m_{Fe_3O_4}=\dfrac{1}{30}.232\approx7,733\left(g\right)\)
Bài 2:
PT: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
a, Ta có: \(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
Theo PT: \(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=\dfrac{1}{15}\left(mol\right)\)
\(\Rightarrow m_{Fe_3O_4}=\dfrac{1}{15}.232\approx15,467\left(g\right)\)
b, Theo PT: \(n_{O_2}=\dfrac{2}{3}n_{Fe}=\dfrac{2}{15}\left(mol\right)\)
\(\Rightarrow V_{O_2}=\dfrac{2}{15}.22,4\approx2,9867\left(l\right)\)
c, PT: \(2N_2+5O_2\underrightarrow{t^o}2N_2O_5\)
Ta có: \(n_{N_2}=\dfrac{2,8}{28}=0,1\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,1}{2}>\dfrac{\dfrac{2}{15}}{5}\), ta được N2 dư.
Theo PT: \(n_{N_2O_5}=\dfrac{2}{5}n_{O_2}=\dfrac{4}{75}\left(mol\right)\)
\(\Rightarrow m_{N_2O_5}=\dfrac{4}{75}.108=5,76\left(g\right)\)
Bạn tham khảo nhé!
Bài 1 :
\(n_{Fe}=\dfrac{5.6}{56}=0.1\left(mol\right)\)
\(n_{O_2}=\dfrac{2.24}{224}=0.1\left(mol\right)\)
\(3Fe+2O_2\underrightarrow{t^0}Fe_3O_4\)
\(Bđ:0.1......0.1\)
\(Pư:0.1.......\dfrac{1}{15}...\dfrac{1}{30}\)
\(Kt:0........\dfrac{1}{30}....\dfrac{1}{30}\)
\(V_{O_2\left(dư\right)}=\dfrac{1}{30}\cdot22.4=0.747\left(l\right)\)
\(m_{Fe_3O_4}=\dfrac{1}{30}\cdot232=7.73\left(g\right)\)
Bài 2 :
\(n_{Fe}=\dfrac{11.2}{56}=0.2\left(mol\right)\)
\(3Fe+2O_2\underrightarrow{t^0}Fe_3O_4\)
\(0.2.......0.3.......\dfrac{1}{15}\)
\(V_{O_2}=0.3\cdot22.4=6.72\left(l\right)\)
\(m_{Fe_3O_4}=\dfrac{1}{15}\cdot232=15.47\left(g\right)\)
\(n_{N_2}=\dfrac{2.8}{28}=0.1\left(mol\right)\)
\(2N_2+5O_2\underrightarrow{t^0}2N_2O_5\)
\(0.12......0.3........0.12\)
\(m_{N_2O_5}=0.12\cdot108=12.96\left(g\right)\)
`1)nP = 6,2: 31= 0,2 (mol)
4P + 5O2 -> 2P2O5
0.2 -> 0.25 -> 0.1 (mol)
mP2O5 = 0.1 × 142 = 14.2 g
VO2 = 0.25× 22.4 = 5.6 l
Bài 2
Zn+2HCl--->ZnCl2+H2
a) n H2=3,36/22,4=0,15(mol)
Theo pthh
n Zn=n H2=0,15(mol)
m Zn=0,15.65=9,75(g)
b) n ZnCl2=n H2=0,15(mol)
m ZnCl2 = 0,15.136= 20,4(g)
c) C1: Theo pthh
n HCl=2n H2=0,3(mol)
m HCl=0,3.36,5=10,95(g)
C2: Áp dụng định luật bảo toàn khối lượng ta có
m HCl=m H2+m ZnCl2-m Zn
=20,4+0,3-9,75=10,95(g)
Câu 3
2H2+O2--->2H2O
a) n H2=n O2=5,6/22,4=0,25(mol)
Lập tỉ số
\(n_{H2}=\frac{0,25}{2}< n_{O2}=\frac{0,25}{1}\)
--> O2 dư
Theo pthh
n O2=1/2n H2=0,125(mol)
n O2 dư=0,25-0,125=0,125(mol)
V O2 dư =0,125.22,4=2,8(l)
b) Theo pthh
n H2O=n H2=0,25(mol)
m H2O = 0,25.18 = 4,5(g)
Bài 4
2Na+2H2O--->2NaOH+H2
a) n H2=2,24/22,4=0,1(mol)
Theo pthh
n Na = 2n H2 = 0,2(g)
m Na=0,2.23=4,6(g)
b) Theo pthh
n NaOH=2 n H2 = 0,2(mol)
m=m NaOH = 0,2.40=8(g)
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